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Uranium Oligomerization in Chloride-Based High Temperature Melts: In Situ XAS Studies Anand I. Bhatt, Erwan du Fou de Kerdaniel, Hajime Kinoshita, Francis R. Livens, Iain May, Ilya B. Polovov, Clint A. Sharrad, Vladimir A. Volkovich, John M. Charnock, and Robert G. Lewin pp 2 - 4; DOI: 10.1021/ic048617v |
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Synthesis and Properties of the Elusive Ruthenium(II) Complexes of 4'-Cyano-2,2':6',2' '-terpyridine Jianhua Wang, Yuan-Qing Fang, Garry S. Hanan, Frédérique Loiseau, and Sebastiano Campagna pp 5 - 7; DOI: 10.1021/ic048891p |
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Tetranuclear Copper(II) Complex with Glucose-1-phosphate and Its Phosphate Ester Exchange with ATP Merii Kato and Tomoaki Tanase pp 8 - 10; DOI: 10.1021/ic0487631 |
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Infrared Spectra of the Group 2 Metal Dihydroxide Molecules Lester Andrews and Xuefeng Wang pp 11 - 13; DOI: 10.1021/ic0483794 |
Sterically Controlled Esterification on Bis( -hydroxo) Dioxovanadium Site in  -H2SiV2W10O404-Yoshinao Nakagawa, Kazuhiro Uehara, and Noritaka Mizuno pp 14 - 16; DOI: 10.1021/ic0483388 |
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Hydrogenation of Two-Electron Mixed-Valence Iridium Alkyl Complexes Adam S. Veige, Thomas G. Gray, and Daniel G. Nocera pp 17 - 26; DOI: 10.1021/ic049246l |
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Solid-State and Solution-State Coordination Chemistry of the Zinc Triad with the Mixed N,S Donor Ligand Bis(2-methylpyridyl) Sulfide Steven M. Berry, Deborah C. Bebout, and Raymond J. Butcher pp 27 - 39; DOI: 10.1021/ic048915s |
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Ternary Ligand-Zinc-Hydroxamate Complexes Yu-Hung Chiu, Gregory J. Gabriel, and James W. Canary pp 40 - 44; DOI: 10.1021/ic0493090 |
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Structural Reinvestigation of Ammonium Hypophosphite: Was Dihydrogen Bonding Observed Long Ago? Simona Marincean, Radu Custelcean, Robin S. Stein, and James E. Jackson pp 45 - 48; DOI: 10.1021/ic048657z |
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Synthesis, Structural Characterization, and Computational Study of the Strong Oxidant Salt [XeOTeF5][Sb(OTeF5)6]·SO2ClF Hélène P. A. Mercier, Matthew D. Moran, Jeremy C. P. Sanders, Gary J. Schrobilgen, and R. J. Suontamo pp 49 - 60; DOI: 10.1021/ic0400890 |
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Syntheses and Crystal Structures of Dinuclear Complexes Containing d-Block and f-Block Luminophores. Sensitization of NIR Luminescence from Yb(III), Nd(III), and Er(III) Centers by Energy Transfer from Re(I)- and Pt(II)-Bipyrimidine Metal Centers Nail M. Shavaleev, Gianluca Accorsi, Dalia Virgili, Zöe R. Bell, Theodore Lazarides, Giuseppe Calogero, Nicola Armaroli, and Michael D. Ward pp 61 - 72; DOI: 10.1021/ic048875s |
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New 3-D Chiral Framework of Indium with 1,3,5-Benzenetricarboxylate Zhengzhong Lin, Feilong Jiang, Lian Chen, Daqiang Yuan, and Maochun Hong pp 73 - 76; DOI: 10.1021/ic0494962 |
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Spirocyclic Sulfur and Selenium Ligands as Molecular Rigid Rods in Coordination of Transition Metal Centers Marina A. Petrukhina, Colin Henck, Bo Li, Eric Block, Jin Jin, Shao-Zhong Zhang, and Rodolphe Clerac pp 77 - 84; DOI: 10.1021/ic040102g |
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Dioxygen Binding to Complexes with FeII2(-OH)2 Cores: Steric Control of Activation Barriers and O2-Adduct Formation Sergey V. Kryatov, Sonia Taktak, Ivan V. Korendovych, Elena V. Rybak-Akimova, József Kaizer, Stéphane Torelli, Xiaopeng Shan, Sanjay Mandal, Vicki L. MacMurdo, Antoni Mairata i Payeras, and Lawrence Que, Jr. pp 85 - 99; DOI: 10.1021/ic0485312 |
Electronic Properties and Stability of DititaniumIV Substituted  -Keggin Polyoxotungstate with Heteroatom Phosphorus by DFTWei Guan, Likai Yan, Zhongmin Su, Shuxia Liu, Min Zhang, and Xiaohong Wang pp 100 - 107; DOI: 10.1021/ic049830u |
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Infrared Spectrum of Hg(OH)2 in Solid Neon and Argon Xuefeng Wang and Lester Andrews pp 108 - 113; DOI: 10.1021/ic048673w |
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Formation of Mono(dithiolene)-Thiocarboxamido Complexes in Reactions of Thio(dithiocarbamato)-Mo/W Complexes and Dimethyl Acetylenedicarboxylate Patrick J. Lim, Damian A. Slizys, Edward R. T. Tiekink, and Charles G. Young pp 114 - 121; DOI: 10.1021/ic048882g |
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Reactions of Potent Antitumor Complex trans-[RuIIICl4(indazole)2]- with a DNA-Relevant Nucleobase and Thioethers: Insight into Biological Action Alexander Egger, Vladimir B. Arion, Erwin Reisner, Berta Cebrián-Losantos, Sergiu Shova, Günter Trettenhahn, and Bernhard K. Keppler pp 122 - 132; DOI: 10.1021/ic048967h |
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Framework Control by a Metalloligand Having Multicoordination Ability: New Synthetic Approach for Crystal Structures and Magnetic Properties Shin-ichiro Noro, Hitoshi Miyasaka, Susumu Kitagawa, Tatsuo Wada, Takashi Okubo, Masahiro Yamashita, and Tadaoki Mitani pp 133 - 146; DOI: 10.1021/ic049550e |
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Dinuclear Zinc(II) Complexes of Tetraiminodiphenol Macrocycles and Their Interactions with Carboxylate Anions and Amino Acids. Photoluminescence, Equilibria, and Structure Bula Dutta, Pradip Bag, Ulrich Flörke, and Kamalaksha Nag pp 147 - 157; DOI: 10.1021/ic049056a |
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Isomerization and Oxygen Atom Transfer Reactivity in Oxo-Mo Complexes of Relevance to Molybdoenzymes Justin T. Hoffman, Simon Einwaechter, Balwant S. Chohan, Partha Basu, and Carl J. Carrano: pp 158 - 158; DOI: 10.1021/ic040126n |
Issue 2
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Neutral Metallomacrocycles with Four or Ten (PEt3)Pd(II) Centers Thomas Brasey, Rosario Scopelliti, and Kay Severin pp 160 - 162; DOI: 10.1021/ic048619f |
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Insertion of Ga(DDP) into the Au-Cl Bond of (PPh3)AuCl: A First Structurally Characterized Au-Ga Bond Andreas Kempter, Christian Gemel, and Roland A. Fischer pp 163 - 165; DOI: 10.1021/ic048524d |
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Synthesis and X-ray Structures of Dinuclear and Trinuclear Gold(I) and Dinuclear Gold(II) Amidinate Complexes Hanan E. Abdou, Ahmed A. Mohamed, and John P. Fackler, Jr. pp 166 - 168; DOI: 10.1021/ic048855q |
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Confirmation of the Semivacant Wells-Dawson Polyoxotungstate Skeleton. The Structures of [Ce{X(H4)W17O61}2]19- (X = P, As) Indicate the Probable Location of Internal Protons Nebebech Belai, Michael H. Dickman, Michael T. Pope, Roland Contant, Bineta Keita, Israel-Martyr Mbomekalle, and Louis Nadjo pp 169 - 171; DOI: 10.1021/ic048920w |
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Bis(1,2,3-trimethylindenyl)iron(III) 2,3-Dicyanonaphtho-1,4-quinonide, a Non-Metallocene, Charge-Transfer Salt Metamagnet with Complementary Donor-Acceptor Geometries Jeffrey A. Crisp, M. Brett Meredith, Timothy P. Hanusa, Guangbin Wang, William W. Brennessel, and Gordon T. Yee pp 172 - 174; DOI: 10.1021/ic048398d |
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Synthesis of a Vanadium(III) Tris(arylthiolato) Complex and Its Reactions with Azide and Azo Compounds: Formation of a Sulfenamide Complex via Cleavage of an Azo N=N Bond Takashi Komuro, Tsukasa Matsuo, Hiroyuki Kawaguchi, and Kazuyuki Tatsumi pp 175 - 177; DOI: 10.1021/ic048721c |
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Engineering of a Novel Ruthenium Sensitizer and Its Application in Dye-Sensitized Solar Cells for Conversion of Sunlight into Electricity C. Klein, Md. K. Nazeeruddin, P. Liska, Davide Di Censo, N. Hirata, E. Palomares, J. R.Durrant, and M. Grätzel pp 178 - 180; DOI: 10.1021/ic048810p |
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Transformation of a Metal-Organic Framework from the NbO to PtS Net Banglin Chen, Nathan W. Ockwig, Frank R. Fronczek, Damacio S. Contreras, and Omar M. Yaghi pp 181 - 183; DOI: 10.1021/ic048612y |
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Incorporating Transition Metal Complexes into Tetrathioarsenates(V): Syntheses, Structures, and Properties of Two Unprecedented [Mn(dien)2]n[Mn(dien)AsS4]2n·4nH2O and [Mn(en)3]2[Mn(en)2AsS4][As3S6] Ming-Lai Fu, Guo-Cong Guo, Li-Zhen Cai, Zhang-Jing Zhang, and Jin-Shun Huang pp 184 - 186; DOI: 10.1021/ic048579f |
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Synthesis, Crystal Structure, and High-Precision High-Frequency and -Field Electron Paramagnetic Resonance Investigation of a Manganese(III) Complex: [Mn(dbm)2(py)2](ClO4) Guillem Aromí, Joshua Telser, Andrew Ozarowski, Louis-Claude Brunel, Helen-Margaret Stoeckli-Evans, and J. Krzystek pp 187 - 196; DOI: 10.1021/ic049180u |
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Structural Chemistry of A3CuBO6 (A = Ca, Sr; B = Mn, Ru, Ir) as a Function of Temperature A. Sam Aldridge, Peter D. Battle, John S. O. Evans, Caroline A. Moore, Timothy J. Prior, and Philip J. Wiseman pp 197 - 205; DOI: 10.1021/ic0487629 |
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High-Frequency, High-Field EPR; Magnetic Susceptibility; and X-ray Studies on a Ferromagnetic Heterometallic Complex of Diethanolamine (H2L), [Cu4(NH3)4(HL)4][CdBr4]Br2·3dmf·H2O Elena A. Buvaylo, Vladimir N. Kokozay, Olga Yu. Vassilyeva, Brian W. Skelton, Julia Jezierska, Louis C. Brunel, and Andrew Ozarowski pp 206 - 216; DOI: 10.1021/ic049044p |
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Knotted Network Consisting of 3-Threads and a Zwitterionic One-Dimensional Polymorphs of trans-3-(3-Pyridyl)acrylate of Cobalt and Nickel, MII(C8H6NO2)2(H2O)2 Mohamedally Kurmoo, Claude Estournès, Yoshimi Oka, Hitoshi Kumagai, and Katsuya Inoue pp 217 - 224; DOI: 10.1021/ic0488536 |
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Laser Photoinitiated Nitrosylation of 3-Electron Reduced Nm europaea Hydroxylamine Oxidoreductase: Kinetic and Thermodynamic Properties of the Nitrosylated Enzyme Maria Zulema Cabail, Joshua Kostera, and A. Andrew Pacheco pp 225 - 231; DOI: 10.1021/ic048822a |
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Novel Chiral "Calixsalen" Macrocycle and Chiral Robson-type Macrocyclic Complexes Jian Gao, Joseph H. Reibenspies, Ralph A. Zingaro, F. Ross Woolley, Arthur E. Martell, and Abraham Clearfield pp 232 - 241; DOI: 10.1021/ic049181m |
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Synthesis, Structure, and Properties of [Pt(II)(diimine)(dithiolate)] Dyes with 3,3'-, 4,4'-, and 5,5'-Disubstituted Bipyridyl: Applications in Dye-Sensitized Solar Cells Elaine A. M. Geary, Lesley J. Yellowlees, Lorna A. Jack, Iain D. H. Oswald, Simon Parsons, Narukuni Hirata, James R. Durrant, and Neil Robertson pp 242 - 250; DOI: 10.1021/ic048799t |
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New Titanium and Nickel Gallophosphates with Layered Structures Chia-Her Lin and Sue-Lein Wang pp 251 - 257; DOI: 10.1021/ic0494556 |
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Toward Templated Metal-Organic Frameworks: Synthesis, Structures, Thermal Properties, and Luminescence of Three Novel Lanthanide-Adipate Frameworks Daniel T. de Lill, Noel S. Gunning, and Christopher L. Cahill pp 258 - 266; DOI: 10.1021/ic048755k |
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Hydrogen Bonding and Covalent Effects in Binding of Cisplatin to Purine Bases: Ab Initio and Atoms in Molecules Studies Arturo Robertazzi and James A. Platts pp 267 - 274; DOI: 10.1021/ic0489544 |
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A Spirocyclic System Comprising Both Phosphazane and Phosphazene Rings Philip I. Richards and Alexander Steiner pp 275 - 281; DOI: 10.1021/ic048665f |
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Two Distinct Ln(III)-Cu(I) Cyanide Extended Arrays: Structures and Synthetic Methodology for Inclusion and Layer Complexes Shengming Liu, Christine E. Plecnik, Edward A. Meyers, and Sheldon G. Shore pp 282 - 292; DOI: 10.1021/ic040113+ |
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Reaction of Thiols with N-Bonded Sulfenamide Complexes of Cobalt(III): Steric Effect and Reaction Pathway Margaret J. Sisley, Michael J. Ferguson, and Robert B. Jordan pp 293 - 299; DOI: 10.1021/ic048926l |
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Syntheses, Structures, and Ion-Exchange Properties of the Three-Dimensional Framework Uranyl Gallium Phosphates, Cs4[(UO2)2(GaOH)2(PO4)4]·H2O and Cs[UO2Ga(PO4)2] Tatiana Y. Shvareva, Tyler A. Sullens, Thomas C. Shehee, and Thomas E. Albrecht-Schmitt pp 300 - 305; DOI: 10.1021/ic048638p |
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Cooperative Pull and Push Effects on the O-O Bond Cleavage in Acylperoxo Complexes of [(Salen)MnIIIL]: Ensuring Formation of Manganese(V) Oxo Species Ilja V. Khavrutskii, Djamaladdin G. Musaev, and Keiji Morokuma pp 306 - 315; DOI: 10.1021/ic0490122 |
Oxidative Dissolution of Copper and Zinc Metal in Carbon Dioxide with tert-Butyl Peracetate and a  -Diketone Chelating AgentPamela M. Visintin, Carol A. Bessel, Peter S. White, Cynthia K. Schauer, and Joseph M. DeSimone pp 316 - 324; DOI: 10.1021/ic049765o |
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Structural and Spectroscopic Characterization of First-Row Transition Metal(II) Substituted Blue Copper Model Complexes with Hydrotris(pyrazolyl)borate Yuki Matsunaga, Kiyoshi Fujisawa, Naoko Ibi, Yoshitaro Miyashita, and Ken-ichi Okamoto pp 325 - 335; DOI: 10.1021/ic049814x |
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Electrochemical Synthesis and Structural Characterization of Silver(I) Complexes of N-2-Pyridyl Sulfonamide Ligands with Different Nuclearity: Influence of the Steric Hindrance at the Pyridine Ring and the Sulfonamide Group on the Structure of the Complexes Inmaculada Beloso, Jesús Castro, José A. García-Vázquez, Paulo Pérez-Lourido, Jaime Romero, and Antonio Sousa pp 336 - 351; DOI: 10.1021/ic0490268 |
Synthesis and Structural Characterization of Bi- and Trimetallic Octacyanometalate(IV) Complexes: [ , -MII(en)3][cis-MII(en)2(OH2)][MIV(CN)8]·2H2O and [cis-MII(en)2(OH2)]2[(-NC)2MIV(CN)6]·4H2O (MII = Mn, Co, Ni; MIV = Mo, W)Jeffrey R. Withers, Chad Ruschmann, Pasano Bojang, Sean Parkin, and Stephen M. Holmes pp 352 - 358; DOI: 10.1021/ic048936m |
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Insertion Reactions of Carbon Dioxide into Zn-N Bonds: Syntheses and Structures of Tetrameric and Dimeric Alkylzinc Carbamato Complexes Yongjun Tang, W. Scott Kassel, Lev N. Zakharov, Arnold L. Rheingold, and Richard A. Kemp pp 359 - 364; DOI: 10.1021/ic048830r |
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Studies of Bicarbonate Binding by Dinuclear and Mononuclear Ni(II) Complexes Rachel Newell, Aaron Appel, D. L. DuBois, and M. Rakowski DuBois pp 365 - 373; DOI: 10.1021/ic049202c |
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Electronic Structure of Li2Ga and Li9Al4, Two Solids Containing Infinite and Uniform Zigzag Chains Pere Alemany, Miquel Llunell, and Enric Canadell pp 374 - 381; DOI: 10.1021/ic049003t |
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Synthesis and Characterization of the Novel Monoamide Derivatives of Gd-TTDA Yun-Ming Wang, Cha-Ru Li, Yu-Chin Huang, Ming-Hung Ou, and Gin-Chung Liu pp 382 - 392; DOI: 10.1021/ic049401w |
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Dendritic Tetranuclear Ru(II) Complexes Based on the Nonsymmetrical PHEHAT Bridging Ligand and Their Building Blocks: Synthesis, Characterization, and Electrochemical and Photophysical Properties Julien Leveque, Benjamin Elias, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker pp 393 - 400; DOI: 10.1021/ic048941q |
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Synthesis, Structure, and Kinetics and Stereochemistry of Base-Catalyzed Hydrolysis of meso- and rac-[Co2(tmpdtne)Cl2]4+, Bis(pentaamine) Complexes Devoid of Deprotonatable NH Centers W. Gregory Jackson, Alistair J. Dickie, Josephine A. McKeon, Leone Spiccia, Suzanne J. Brudenell, David C. R. Hockless, and Anthony C. Willis pp 401 - 409; DOI: 10.1021/ic0400888 |
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Carbon-Halogen Bond Activation Mechanism by Copper(I) Complexes of (2-Pyridyl)alkylamine Ligands Takao Osako, Kenneth D. Karlin, and Shinobu Itoh pp 410 - 415; DOI: 10.1021/ic048902e |
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Trigonal-Bipyramidal Tin(IV) Complexes Containing Tetradentate Tripodal Tristhiolatophosphine Ligands: Synthesis, Characterization, Crystal Structure, and Transmetalation Reactions Kerry A. (Fusie) Clark and T. Adrian George pp 416 - 422; DOI: 10.1021/ic049328+ |
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Short-Range Structure and Cation Bonding in Calcium-Aluminum Metaphosphate Glasses J. Schneider, S. L. Oliveira, L. A. O. Nunes, F. Bonk, and H. Panepucci pp 423 - 430; DOI: 10.1021/ic0499704 |
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"Venetian Blinds" Mechanism of Solvation/Desolvation in Palladium(II) Wheel-and-Axle Organic-Inorganic Diols Alessia Bacchi, Elsa Bosetti, Mauro Carcelli, Paolo Pelagatti, Dominga Rogolino, and Giancarlo Pelizzi pp 431 - 442; DOI: 10.1021/ic048896m |
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Experimental and Theoretical Investigations of Tellurium(IV) Diimides and Imidotelluroxanes: X-ray Structures of B(C6F5)3 Adducts of OTe(-NtBu)2TeNtBu, [OTe(-NtBu)2Te(-O)]2 and tBuNH2 Gabriele Schatte, Tristram Chivers, Heikki M. Tuononen, Reijo Suontamo, Risto Laitinen, and Jussi Valkonen pp 443 - 451; DOI: 10.1021/ic048565+ |
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Facile C-H Bond Activation: Synthesis of the N4C Donor Set Pentadentate Ligand 1,4-Bis(2-pyridylmethyl)-1,4-diazacyclononane (dmpdacn) and a Structural Study of Its Alkyl-Cobalt(III) Complex [Co(dmpdacn-C)(OH2)](ClO4)2·H2O and Its Hydroxylated Derivative [Co(dmpdacnOH-O)Cl](ClO4)2·C3H6O Xiangting Zhou, Anthony I. Day, Alison J. Edwards, Anthony C. Willis, and W. Gregory Jackson pp 452 - 460; DOI: 10.1021/ic040081q |
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Synthesis and Molecular Structure of the First Rhodium(I) Complex Containing a Tetra-tert-butylcyclopentaphosphanide Ligand Andrea Schisler, Peter Lönnecke, and Evamarie Hey-Hawkins pp 461 - 464; DOI: 10.1021/ic048844x |
Issue 3
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Eight-Vertex Tetrametallic Structures Derived from Cubanes: A Close Relationship between Bisdisphenoidal Metallaborane and Organometallic Clusters R. Bruce King pp 466 - 467; DOI: 10.1021/ic0485357 |
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Azide Addition To Give a Tetra-azazirconacycle Complex Alan F. Heyduk, Karen J. Blackmore, Nicole A. Ketterer, and Joseph W. Ziller pp 468 - 470; DOI: 10.1021/ic048560c |
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Green Photoluminescence from Platinum(II) Complexes Bearing Silylacetylide Ligands Fei Hua, Solen Kinayyigit, John R. Cable, and Felix N. Castellano pp 471 - 473; DOI: 10.1021/ic048498j |
Iron Coordination Chemistry of Phenylpyruvate: An Unexpected  3-Bridging Mode That Leads to Oxidative Cleavage of the C2-C3 BondTapan K. Paine, Hui Zheng, and Lawrence Que, Jr. pp 474 - 476; DOI: 10.1021/ic048427k |
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NaSn2: A Novel Binary Zintl Phase with 2D Polyanions of Realgar-Type Units [Sn8]4- Franck Dubois, Martin Schreyer, and Thomas F. Fässler pp 477 - 479; DOI: 10.1021/ic048770p |
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An Unprecedented Tetranuclear Niobium Aqua Ion with a Capping 4-Sulfido Ligand Bee-Lean Ooi, Inger S  tofte, Maja F. Bendtsen, Astrid Munch, Loa C. Nielsen, and Jonas Henriksenpp 480 - 482; DOI: 10.1021/ic048659j |
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Platination of Nucleobases To Enhance Noncovalent Recognition in Protein-DNA/RNA Complexes Atilio I. Anzellotti, Erin S. Ma, and Nicholas Farrell pp 483 - 485; DOI: 10.1021/ic049086d |
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Heterometallic Metal-Organic Frameworks Based on Tris(dipyrrinato) Coordination Complexes Sara R. Halper and Seth M. Cohen pp 486 - 488; DOI: 10.1021/ic048289z |
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Catalysis by Methyltrioxorhenium(VII): Reduction of Hydronium Ions by Europium(II) and Reduction of Perchlorate Ions by Europium(II) and Chromium(II) Yang Cai and James H. Espenson pp 489 - 495; DOI: 10.1021/ic048669k |
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Binuclear Ruthenium Macrocycles Formed via the Weak-Link Approach Meisa S. Khoshbin, Maxim V. Ovchinnikov, Chad A. Mirkin, Lev N. Zakharov, and Arnold L. Rheingold pp 496 - 501; DOI: 10.1021/ic048975y |
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Single-Molecule Magnets: Structure and Properties of [Mn18O14(O2CMe)18(hep)4(hepH)2(H2O)2](ClO4)2 with Spin S = 13 E. K. Brechin, E. C. Sañudo, W. Wernsdorfer, C. Boskovic, J. Yoo, D. N. Hendrickson, A. Yamaguchi, H. Ishimoto, T. E. Concolino, A. L. Rheingold, and G. Christou pp 502 - 511; DOI: 10.1021/ic048857a |
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Mg35Cu24Ga53: A Three-Dimensional Cubic Network Composed of Interconnected Cu6Ga6 Icosahedra, Mg-Centered Ga16 Icosioctahedra, and a Magnesium Lattice Qisheng Lin and John D. Corbett pp 512 - 518; DOI: 10.1021/ic040075u |
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Structural Variety and Magnetic Properties of Tetranuclear Nickel(II) Complexes with a Central 4-Azide Serhiy Demeshko, Guido Leibeling, Walter Maringgele, Franc Meyer, Christopher Mennerich, Hans-Henning Klauss, and Hans Pritzkow pp 519 - 528; DOI: 10.1021/ic049251p |
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Visible and Near-Infrared Intense Luminescence from Water-Soluble Lanthanide [Tb(III), Eu(III), Sm(III), Dy(III), Pr(III), Ho(III), Yb(III), Nd(III), Er(III)] Complexes Silvio Quici, Marco Cavazzini, Giovanni Marzanni, Gianluca Accorsi, Nicola Armaroli, Barbara Ventura, and Francesco Barigelletti pp 529 - 537; DOI: 10.1021/ic0486466 |
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Diversification of Hydrothermal Reaction Products Induced by Naphthalene Molecules Eun Young Choi and Young-Uk Kwon pp 538 - 545; DOI: 10.1021/ic049030j |
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[BDTA]2[Cu(mnt)2]: An Almost Perfect One-Dimensional Magnetic Material Sarah S. Staniland, Wataru Fujita, Yoshikatsu Umezono, Kunio Awaga, Philip J. Camp, Stewart J. Clark, and Neil Robertson pp 546 - 551; DOI: 10.1021/ic048479+ |
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New Zinc Phosphates Decorated by Imidazole-Containing Ligands Jian Fan, Carla Slebodnick, Ross Angel, and Brian E. Hanson pp 552 - 558; DOI: 10.1021/ic0487528 |
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Controlled Aggregation of Heterometallic Nanoscale Cu12Ln6 Clusters (Ln = GdIII or NdIII) into 2D Coordination Polymers Feng He, Ming-Liang Tong, Xiao-Lan Yu, and Xiao-Ming Chen pp 559 - 565; DOI: 10.1021/ic048754s |
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New Types of Metal Squarato-phosphonates: Condensation of Aminodiphosphonate with Squaric Acid under Hydrothermal Conditions Bing-Ping Yang and Jiang-Gao Mao pp 566 - 571; DOI: 10.1021/ic048685h |
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Formate-The Analogue of Azide: Structural and Magnetic Properties of M(HCOO)2(4,4'-bpy)·nH2O (M = Mn, Co, Ni; n = 0, 5) Xin-Yi Wang, Hai-Yan Wei, Zhe-Ming Wang, Zhi-Da Chen, and Song Gao pp 572 - 583; DOI: 10.1021/ic049170t |
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Tris(dithiolene) Complexes of Neodymium and Cerium: Mononuclear Species, Chains, and Honeycomb Networks Mathieu Roger, Thérèse Arliguie, Pierre Thuéry, Marc Fourmigué, and Michel Ephritikhine pp 584 - 593; DOI: 10.1021/ic049055i |
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Homoleptic Tris(dithiolene) and Tetrakis(dithiolene) Complexes of Uranium(IV) Mathieu Roger, Thérèse Arliguie, Pierre Thuéry, Marc Fourmigué, and Michel Ephritikhine pp 594 - 600; DOI: 10.1021/ic049054q |
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Organoboron Compounds with an 8-Hydroxyquinolato Chelate and Its Derivatives: Substituent Effects on Structures and Luminescence Yi Cui, Qin-De Liu, Dong-Ren Bai, Wen-Li Jia, Ye Tao, and Suning Wang pp 601 - 609; DOI: 10.1021/ic0489746 |
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One-Dimensional BeH2 Polymers: Infrared Spectra and Theoretical Calculations Xuefeng Wang and Lester Andrews pp 610 - 614; DOI: 10.1021/ic048464b |
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Synthesis of Titanium(IV) Guanidinate Complexes and the Formation of Titanium Carbonitride via Low-Pressure Chemical Vapor Deposition Claire J. Carmalt, Anne C. Newport, Shane A. O'Neill, Ivan P. Parkin, Andrew J. P. White, and David J. Williams pp 615 - 619; DOI: 10.1021/ic049013u |
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Structural and Electronic Properties of Phosphino(oligothiophene) Gold(I) Complexes Tracey L. Stott, Michael O. Wolf, and Brian O. Patrick pp 620 - 627; DOI: 10.1021/ic0493200 |
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First Example of a 2:1 Cocrystal of Mixed Cu(I)/Cu(II) Complexes and a Novel Ferromagnetic Bis(-hydroxo)dicopper(II) Complex with a Bis(pyrazol-1-yl)methane Bidentate Ligand Chang-Chuan Chou, Chan-Cheng Su, Hui-Lien Tsai, and Kwang-Hwa Lii pp 628 - 632; DOI: 10.1021/ic048854y |
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Synthesis, Structure, and Magnetism of a 1D Compound Engineered from a Biradical [5,5'-Bis(3' '-oxide-1' '-oxyl-4' ',4' ',5' ',5' '-tetramethylimidazolin-2' '-yl)-2,2'-bipyridine] and MnII(hfac)2 Dominique Luneau, Christophe Stroh, Joan Cano, and Raymond Ziessel pp 633 - 637; DOI: 10.1021/ic049007y |
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Dramatic Variation of Magnetic Exchange through Double End-on Azide Bridges in a Series of Ladder-Like Copper(II) Coordination Polymers Jonathan D. Woodward, Rénal V. Backov, Khalil A. Abboud, D. Dai, H.-J. Koo, M.-H. Whangbo, Mark W. Meisel, and Daniel R. Talham pp 638 - 648; DOI: 10.1021/ic049175q |
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Inelastic Neutron Scattering Study of Electron Reduction in Mn12 Derivatives Reto Basler, Andreas Sieber, Grégory Chaboussant, Hans U. Güdel, Nicole E. Chakov, Monica Soler, George Christou, Arnaud Desmedt, and Ruep Lechner pp 649 - 653; DOI: 10.1021/ic048931p |
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An Open-Framework Rare-Earth Acetylenedicarboxylate: MIL-95, EuIII2(H2O)2(CO3)2·{O2C-C2-CO2}·{H2O}x Christian Serre, Jérôme Marrot, and Gérard Férey pp 654 - 657; DOI: 10.1021/ic0487373 |
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New Amine-Templated Zinc Phosphates with a Temperature-Induced Increase of Structural Dimensionality Torben R. Jensen, Nicolas Gérentes, Josua Jepsen, Rita G. Hazell, and Hans J. Jakobsen pp 658 - 665; DOI: 10.1021/ic049156g |
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Aerobic Oxidation of Formaldehyde Mediated by a Ce-Containing Polyoxometalate under Mild Conditions Oxana A. Kholdeeva, Maria N. Timofeeva, Gennadii M. Maksimov, Raisa I. Maksimovskaya, Wade A. Neiwert, and Craig L. Hill pp 666 - 672; DOI: 10.1021/ic049109o |
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A Cyclic Hexamer of Silver Trifluoroacetate Supported by Four Triphenylphosphine Sulfide Template Molecules Bratislav Djordjevic, Oliver Schuster, and Hubert Schmidbaur pp 673 - 676; DOI: 10.1021/ic048795o |
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Tetramanganese(II) Cluster with Centered Trigonal Topology: Structure and Magnetic Properties En-Qing Gao, Shi-Qiang Bai, Zheng He, and Chun-Hua Yan pp 677 - 682; DOI: 10.1021/ic048699n |
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Syntheses and Characterization of Dicarbonyl-Nitrosyl Complexes of Technetium(I) and Rhenium(I) in Aqueous Media: Spectroscopic, Structural, and DFT Analyses Roger Schibli, Niklaus Marti, Patrick Maurer, Bernhard Spingler, Marie-Line Lehaire, Volker Gramlich, and Charles L. Barnes pp 683 - 690; DOI: 10.1021/ic049599k |
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Copper(II) Complexes of a Series of Polypyridine Ligands Possessing a 1,2-Bis(2-pyridyl)ethane Common Moiety: Incorporation and Hydrolysis of Phosphate Esters Motoharu Itoh, Jun Nakazawa, Kunihiro Maeda, Koji Kano, Tadashi Mizutani, and Masahito Kodera pp 691 - 702; DOI: 10.1021/ic049240w |
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Family of Mixed-Valence Oxovanadium(IV/V) Dinuclear Entities Incorporating N4O3-Coordinating Heptadentate Ligands: Synthesis, Structure, and EPR Spectra Amrita Mondal, Sumana Sarkar, Deepak Chopra, T. N. Guru Row, Kausikisankar Pramanik, and Kajal Krishna Rajak pp 703 - 708; DOI: 10.1021/ic048919x |
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Synthesis, Crystal Structure, and Magnetic Properties of Oxime-Bridged Polynuclear Ni(II) and Cu(II) Complexes Yun-Bo Jiang, Hui-Zhong Kou, Ru-Ji Wang, Ai-Li Cui, and Joan Ribas pp 709 - 715; DOI: 10.1021/ic048729m |
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Reactivity of Organolanthanide and Organolithium Complexes Containing the Guanidinate Ligands toward Isocyanate or Carbodiimide: Synthesis and Crystal Structures Jie Zhang, Xigeng Zhou, Ruifang Cai, and Linhong Weng pp 716 - 722; DOI: 10.1021/ic048683x |
Issue 4
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Preface Forum: "Functional Insight from Physical Methods on Metalloenzymes" Edward I. Solomon pp 723 - 726; DOI: 10.1021/ic040127f |
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Spectroscopic Approaches to Elucidating Novel Iron-Sulfur Chemistry in the "Radical-SAM" Protein Superfamily Charles J. Walsby, Danilo Ortillo, Jian Yang, Mbako R. Nnyepi, William E. Broderick, Brian M. Hoffman, and Joan B. Broderick pp 727 - 741; DOI: 10.1021/ic0484811 |
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Rapid Freeze-Quench 57Fe Mössbauer Spectroscopy: Monitoring Changes of an Iron-Containing Active Site during a Biochemical Reaction Carsten Krebs, John C. Price, Jeffrey Baldwin, Lana Saleh, Michael T. Green, and J. Martin Bollinger, Jr. pp 742 - 757; DOI: 10.1021/ic048523l |
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Resonance Raman Investigation of the Specific Sensing Mechanism of a Target Molecule by Gas Sensory Proteins Takehiro Ohta and Teizo Kitagawa pp 758 - 769; DOI: 10.1021/ic0486318 |
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X-ray Crystallography and Biological Metal Centers: Is Seeing Believing? Monika Sommerhalter, Raquel L. Lieberman, and Amy C. Rosenzweig pp 770 - 778; DOI: 10.1021/ic0485256 |
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Paramagnetic NMR Spectroscopy and Density Functional Calculations in the Analysis of the Geometric and Electronic Structures of Iron-Sulfur Proteins Timothy E. Machonkin, William M. Westler, and John L. Markley pp 779 - 797; DOI: 10.1021/ic048624j |
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Investigating Metalloenzyme Reactions Using Electrochemical Sweeps and Steps: Fine Control and Measurements with Reactants Ranging from Ions to Gases Kylie A. Vincent and Fraser A. Armstrong pp 798 - 809; DOI: 10.1021/ic048519+ |
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Flexible Eightfold Interpenetrating Diamondoid Network Generating 1D Channels: Selective Binding with Organic Guests Hyunji Kim and Myunghyun Paik Suh pp 810 - 812; DOI: 10.1021/ic048869w |
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Uranyl-Peptide Interactions in Carbonate Solution with DAHK and Derivatives Huan Huang, Shveta Chaudhary, and J. David Van Horn pp 813 - 815; DOI: 10.1021/ic049528l |
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An Infinite Water Chain Passes through an Array of Zn(II) Metallocycles Built with a Podand Bearing Terminal Carboxylates Subhadip Neogi and Parimal K. Bharadwaj pp 816 - 818; DOI: 10.1021/ic048489a |
The First Example of Solvothermally Synthesized Thioantimonates(V) with Ethylenediamine Coordinated Lanthanide(III): [Sm(en)4]SbS4·0.5en and [Sm(en)3(H2O)(-SbS4)] Ding-xian Jia, Qin-Yu Zhu, Jie Dai, Wen Lu, and Wen-Juan Guo pp 819 - 821; DOI: 10.1021/ic0484957 |
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Ditopic Macropolycyclic Complexes: Synthesis of Hybrid Phthalocyaninoclathrochelates Yan Z. Voloshin, Oleg A. Varzatskii, Sergey V. Korobko, Viktor Y. Chernii, Sergey V. Volkov, Larisa A. Tomachynski, Vasilii I. Pehn'o, Mikhail Yu. Antipin, and Zoya A. Starikova pp 822 - 824; DOI: 10.1021/ic048189t |
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Photocleavage of Lysozyme by Cobalt(III) Complexes Challa V. Kumar and Jyotsna Thota pp 825 - 827; DOI: 10.1021/ic0488233 |
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A Zinc Carboxylate Network Containing Metal Sites with Low Coordination Numbers Diane A. Dickie, Michael C. Jennings, Hilary A. Jenkins, and Jason A. C. Clyburne pp 828 - 830; DOI: 10.1021/ic048443h |
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Anions or Cations: Who Is in Charge of Inhibiting the Nickel(II) Promoted B- to Z-DNA Transition? Bernhard Spingler pp 831 - 833; DOI: 10.1021/ic048760o |
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Mono- and Dinuclear Tricarbonyltechnetium(I) Complexes with Thiosemicarbazones Gumersindo Pereiras-Gabián, Ezequiel M. Vázquez-López, Henrik Braband, and Ulrich Abram pp 834 - 836; DOI: 10.1021/ic0483038 |
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Assembly of Hydrogen Bonded Diamondoid Networks Based on Synthetic Metal-Organic Tetrahedral Nodes Bao-Qing Ma, Hao-Ling Sun, and Song Gao pp 837 - 839; DOI: 10.1021/ic048648q |
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Structure and Emission Properties of Er3Q9 (Q = 8-Quinolinolate) Flavia Artizzu, Paola Deplano, Luciano Marchiò, Maria Laura Mercuri, Luca Pilia, Angela Serpe, Francesco Quochi, Riccardo Orrù, Fabrizio Cordella, Francesco Meinardi, Riccardo Tubino, Andrea Mura, and Giovanni Bongiovanni pp 840 - 842; DOI: 10.1021/ic0483895 |
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Violation of the Isolated Square Rule for Group 13-15 Oligomers: Theoretical Prediction of a New Class of Inorganic Polymers Alexey Y. Timoshkin and Henry F. Schaefer III pp 843 - 845; DOI: 10.1021/ic048468g |
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The First Nitro-Substituted Heteroscorpionate Ligand Maura Pellei, Franco Benetollo, Giancarlo Gioia Lobbia, Simone Alidori, and Carlo Santini pp 846 - 848; DOI: 10.1021/ic048562x |
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Tuning of Luminescence Spectra of Neutral Ruthenium(II) Complexes by Crystal Waters Taichi Abe and Kazuteru Shinozaki pp 849 - 851; DOI: 10.1021/ic049169u |
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Uranyl Complexation in Fluorinated Acids (HF, HBF4, HPF6, HTf2N): A Combined Experimental and Theoretical Study Clotilde Gaillard, Antoine El Azzi, Isabelle Billard, Hélène Bolvin, and Christoph Hennig pp 852 - 861; DOI: 10.1021/ic0490324 |
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Coordination Polymers Based on Inorganic Lanthanide(III) Sulfate Skeletons and an Organic Isonicotinate N-oxide Connector: Segregation into Three Structural Types by the Lanthanide Contraction Effect Zheng He, En-Qing Gao, Zhe-Ming Wang, Chun-Hua Yan, and Mohamedally Kurmoo pp 862 - 874; DOI: 10.1021/ic0487575 |
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N2S2Ni Metallodithiolate Complexes as Ligands: Structural and Aqueous Solution Quantitative Studies of the Ability of Metal Ions to Form M-S-Ni Bridges to Mercapto Groups Coordinated to Nickel(II). Implications for Acetyl Coenzyme A Synthase Melissa L. Golden, Curtis M. Whaley, Marilyn V. Rampersad, Joseph H. Reibenspies, Robert D. Hancock, and Marcetta Y. Darensbourg pp 875 - 883; DOI: 10.1021/ic0489701 |
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Examining the Out-of-Center Distortion in the [NbOF5]2- Anion Heather K. Izumi, Janet E. Kirsch, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 884 - 895; DOI: 10.1021/ic048766d |
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Structure, Electrochemistry, and Magnetism of the Iron(III)-Substituted Keggin Dimer, [Fe6(OH)3(A--GeW9O34(OH)3)2]11- Li-Hua Bi, Ulrich Kortz, Saritha Nellutla, Ashley C. Stowe, Johan van Tol, Naresh S. Dalal, Bineta Keita, and Louis Nadjo pp 896 - 903; DOI: 10.1021/ic048713w |
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Cytochrome c-Crown Ether Complexes as Supramolecular Catalysts: Cold-Active Synzymes for Asymmetric Sulfoxide Oxidation in Methanol Atsuko Suzumura, Dharam Paul, Hideki Sugimoto, Satoshi Shinoda, Ryan R. Julian, J. L. Beauchamp, Junji Teraoka, and Hiroshi Tsukube pp 904 - 910; DOI: 10.1021/ic0486567 |
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Systematic Investigation of the Hydrothermal Syntheses of Pr(III)-PDA (PDA = Pyridine-2,6-dicarboxylate Anion) Metal-Organic Frameworks Bin Zhao, Long Yi, Yan Dai, Xiao-Yan Chen, Peng Cheng, Dai-Zheng Liao, Shi-Ping Yan, and Zong-Hui Jiang pp 911 - 920; DOI: 10.1021/ic049498m |
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Hydrolytic Protein Cleavage Mediated by Unusual Mononuclear Copper(II) Complexes: X-ray Structures and Solution Studies Mauricio C. B. de Oliveira, Marciela Scarpellini, Ademir Neves, Hernán Terenzi, Adailton J. Bortoluzzi, Bruno Szpoganics, Alessandra Greatti, Antônio S. Mangrich, Emanuel M. de Souza, Pablo M. Fernandez, and Marcia R. Soares pp 921 - 929; DOI: 10.1021/ic0485864 |
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Pentanuclear Ba(II) Complex of a Macrocyclic Ligand Alberto Freiría, Rufina Bastida, Ma del Carmen Fernández-Fernández, Alejandro Macías, Laura Valencia, and Manuel Vicente pp 930 - 934; DOI: 10.1021/ic048704n |
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K5(UO2)2[Si4O12(OH)]: A Uranyl Silicate Containing Chains of Four Silicate Tetrahedra Linked by SiO···HOSi Hydrogen Bonds Chih-Shan Chen, Hsien-Ming Kao, and Kwang-Hwa Lii pp 935 - 940; DOI: 10.1021/ic0487880 |
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Kinetics and Mechanism of Hydrolysis of a Model Phosphate Diester by [Cu(Me3tacn)(OH2)2]2+ (Me3tacn = 1,4,7-Trimethyl-1,4,7-triazacyclononane) Fiona H. Fry, Adam J. Fischmann, Matthew J. Belousoff, Leone Spiccia, and Joel Brügger pp 941 - 950; DOI: 10.1021/ic049469b |
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Single-Source Approach to Cubic FeS2 Crystallites and Their Optical and Electrochemical Properties Xiangying Chen, Zhenghua Wang, Xiong Wang, Junxi Wan, Jianwei Liu, and Yitai Qian pp 951 - 954; DOI: 10.1021/ic049049m |
Di([5]trovacenyl)ethyne, Di([5]trovacenyl)butadiyne, and Di-1,4-([5]trovacenylethynyl)benzene: Electrocommunication and Magnetocommunication Mediated by -C C-, -CC-CC- and -CC-C6H4-CC- SpacersChristoph Elschenbroich, Jörn Plackmeyer, Mathias Nowotny, Klaus Harms, Jürgen Pebler, and Olaf Burghaus pp 955 - 963; DOI: 10.1021/ic040090z |
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Effect of Crystal Packing on the Structures of Polymeric Metallocenes R. E. Dinnebier, Sander van Smaalen, F. Olbrich, and S. Carlson pp 964 - 968; DOI: 10.1021/ic049214y |
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Cyano-Bridged Structures Based on [MnII(N3O2-Macrocycle)]2+: A Synthetic, Structural, and Magnetic Study Federica Bonadio, Maria-Cristina Senna, Jürgen Ensling, Andreas Sieber, Antonia Neels, Helen Stoeckli-Evans, and Silvio Decurtins pp 969 - 978; DOI: 10.1021/ic049209u |
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Formation of CH3TiX, CH2=TiHX, and (CH3)2TiX2 by Reaction of Methyl Chloride and Bromide with Laser-Ablated Titanium Atoms: Photoreversible -Hydrogen Migration Han-Gook Cho and Lester Andrews pp 979 - 988; DOI: 10.1021/ic048615a |
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Cu(HCO2)2(pym) (pym = pyrimidine): Low-Dimensional Magnetic Behavior and Long-Range Ordering in a Quantum-Spin Lattice J. L. Manson, T. Lancaster, L. C. Chapon, S. J. Blundell, J. A. Schlueter, M. L. Brooks, F. L. Pratt, C. L. Nygren, and J. S. Qualls pp 989 - 995; DOI: 10.1021/ic048723x |
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Anion-Dependent Silver(I) Coordination Polymers of the Tridentate Pyridylphosphonite: PPh(3-OCH2C5H4N)2 Rodney P. Feazell, Cody E. Carson, and Kevin K. Klausmeyer pp 996 - 1005; DOI: 10.1021/ic0486365 |
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Thermodynamic Profiles for CO Photodissociation from Heme Model Compounds: Effect of Proximal Ligands Jaroslava Mik  ovská, Jeni Norstrom, and Randy W. Larsenpp 1006 - 1014; DOI: 10.1021/ic048963c |
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Tetracyanoborate Salts M[B(CN)4] with M = Singly Charged Cations: Properties and Structures Torsten Küppers, Eduard Bernhardt, Helge Willner, Henning W. Rohm, and Martin Köckerling pp 1015 - 1022; DOI: 10.1021/ic048780q |
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Formation of Hypervalent Complexes of Trifluorosilanes with Pyridine and with 4-Methoxypyridine, through Intermolecular Silicon···Nitrogen Interactions Moshe Nakash, Dalia Gut, and Michael Goldvaser pp 1023 - 1030; DOI: 10.1021/ic048664n |
Silver(I) Coordination Polymers of Fluorescent Oligo(phenylenevinylene) with  - Stackings: Luminescence and ConductivityShu Qin Liu, Takayoshi Kuroda-Sowa, Hisashi Konaka, Yusaku Suenaga, Masahiko Maekawa, Tomonari Mizutani, Gui Ling Ning, and Megumu Munakata pp 1031 - 1036; DOI: 10.1021/ic0400585 |
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Syntheses and Characterization of Oxo-Centered Triruthenium Compounds with Orthometalated Bipyridine Jing-Lin Chen, Xu-Dong Zhang, Li-Yi Zhang, Lin-Xi Shi, and Zhong-Ning Chen pp 1037 - 1043; DOI: 10.1021/ic048681c |
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Chromium(V) Peptide Complexes: Synthesis and Spectroscopic Characterization Peter J. Barnard, Aviva Levina, and Peter A. Lay pp 1044 - 1053; DOI: 10.1021/ic048322h |
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Rhenium Chemistry of Azooximes: Oxygen Atom Transfer, Azoimine Chelation, and Imine-Oxime Contrast Indranil Chakraborty, Bikash Kumar Panda, Jaydip Gangopadhyay, and Animesh Chakravorty pp 1054 - 1060; DOI: 10.1021/ic0486116 |
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Cations M2(O2CtBu)4+, Where M = Mo and W, and MoW(O2CtBu)4+. Theoretical, Spectroscopic, and Structural Investigations Malcolm H. Chisholm, Jason S. D'Acchioli, Brian D. Pate, Nathan J. Patmore, Naresh S. Dalal, and David J. Zipse pp 1061 - 1067; DOI: 10.1021/ic049081g |
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Reaction Systems Related to Dissimilatory Nitrate Reductase: Nitrate Reduction Mediated by Bis(dithiolene)tungsten Complexes Jianfeng Jiang and R. H. Holm pp 1068 - 1072; DOI: 10.1021/ic040109y |
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Conducting Polymers Containing In-Chain Metal Centers: Electropolymerization of Oligothienyl-Substituted {M(tpy)2} Complexes and in Situ Conductivity Studies, M = Os(II), Ru(II) Johan Hjelm, Robyn W. Handel, Anders Hagfeldt, Edwin C. Constable, Catherine E. Housecroft, and Robert J. Forster pp 1073 - 1081; DOI: 10.1021/ic049221m |
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Interaction of Molybdocene Dichloride with Cysteine-Containing Peptides: Coordination, Regioselective Hydrolysis, and Intramolecular Aminolysis Andrea Erxleben pp 1082 - 1094; DOI: 10.1021/ic048824v |
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Hydride Affinities of Borane Derivatives: Novel Approach in Determining the Origin of Lewis Acidity Based on Triadic Formula Robert Vianello and Zvonimir B. Maksi  pp 1095 - 1102; DOI: 10.1021/ic048647y |
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Studies Relevant to Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Triamidoamine Complexes Dmitry V. Yandulov and Richard R. Schrock pp 1103 - 1117; DOI: 10.1021/ic040095w |
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Utilization of CS2 as a Source of C1 Synthetic Units for the Preparation of Bis(alkylthio)methanes and Alkyl Dithioformates Thirumanavelan Gandhi and Balaji R. Jagirdar pp 1118 - 1124; DOI: 10.1021/ic048849u |
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Disilver(I) Macrocycles: Variation of Cavity Size with Anion Binding Nancy L. S. Yue, Michael C. Jennings, and Richard J. Puddephatt pp 1125 - 1131; DOI: 10.1021/ic048549c |
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Preparation and Properties of the Full Series of Cuboidal Clusters [MoxW4-xSe4(H2O)12]n+ (n = 4-6) and Their Derivatives M. Sokolov, P. Esparza, R. Hernandez-Molina, J. G. Platas, A. Mederos, J. A. Gavin, R. Llusar, and C. Vicent pp 1132 - 1141; DOI: 10.1021/ic049298a |
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New Efficient Synthesis of [UI4(MeCN)4]. X-ray Crystal Structures of [UI2(MeCN)7][UI6], [UI4(py)3], and [U(dmf)9]I4 Jean-Claude Berthet, Pierre Thuéry, and Michel Ephritikhine pp 1142 - 1146; DOI: 10.1021/ic048603p |
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Synthesis and X-ray Crystal Structure of a Cationic Homoleptic (SPS)2Rh(III) Complex and EPR Study of Its Reduction Process Marjolaine Doux, Nicolas Mézailles, Louis Ricard, Pascal Le Floch, Prashant Adkine, Théo Berclaz, and Michel Geoffroy pp 1147 - 1152; DOI: 10.1021/ic049046+ |
Issue 5
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Antitumor Metallothiosemicarbazonates: Structure and Antitumor Activity of Palladium Complex of Phenanthrenequinone Thiosemicarbazone Subhash Padhye, Zahra Afrasiabi, Ekk Sinn, Jansina Fok, Kapil Mehta, and Nigam Rath pp 1154 - 1156; DOI: 10.1021/ic048214v |
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Synthesis and Characterization of Phenanthrylphosphine Gold Complex: Observation of Au-Induced Blue-Green Phosphorescence at Room Temperature Masahisa Osawa, Mikio Hoshino, Munetaka Akita, and Tatsuo Wada pp 1157 - 1159; DOI: 10.1021/ic048538j |
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Both Nucleophile and Substrate Bind to the Catalytic Fe(II)-Center in the Type-II Methionyl Aminopeptidase from Pyrococcus furiosus Alicja J. Copik, Sarah Waterson, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz pp 1160 - 1162; DOI: 10.1021/ic0487934 |
Unsupported Gold(I)-Copper(I) Interactions through  1Au-[Au(C6F5)2]- Coordination to Cu+ Lewis Acid SitesEduardo J. Fernández, Antonio Laguna, José M. López-de-Luzuriaga, Miguel Monge, Manuel Montiel, and M. Elena Olmos pp 1163 - 1165; DOI: 10.1021/ic048346o |
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(C4N3H15)[(BO2)2(GeO2)4]: The First Organically Templated 3D Borogermanate Showing 1D 12-Rings, Large Channels, and a Novel Zeolite-type Framework Topology Constructed from Ge8O24 and B2O7 Cluster Units Hong-Xia Zhang, Jie Zhang, Shou-Tian Zheng, and Guo-Yu Yang pp 1166 - 1168; DOI: 10.1021/ic048658r |
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Role of Protons in Superoxide Reduction by a Superoxide Reductase Analogue Roslyn M. Theisen and Julie A. Kovacs pp 1169 - 1171; DOI: 10.1021/ic048818z |
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Amide-Ligand Hydrogen Bonding in Reverse Micelles Marc A. Walters, Pamela M. Tadross, Arnold L. Rheingold, Lev N. Zakharov, Danai Mudzudzu, and John Texter pp 1172 - 1174; DOI: 10.1021/ic050033l |
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Transformation of Inorganic Sulfur into Organic Sulfur: A Novel Photoluminescent 3-D Polymeric Complex Involving Ligands in Situ Formation Dan Li and Tao Wu pp 1175 - 1177; DOI: 10.1021/ic0484856 |
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Self-Assembly of Homochiral Porous Solids Based on 1D Cadmium(II) Coordination Polymers Chuan-De Wu and Wenbin Lin pp 1178 - 1180; DOI: 10.1021/ic048671b |
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Rational Assembly of Primitive Cubic Networks Using Hexameric Stacks of Sodium Aryloxides as Nodes Dugald J. MacDougall, Bruce C. Noll, and Kenneth W. Henderson pp 1181 - 1183; DOI: 10.1021/ic048257b |
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Ferromagnetic Ordering of Fe(III) d Spins of FeBr4- Ions in (Ethylenedithiotetrathiafulvalenothioquinone-ethylenedithio-1,3-dithiolemethide)·FeBr4 Mingxing Wang, Hideki Fujiwara, Toyonari Sugimoto, Satoru Noguchi, and Takekazu Ishida pp 1184 - 1186; DOI: 10.1021/ic0482988 |
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Dinitrogen Partial Reduction by Formally Zero- and Divalent Vanadium Complexes Supported by the Bis-iminopyridine System Indu Vidyaratne, Sandro Gambarotta, Ilia Korobkov, and Peter H. M. Budzelaar pp 1187 - 1189; DOI: 10.1021/ic048358+ |
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pH-Dependent Assembly of Keggin-Based Supramolecular Architecture Pei-Qing Zheng, Yan-Ping Ren, La-Sheng Long, Rong-Bin Huang, and Lan-Sun Zheng pp 1190 - 1192; DOI: 10.1021/ic048708s |
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Control of Iron(III) Spin-State in the Model Complexes of Azide Hemoprotein by Porphycene, Corrphycene, and Hemiporphycene Macrocycles Saburo Neya, C. K. Chang, Daichi Okuno, Tyuji Hoshino, Masayuki Hata, and Noriaki Funasaki pp 1193 - 1195; DOI: 10.1021/ic048353c |
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Unique Cooperative Binding Interaction Observed between a Minor Groove Binding Pt Antitumor Agent and Hoeschst Dye 33258 Amanda Harris, Yun Qu, and Nicholas Farrell pp 1196 - 1198; DOI: 10.1021/ic048356p |
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Reaction of LAlH2 with tert-Butyl Hydrogenperoxide under C-H Bond Activation and Substitution Leads to the Formation of a Pentacoordinated tert-Butylperoxo Aluminum Compound S. Shravan Kumar, Sanjay Singh, Herbert W. Roesky, and Jörg Magull pp 1199 - 1201; DOI: 10.1021/ic048336n |
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Electronic Structure and Intrinsic Redox Properties of [2Fe-2S]+ Clusters with Tri- and Tetracoordinate Iron Sites You-Jun Fu, Shuqiang Niu, Toshiko Ichiye, and Lai-Sheng Wang pp 1202 - 1204; DOI: 10.1021/ic048559d |
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Novel Thiosalamo Ligand as a Remarkably Stable N2S2 Salen-Type Chelate and Synthesis of a Nickel(II) Complex Shigehisa Akine and Tatsuya Nabeshima pp 1205 - 1207; DOI: 10.1021/ic048347g |
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Antiferromagnetic FeIII6 Ring and Single-Molecule Magnet MnII3MnIII4 Wheel Satoshi Koizumi, Masayuki Nihei, Motohiro Nakano, and Hiroki Oshio pp 1208 - 1210; DOI: 10.1021/ic0484203 |
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Luminescent Platinum(II) Dimers with a Cyclometallating Aryldiamine Ligand Hershel Jude, Jeanette A. Krause Bauer, and William B. Connick pp 1211 - 1220; DOI: 10.1021/ic049166h |
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X-ray Absorption Spectroscopic Investigation of the Spin-Transition Character in a Series of Single-Site Perturbed Iron(II) Complexes Deanne Jackson Rudd, Christian R. Goldsmith, Adam P. Cole, T. Daniel P. Stack, Keith O. Hodgson, and Britt Hedman pp 1221 - 1229; DOI: 10.1021/ic048765l |
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Synthesis and Characterization of a Porous Magnetic Diamond Framework, Co3(HCOO)6, and Its N2 Sorption Characteristic Zheming Wang, Bin Zhang, Mohamedally Kurmoo, Mark A. Green, Hideki Fujiwara, Takeo Otsuka, and Hayao Kobayashi pp 1230 - 1237; DOI: 10.1021/ic048986r |
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Dioxygen Reactivity of Copper and Heme-Copper Complexes Possessing an Imidazole-Phenol Cross-Link Eunsuk Kim, Kaliappan Kamaraj, Benedikt Galliker, Nick D. Rubie, Pierre Moënne-Loccoz, Susan Kaderli, Andreas D. Zuberbühler, and Kenneth D. Karlin pp 1238 - 1247; DOI: 10.1021/ic048907b |
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Structural Properties and Dissociative Fluxional Motion of 2,9-Dimethyl-1,10-Phenanthroline in Platinum(II) Complexes Raffaello Romeo, Salvatore Carnabuci, Maria Rosaria Plutino, Andrea Romeo, Silvia Rizzato, and Alberto Albinati pp 1248 - 1262; DOI: 10.1021/ic0485920 |
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Experimental and Theoretical Studies of Carbodiphosphorane-CX2 Adducts with Unusual Bonding Situations: Preparation, Crystal Structures, and Bonding Analyses of S2CC(PPh3)2, O2CC(PPh3)2, and [(CO)4MS2CC(PPh3)2] (M = Cr, Mo, W) Wolfgang Petz, Christian Kutschera, Maya Heitbaum, Gernot Frenking, Ralf Tonner, and Bernhard Neumüller pp 1263 - 1274; DOI: 10.1021/ic048397l |
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Cation-Directed Synthesis of Tungstosilicates. 2. Synthesis, Structure, and Characterization of the Open Wells-Dawson Anion -[{K(H2O)2}(Si2W18O66)]15- and Its Transiton-Metal Derivatives [{M(H2O)}(-H2O)2K(Si2W18O66)]13- and [{M(H2O)}(-H2O)2K{M(H2O)4}(Si2W18O66)]11- Nathalie Leclerc-Laronze, Jérôme Marrot, and Gilbert Hervé pp 1275 - 1281; DOI: 10.1021/ic0486769 |
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Iridium Cyclometalated Complexes with Axial Symmetry: Time-Dependent Density Functional Theory Investigation of trans-Bis-Cyclometalated Complexes Containing the Tridentate Ligand 2,6-Diphenylpyridine Matthew Polson, Marcella Ravaglia, Sandro Fracasso, Marco Garavelli, and Franco Scandola pp 1282 - 1289; DOI: 10.1021/ic049277g |
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Determination of the g-Tensors and Their Orientations for cis,trans-(L-N2S2)MoVOX (X = Cl, SCH2Ph) by Single-Crystal EPR Spectroscopy and Molecular Orbital Calculations Michele Mader Cosper, Frank Neese, Andrei V. Astashkin, Michael D. Carducci, Arnold M. Raitsimring, and John H. Enemark pp 1290 - 1301; DOI: 10.1021/ic0483850 |
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Structural Characterization of an Enantiopure Hydroxo-Bridged Binuclear Iron(III) Complex with Empty One-Dimensional Helical Channels Md. Akhtarul Alam, Munirathinum Nethaji, and Manabendra Ray pp 1302 - 1308; DOI: 10.1021/ic049145n |
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Cadmium Amido Alkoxide and Alkoxide Precursors for the Synthesis of Nanocrystalline CdE (E = S, Se, Te) Timothy J. Boyle, Scott D. Bunge, Todd M. Alam, Gregory P. Holland, Thomas J. Headley, and Gabriel Avilucea pp 1309 - 1318; DOI: 10.1021/ic0485155 |
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Redox Control of Light-Induced Charge Separation in a Transition Metal Cluster: Photochemistry of a Methyl Viologen-Substituted [Os3(CO)10(-diimine)] Cluster Frank W. Vergeer, Cornelis J. Kleverlaan, Pavel Matousek, Michael Towrie, Derk J. Stufkens, and Franti ek Hartlpp 1319 - 1331; DOI: 10.1021/ic049191n |
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Blue Luminescent 2-(2'-Pyridyl)benzimidazole Derivative Ligands and Their Orange Luminescent Mononuclear and Polynuclear Organoplatinum(II) Complexes Qin-De Liu, Wen-Li Jia, and Suning Wang pp 1332 - 1343; DOI: 10.1021/ic0487530 |
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Iridium(III) Complexes with Orthometalated Quinoxaline Ligands: Subtle Tuning of Emission to the Saturated Red Color Fu-Ming Hwang, Hsing-Yi Chen, Po-Shen Chen, Chao-Shiuan Liu, Yun Chi, Ching-Fong Shu, Fang-Iy Wu, Pi-Tai Chou, Shie-Ming Peng, and Gene-Hsiang Lee pp 1344 - 1353; DOI: 10.1021/ic0489443 |
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A New Bimetallic Intercalated 3-D Assembly Magnet [{(323)Ni}3{FeIII(CN)6}2]n·12nH2O (323 = N,N'-Bis(3-aminopropyl) Ethylenediamine): An Unprecedented Concomitant Presence of Meridional and Facial Arrangment of Ferricyanide Anion Manas K. Saha, María C. Morón, Fernando Palacio, and Ivan Bernal pp 1354 - 1361; DOI: 10.1021/ic048947f |
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Generation of a Plastic Crystal Including Methane Rotator within Metal-Organic Cavity by Forcible Gas Adsorption Satoshi Takamizawa, Ei-ichi Nakata, Teruo Saito, and Takamasa Akatsuka pp 1362 - 1366; DOI: 10.1021/ic048759p |
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Fe-N-O Structure and Bonding in Six-Coordinate {FeNO}6 Porphyrinates Containing Imidazole: Implications for Reactivity of Coordinated NO Douglas P. Linder and Kenton R. Rodgers pp 1367 - 1380; DOI: 10.1021/ic049045h |
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Atomic Silicon in Siloxanic Networks: The Nature of the Oxo-Oxygen-Silicon Bond P. Belanzoni, G. Giorgi, G. F. Cerofolini, and A. Sgamellotti pp 1381 - 1390; DOI: 10.1021/ic048927d |
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Synthesis and Structure of Pt(II) Phosphonato-Phosphine Complexes and of a P,O-Stabilized Metal-Metal-Bonded Pt2Ag2 Complex Nicola Oberbeckmann-Winter, Xavier Morise, Pierre Braunstein, and Richard Welter pp 1391 - 1403; DOI: 10.1021/ic0485559 |
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Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand Manuel Miguirditchian, Denis Guillaneux, Dominique Guillaumont, Philippe Moisy, Charles Madic, Mark P. Jensen, and Kenneth L. Nash pp 1404 - 1412; DOI: 10.1021/ic0488785 |
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High-Nuclearity Iridium Carbonyl Clusters Containing Phenylgermyl Ligands: Synthesis, Structures, and Reactivity Richard D. Adams, Burjor Captain, and Jack L. Smith, Jr. pp 1413 - 1420; DOI: 10.1021/ic0485108 |
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Selective Generation of Organic Aggregates Included within Metal-Organic Micropores through Vapor Adsorption Satoshi Takamizawa, Teruo Saito, Takamasa Akatsuka, and Ei-ichi Nakata pp 1421 - 1424; DOI: 10.1021/ic048351s |
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(salen)MnIII Compounds as Nonpeptidyl Mimics of Catalase. Mechanism-Based Tuning of Catalase Activity: A Theoretical Study Yuri G. Abashkin and Stanley K. Burt pp 1425 - 1432; DOI: 10.1021/ic048714o |
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Aluminum Salen Complexes and Tetrabutylammonium Salts: A Binary Catalytic System for Production of Polycarbonates from CO2 and Cyclohexene Oxide Donald J. Darensbourg and Damon R. Billodeaux pp 1433 - 1442; DOI: 10.1021/ic048508g |
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Hydrothermal Single-Crystal Growth in the Systems Ag/Hg/X/O (X = VV, AsV): Crystal Structures of (Ag3Hg)VO4, (Ag2Hg2)3(VO4)4, and (Ag2Hg2)2(HgO2)(AsO4)2 with the Unusual Tetrahedral Cluster Cations (Ag3Hg)3+ and (Ag2Hg2)4+ and Crystal Structure of AgHgVO4 Matthias Weil, Ekkehart Tillmanns, and Dmitry Yu. Pushcharovsky pp 1443 - 1451; DOI: 10.1021/ic0484912 |
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Metal Complexes of meso-Amino-octaethylporphyrin and the Oxidation of NiII(meso-amino-octaethylporphyrin) Natasza Sprutta, Sankar Prasad Rath, Marilyn M. Olmstead, and Alan L. Balch pp 1452 - 1459; DOI: 10.1021/ic0486623 |
High-Pressure Synthesis and Transport Properties of a New Binary Germanide, SrGe6- (  0.5), with a Cagelike StructureHiroshi Fukuoka, Shoji Yamanaka, Eiichi Matsuoka, and Toshiro Takabatake pp 1460 - 1465; DOI: 10.1021/ic0485615 |
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A Theoretical Study on the Mechanism of the Reductive Half-Reaction of Xanthine Oxidase Xin-Hao Zhang and Yun-Dong Wu pp 1466 - 1471; DOI: 10.1021/ic048730l |
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Structure, Spectroscopic Properties, and Reversible Solid-to-Solid Reactions of Metal Complexes of 5-Nitro-pyrimidin-2-olate Elisa Barea, M. Angustias Romero, Jorge A. R. Navarro, Juan M. Salas, Norberto Masciocchi, Simona Galli, and Angelo Sironi pp 1472 - 1481; DOI: 10.1021/ic048539b |
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Interactions of Rh(III)-Dihydrido-Bis(phosphine) Complexes with Semicarbazones Maria B. Ezhova, Brian O. Patrick, Kapila N. Sereviratne, Brian R. James, Francis J. Waller, and Michael E. Ford pp 1482 - 1491; DOI: 10.1021/ic0489185 |
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Functionalized Platinum(II) Terpyridyl Alkynyl Complexes as Colorimetric and Luminescence pH Sensors Keith Man-Chung Wong, Wing-Suen Tang, Xiao-Xia Lu, Nianyong Zhu, and Vivian Wing-Wah Yam pp 1492 - 1498; DOI: 10.1021/ic049079p |
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First Example of Low-Valence Ion Substitution in Ln5O(OPri)13: Mixed-Valence Europium Oxoalkoxide [EuIII4EuIIO(OPri)12(HOPri)]*HOPri Marat Moustiakimov, Mikael Kritikos, and Gunnar Westin pp 1499 - 1504; DOI: 10.1021/ic048575a |
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Deprotonation Reactions of Zirconium and Hafnium Amide Complexes H2N-M[N(SiMe3)2]3 and Subsequent Silyl Migration from Amide -N(SiMe3)2 to Imide =NH Ligands Xianghua Yu and Zi-Ling Xue pp 1505 - 1510; DOI: 10.1021/ic0485413 |
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Structural Variations and Spectroscopic Properties of Luminescent Mono- and Multinuclear Silver(I) and Copper(I) Complexes Bearing Phosphine and Cyanide Ligands Yong-Yue Lin, Siu-Wai Lai, Chi-Ming Che, Wen-Fu Fu, Zhong-Yuan Zhou, and Nianyong Zhu pp 1511 - 1524; DOI: 10.1021/ic048876k |
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XeF2 as a Ligand in a Coordination Compound with the BF4- Anion Ga per Tav ar and Boris  emvapp 1525 - 1529; DOI: 10.1021/ic048684p |
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Methyl Transfer Reactivity of Five-Coordinate CH3CoIIIPc Wlodzimierz Galezowski pp 1530 - 1546; DOI: 10.1021/ic048698v |
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Difluoro Complexes of Platinum(II) and -(IV) with Monodentate Phosphine Ligands: An Exceptional Stability of d6 Octahedral Organometallic Fluorides Anette Yahav, Israel Goldberg, and Arkadi Vigalok pp 1547 - 1553; DOI: 10.1021/ic0488177 |
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Homo- and Heterobimetallic Niobiumv and Tantalumv Peroxo-tartrate Complexes and Their Use as Molecular Precursors for Nb-Ta Mixed Oxides Daisy Bayot, Bernard Tinant, and Michel Devillers pp 1554 - 1562; DOI: 10.1021/ic0484250 |
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Synthesis, Crystal Structure, and Properties of Multicomponent Bis(ethylenedithio)tetrathiafulvalene Charge-Transfer Salts of the [Mo3S7Br6]2- Cluster Rosa Llusar, Sonia Triguero, Santiago Uriel, Cristian Vicent, Eugenio Coronado, and Carlos J. Gomez-Garcia pp 1563 - 1570; DOI: 10.1021/ic0488379 |
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Unusual Monodentate Binding Mode of 2,2'-Dipyridylamine (L) in Isomeric trans-(acac)2RuII(L)2, trans-[(acac)2RuIII(L)2]ClO4, and cis-(acac)2RuII(L)2 (acac = Acetylacetonate). Synthesis, Structures, and Spectroscopic, Electrochemical, and Magnetic Aspects Sanjib Kar, Nripen Chanda, Shaikh M. Mobin, Francisco A. Urbanos, Mark Niemeyer, Vedavati G. Puranik, Reyes Jimenez-Aparicio, and Goutam Kumar Lahiri pp 1571 - 1579; DOI: 10.1021/ic049219v |
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Control of Electron Acceptor Ability with Ligands (L) in Photoinduced Electron Transfer from Zinc Porphyrin or Zinc Phthalocyanine to [Ru3(3-O)(-CH3COO)6L3]+ Mitsunari Itou, Midoriko Otake, Yasuyuki Araki, Osamu Ito, and Hiroaki Kido pp 1580 - 1587; DOI: 10.1021/ic049114s |
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Synthesis and Characterization of a Family of Structurally Characterized Dysprosium Alkoxides for Improved Fatigue-Resistance Characteristics of PDyZT Thin Films Timothy J. Boyle, Scott D. Bunge, Paul G. Clem, Jacob Richardson, Jeffrey T. Dawley, Leigh Anna M. Ottley, Mark A. Rodriguez, Bruce A. Tuttle, Gabriel R. Avilucea, and Ralph G. Tissot pp 1588 - 1600; DOI: 10.1021/ic048550b |
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Two Stereoisomers of an S-Bridged RhIII2PtII2 Tetranuclear Complex [{Pt(NH3)2}2{Rh(aet)3}2]4+ That Lead to a Discrete and a 1D RhIII2PtII2AgI Structures by Reacting with AgI (aet = 2-Aminoethanethiolate) Yu Chikamoto, Tatsuya Kawamoto, Asako Igashira-Kamiyama, and Takumi Konno pp 1601 - 1610; DOI: 10.1021/ic048680k |
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Efficient Electroluminescence from New Lanthanide (Eu3+, Sm3+) Complexes Jiangbo Yu, Liang Zhou, Hongjie Zhang, Youxuan Zheng, Huanrong Li, Ruiping Deng, Zeping Peng, and Zhefeng Li pp 1611 - 1618; DOI: 10.1021/ic0485561 |
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Reaction of Copper(II) with Ferrocene and 1,1'-Dimethylferrocene in Aqueous Acetonitrile: The Copper(II/I) Self-Exchange Rate Japhet Irangu, Michael J. Ferguson, and Robert B. Jordan pp 1619 - 1625; DOI: 10.1021/ic048614i |
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Synthesis, Characterization, and Electrochemistry of Biorelevant Photosensitive Low-Potential Orthometalated Ruthenium Complexes Alexander D. Ryabov, Ronan Le Lagadec, Hebert Estevez, Ruben A. Toscano, Simon Hernandez, Larissa Alexandrova, Viktoria S. Kurova, Andreas Fischer, Claude Sirlin, and Michel Pfeffer pp 1626 - 1634; DOI: 10.1021/ic048270w |
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Synthesis, Characterization, and Reactivity of Ti(IV)-Monosubstituted Keggin Polyoxometalates Oxana A. Kholdeeva, Tatiana A. Trubitsina, Gennadii M. Maksimov, Anatolii V. Golovin, and Raisa I. Maksimovskaya pp 1635 - 1642; DOI: 10.1021/ic0490829 |
Issue 6
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Electronic Structure of the K3Bi2 Metallic Phase Pere Alemany, Miquel Llunell, and Enric Canadell pp 1644 - 1646; DOI: 10.1021/ic048239u |
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-Stacking Induced NMR Spectrum Splitting in Enantiomerically Enriched Ru(II) Complexes: Evaluation of Enantiomeric Excess Sheba D. Bergman and Moshe Kol pp 1647 - 1654; DOI: 10.1021/ic048569e |
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Synthesis and Rearrangements of Aminosubstituted Ferra- and Ruthenatricarbaboranes Josef Holub, Bohumír Grüner, Dmitry S. Perekalin, Denis G. Golovanov, Konstantin A. Lyssenko, Pavel V. Petrovskii, Alexander R. Kudinov, and Bohumil  tíbrpp 1655 - 1659; DOI: 10.1021/ic0483702 |
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The Highest Bond Order Between Heavier Main-Group Elements in an Isolated Compound? Energetics and Vibrational Spectroscopy of S2I4(MF6)2 (M = As, Sb) Scott Brownridge, T. Stanley Cameron, Hongbin Du, Carsten Knapp, Ralf Köppe, Jack Passmore, J. Mikko Rautiainen, and Hansgeorg Schnöckel pp 1660 - 1671; DOI: 10.1021/ic049035g |
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Syntheses and Characterization of the MF6- (M = As, Sb) Salts of the Simple Trithietanylium PhCS3+ Cation and the Identity of PhCS3Cl Min Fang, Jack Passmore, and Andreas Decken pp 1672 - 1685; DOI: 10.1021/ic049759s |
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Silver(I) Compounds Consisting of [2.2]Paracyclophane: Reversible Guest-Driven Solid-State Transformation and Incorporation Behavior Takayoshi Kuroda-Sowa, Shu Qin Liu, Yuji Yamazaki, Megumu Munakata, Masahiko Maekawa, Yusaku Suenaga, Hisashi Konaka, and Hisao Nakagawa pp 1686 - 1692; DOI: 10.1021/ic0400742 |
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Organometallic Silver(I) Supramolecular Complexes Generated from Multidentate Furan-Containing Symmetric and Unsymmetric Fulvene Ligands and Silver(I) Salts Yu-Bin Dong, Yan Geng, Jian-Ping Ma, and Ru-Qi Huang pp 1693 - 1703; DOI: 10.1021/ic048518h |
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Guanidinium-Based Ionic Liquids Ye Gao, Sean W. Arritt, Brendan Twamley, and Jean'ne M. Shreeve pp 1704 - 1712; DOI: 10.1021/ic048513k |
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Synthetic Control of Excited-State Properties in Cyclometalated Ir(III) Complexes Using Ancillary Ligands Jian Li, Peter I. Djurovich, Bert D. Alleyne, Muhammed Yousufuddin, Nam N. Ho, J. Christopher Thomas, Jonas C. Peters, Robert Bau, and Mark E. Thompson pp 1713 - 1727; DOI: 10.1021/ic048599h |
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Synthesis and Characterization of Copper(I) Amidinates as Precursors for Atomic Layer Deposition (ALD) of Copper Metal Zhengwen Li, Seán T. Barry, and Roy G. Gordon pp 1728 - 1735; DOI: 10.1021/ic048492u |
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Two Closely Related Lanthanum Phosphonate Frameworks Formed by Anion-Directed Linking of Inorganic Chains John A. Groves, Paul A. Wright, and Philip Lightfoot pp 1736 - 1739; DOI: 10.1021/ic048456v |
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Mono-, Di-, and Tricoordinated Phosphorus Attached to a N-N Unit: An Experimental and Theoretical Study Gerd Fischer, Sebastian Herler, Peter Mayer, Axel Schulz, Alexander Villinger, and Jan J. Weigand pp 1740 - 1751; DOI: 10.1021/ic048286m |
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Spectroscopic and Computational Studies on the Trans--1,2-Peroxo-Bridged Dinickel(II) Species [{Ni(tmc)}2(O2)](OTf)2: Nature of End-On Peroxo-Nickel(II) Bonding and Comparison with Peroxo-Copper(II) Bonding Ralph Schenker, Matthew T. Kieber-Emmons, Charles G. Riordan, and Thomas C. Brunold pp 1752 - 1762; DOI: 10.1021/ic048584j |
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Two Novel Iron(II) Materials Based on Dianionic N4O2 Schiff Bases: Structural Properties and Spin-Crossover Characteristics in the Series [Fe(3-X,5-NO2-sal-N(1,4,7,10)] (X = H, 3-MeO, 3-EtO) Lionel Salmon, Azzedine Bousseksou, Bruno Donnadieu, and Jean-Pierre Tuchagues pp 1763 - 1773; DOI: 10.1021/ic048387k |
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Synthesis, Structural Characterization, and Molecular Modeling of Dodecaniobate Keggin Chain Materials François Bonhomme, James P. Larentzos, Todd M. Alam, Edward J. Maginn, and May Nyman pp 1774 - 1785; DOI: 10.1021/ic048847+ |
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Rare Azido-Bridged Manganese(II) Systems: Syntheses, Crystal Structures, and Magnetic Properties A. K. Ghosh, D. Ghoshal, E. Zangrando, J. Ribas, and N. Ray Chaudhuri pp 1786 - 1793; DOI: 10.1021/ic048466w |
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Combined Spectroscopic/Computational Study of Binuclear Fe(I)-Fe(I) Complexes: Implications for the Fully-Reduced Active-Site Cluster of Fe-Only Hydrogenases Adam T. Fiedler and Thomas C. Brunold pp 1794 - 1809; DOI: 10.1021/ic048739n |
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A Noninterpenetrated 1D Molecular Ladder and 2D Butterfly Network: Effect of Positional Isomerism of Semirigid Bis(pyridylmethyl)pyromellitic Diimide Ligands on the Architecture of Their Metal(II) Complexes Xing-Qiang Lü, Ji-Jun Jiang, Hans-Conrad zur Loye, Bei-Sheng Kang, and Cheng-Yong Su pp 1810 - 1817; DOI: 10.1021/ic048634k |
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Synthesis and Luminescent Properties of Novel Lanthanide(III) -Diketone Complexes with Nitrogen p,p'-Disubstituted Aromatic Ligands Anna Bellusci, Giovanna Barberio, Alessandra Crispini, Mauro Ghedini, Massimo La Deda, and Daniela Pucci pp 1818 - 1825; DOI: 10.1021/ic048951r |
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Spectroscopy of Non-Heme Iron Thiolate Complexes: Insight into the Electronic Structure of the Low-Spin Active Site of Nitrile Hydratase Pierre Kennepohl, Frank Neese, Dirk Schweitzer, Henry L. Jackson, Julie A. Kovacs, and Edward I. Solomon pp 1826 - 1836; DOI: 10.1021/ic0487068 |
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Naphthalene-1,2,3-Dithiazolyl and Its Selenium-Containing Variants Richard T. Oakley, Robert W. Reed, Craig M. Robertson, and John F. Richardson pp 1837 - 1845; DOI: 10.1021/ic048534e |
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Two Organometallic Fragments Inclusioned in a 1,3-Alternate Calix[4]arene Tetraphosphane: Evidence for Transition Metal-Arene Interaction through the Cavity Sanghoon Kim, Jong Seung Kim, Sung Kuk Kim, Il-Hwan Suh, Sang Ook Kang, and Jaejung Ko pp 1846 - 1851; DOI: 10.1021/ic048402l |
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Polymorphism in Fe[(p-IC6H4)B(3-Mepz)3]2 (pz = Pyrazolyl): Impact of Supramolecular Structure on an Iron(II) Electronic Spin-State Crossover Daniel L. Reger, James R. Gardinier, Mark D. Smith, Ahmed M. Shahin, Gary J. Long, Leila Rebbouh, and Fernande Grandjean pp 1852 - 1866; DOI: 10.1021/ic048406q |
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Gold Dithiocarbamate Derivatives as Potential Antineoplastic Agents: Design, Spectroscopic Properties, and in Vitro Antitumor Activity Luca Ronconi, Lorena Giovagnini, Christine Marzano, Frazia Bettìo, Rodolfo Graziani, Giuseppe Pilloni, and Dolores Fregona pp 1867 - 1881; DOI: 10.1021/ic048260v |
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Magnetic Resonance and Structural Investigations of (Monooxooctaethylchlorinato)iron(III) Chloride and Its Bis(imidazole) Complex Sheng Cai, Elena Belikova, Liliya A. Yatsunyk, Alan M. Stolzenberg, and F. Ann Walker pp 1882 - 1889; DOI: 10.1021/ic049088y |
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NMR and EPR Studies of the Bis(pyridine) and Bis(tert-butyl isocyanide) Complexes of Iron(III) Octaethylchlorin Sheng Cai, Dennis L. Lichtenberger, and F. Ann Walker pp 1890 - 1903; DOI: 10.1021/ic0490876 |
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A Computational and Experimental Study of the Structures and Raman and 77Se NMR Spectra of SeX3+ and SeX2 (X = Cl, Br, I): FT-Raman Spectrum of (SeI3)[AsF6] J. Mikko Rautiainen, Todd Way, Gabriele Schatte, Jack Passmore, Risto S. Laitinen, Reijo J. Suontamo, and Jussi Valkonen pp 1904 - 1913; DOI: 10.1021/ic048310w |
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Versatility of Heterocyclic Thioamides in the Construction of a Trinuclear Cluster [Cu3I3(dppe)3(SC5H4NH)] and CuI Linear Polymers {Cu6(SC5H4NH)6I6}n·2nCH3CN and {CuI6(SC3H6N2)6X6}n (X = Br, I) Tarlok S. Lobana, Ritu Sharma, Renu Sharma, Sheetal Mehra, Alfonso Castineiras, and Peter Turner pp 1914 - 1921; DOI: 10.1021/ic0484809 |
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The Solution Structure of [Cu(aq)]2+ and Its Implications for Rack-Induced Bonding in Blue Copper Protein Active Sites Patrick Frank, Maurizio Benfatto, Robert K. Szilagyi, Paola D'Angelo, Stefano Della Longa, and Keith O. Hodgson pp 1922 - 1933; DOI: 10.1021/ic0400639 |
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Size and Shape Selectivity of Host Networks Built Based on Tunable Secondary Building Units Dohyun Moon and Myoung Soo Lah pp 1934 - 1940; DOI: 10.1021/ic0486872 |
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DFT Study of Unligated and Ligated ManganeseII Porphyrins and Phthalocyanines Meng-Sheng Liao, John D. Watts, and Ming-Ju Huang pp 1941 - 1949; DOI: 10.1021/ic0401039 |
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Metal Ion Catalysis of Natural Products Transformations. Novel Aldopentose Disproportionation Reactions Catalyzed by Rhodium(III) L. M nsted and O. Mnstedpp 1950 - 1954; DOI: 10.1021/ic0400989 |
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Intramolecular Metal···Sulfur Interactions of Platinum(II) 1,4,7-Trithiacyclononane Complexes with Bipyridyl Ligands: The Relationship between Molecular and Electronic Structures Tyler W. Green, Rachel Lieberman, Neal Mitchell, Jeanette A. Krause Bauer, and William B. Connick pp 1955 - 1965; DOI: 10.1021/ic048610d |
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Effects of the Intramolecular NH···S Hydrogen Bond in Mononuclear Platinum(II) and Palladium(II) Complexes with 2,2'-Bipyridine and Benzenethiol Derivatives Masahiro Kato, Taka-aki Okamura, Hitoshi Yamamoto, and Norikazu Ueyama pp 1966 - 1972; DOI: 10.1021/ic0490167 |
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Synthesis, Crystal Structures, and Nonlinear Optical (NLO) Properties of New Schiff-Base Nickel(II) Complexes. Toward a New Type of Molecular Switch? Jean Pierre Costes, Jean François Lamère, Christine Lepetit, Pascal G. Lacroix, Françoise Dahan, and Keitaro Nakatani pp 1973 - 1982; DOI: 10.1021/ic048578n |
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Theoretical and Synthetic Investigations of Carbodiimide Insertions into Al-CH3 and Al-N(CH3)2 Bonds Christopher N. Rowley, Gino A. DiLabio, and Seán T. Barry pp 1983 - 1991; DOI: 10.1021/ic048501z |
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Design of Rhenium(I) Polypyridine Biotin Complexes as a New Class of Luminescent Probes for Avidin Kenneth Kam-Wing Lo and Wai-Ki Hui pp 1992 - 2002; DOI: 10.1021/ic049059n |
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Enhanced Photoluminescence from Group 14 Metalloles in Aggregated and Solid Solutions Henry J. Tracy, Jerome L. Mullin, Wim T. Klooster, James A. Martin, Judith Haug, Scott Wallace, Isaac Rudloe, and Kimberly Watts pp 2003 - 2011; DOI: 10.1021/ic049034o |
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H-Bonding Interactions and Control of Thiolate Nucleophilicity and Specificity in Model Complexes of Zinc Metalloproteins Jennifer N. Smith, Justin T. Hoffman, Zahida Shirin, and Carl J. Carrano pp 2012 - 2017; DOI: 10.1021/ic048630f |
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Coumarin-Based Chemosensors for Zinc(II): Toward the Determination of the Design Algorithm for CHEF-Type and Ratiometric Probes Nathaniel C. Lim, Jolene V. Schuster, Maura C. Porto, Maria A. Tanudra, Lili Yao, Hedley C. Freake,, and Christian Brückner pp 2018 - 2030; DOI: 10.1021/ic048905r |
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Synthesis, Characterization, and Structures of Mn(DMHP)3·12H2O and Mn(DMHP)2Cl·0.5H2O Wen-Yuan Hsieh and Shuang Liu pp 2031 - 2038; DOI: 10.1021/ic0490627 |
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Structural Determination of Ruthenium-Porphyrin Complexes Relevant to Catalytic Epoxidation of Olefins Emma Gallo, Alessandro Caselli, Fabio Ragaini, Simone Fantauzzi, Norberto Masciocchi, Angelo Sironi, and Sergio Cenini pp 2039 - 2049; DOI: 10.1021/ic048587w |
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[Fe(bpb)(CN)2]- as a Versatile Building Block for the Design of Novel Low-Dimensional Heterobimetallic Systems: Synthesis, Crystal Structures, and Magnetic Properties of Cyano-Bridged FeIII-NiII Complexes [(bpb)2- = 1,2-Bis(pyridine-2-carboxamido)benzenate] Zhong-Hai Ni, Hui-Zhong Kou, Yi-Hua Zhao, Lei Zheng, Ru-Ji Wang, Ai-Li Cui, and Osamu Sato pp 2050 - 2059; DOI: 10.1021/ic0489903 |
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Structure and Magnetism of a New Hydrogen-Bonded Layered Cobalt(II) Network, Constructed by the Unprecedented Carboxylate-Phosphinate Ligand [O2(C6H5)PCH2CO2]2- Stefano Midollini, Annabella Orlandini, Patrick Rosa, and Lorenzo Sorace pp 2060 - 2066; DOI: 10.1021/ic048602x |
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Zirconium Arene-Phosphonates: Chemical and Structural Characterization of 2-Naphthyl- and 2-Anthracenylphosphonate Systems Jay C. Amicangelo and Willem R. Leenstra pp 2067 - 2073; DOI: 10.1021/ic0400282 |
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From Parquets to Bricks: A Series of Lanthanide Coordination Polymers with Bis(diphenylphosphino)ethane Dioxide Zdenek Spichal, Marek Necas, and Jiri Pinkas pp 2074 - 2080; DOI: 10.1021/ic048826f |
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Variable Coordination Mode of Chloranilic Acid. Synthesis, Structure, and Electrochemical Properties of Some Osmium Complexes Parna Gupta, Anindya Das, Falguni Basuli, Alfonso Castineiras, William S. Sheldrick, Heike Mayer-Figge, and Samaresh Bhattacharya pp 2081 - 2088; DOI: 10.1021/ic049149s |
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Photoelectrochemistry on RuII-2,2'-bipyridine-phosphonate-Derivatized TiO2 with the I3-/I- and Quinone/Hydroquinone Relays. Design of Photoelectrochemical Synthesis Cells Laurie A. Gallagher, Scafford A. Serron, Xingu Wen, Brooks J. Hornstein, D. M. Dattelbaum, J. R. Schoonover, and Thomas J. Meyer pp 2089 - 2097; DOI: 10.1021/ic0400991 |
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Reactions of a Gallium(II)-Diazabutadiene Dimer, [{{[(H)C(But)N]2}GaI}2], with [ME(SiMe3)2] (M = Li or Na; E = N, P, or As): Structural, EPR, and ENDOR Characterization of Paramagnetic Gallium(III) Pnictide Complexes Karen L. Antcliff, Robert J. Baker, Cameron Jones, Damien M. Murphy, and Richard P. Rose pp 2098 - 2105; DOI: 10.1021/ic0486825 |
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Synthesis and Characterization of Two Quaternary Thorium Chalcophosphates: Cs4Th2P6S18 and Rb7Th2P6Se21 Benny C. Chan, Ryan F. Hess, Patrick L. Feng, Kent D. Abney, and Peter K. Dorhout pp 2106 - 2113; DOI: 10.1021/ic049101e |
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Heteroleptic Rare Earth Double-Decker Complexes with Naphthalocyaninato and Phthalocyaninato Ligands. General Synthesis, Spectroscopic, and Electrochemical Characteristics Rongming Wang, Yong Li, Renjie Li, Diana Y. Y. Cheng, Peihua Zhu, Dennis K. P. Ng, Meng Bao, Xuegui Cui, Nagao Kobayashi, and Jianzhuang Jiang pp 2114 - 2120; DOI: 10.1021/ic048472s |
Issue 7
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Single-Crystal 55Mn NMR Spectra of Two Mn12 Single-Molecule Magnets Andrew G. Harter, Nicole E. Chakov, Brian Roberts, Randy Achey, Arneil Reyes, Philip Kuhns, George Christou, and Naresh S. Dalal pp 2122 - 2124; DOI: 10.1021/ic050048j |
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A Schiff Base Expanded Porphyrin Macrocycle that Acts as a Versatile Binucleating Ligand for Late First-Row Transition Metals Jonathan L. Sessler, Elisa Tomat, Tarak D. Mody, Vincent M. Lynch, Jacqueline M. Veauthier, Utkir Mirsaidov, and John T. Markert pp 2125 - 2127; DOI: 10.1021/ic048412m |
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Inclusion of Ferrocene in a Cyclodextrin-Functionalized Layered Metal Hydroxide: A New Organometallic-Organic-LDH Nanohybrid L. Mohanambe and S. Vasudevan pp 2128 - 2130; DOI: 10.1021/ic050039a |
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A Tris(-hydroxy)tricopper(II) Complex as a Model of the Native Intermediate in Laccase and Its Relationship to a Binuclear Analogue Liviu M. Mirica and T. Daniel P. Stack pp 2131 - 2133; DOI: 10.1021/ic048182b |
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-Hematin (Hemozoin) Mediated Decompostion of Polyunsaturated Fatty Acids to 4-Hydroxy-2-nonenal Crystal M. Miller, Clare Kenny Carney, Alexandra C. Schrimpe, and David W. Wright pp 2134 - 2136; DOI: 10.1021/ic048821i |
2-Phosphinophenolate Complexes: Formation and Crystal Structure of a Novel Trinuclear -O Nickel(II)-Tris(P O- Chelate)Joachim Heinicke, Normen Peulecke, Konstantin Karaghiosoff, and Peter Mayer pp 2137 - 2139; DOI: 10.1021/ic0484304 |
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Selected-Control Synthesis of Metal Phosphonate Nanoparticles and Nanorods Shu-Yan Song, Jian-Fang Ma, Jin Yang, Min-Hua Cao, and Ke-Chun Li pp 2140 - 2142; DOI: 10.1021/ic048436t |
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Tritopic (Cascade) and Ditopic Complexes of Halides with an Azacryptand Md. Alamgir Hossain, Paula Morehouse, Douglas Powell, and Kristin Bowman-James pp 2143 - 2149; DOI: 10.1021/ic048937e |
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Oxidations of NADH Analogues by cis-[RuIV(bpy)2(py)(O)]2+ Occur by Hydrogen-Atom Transfer Rather than by Hydride Transfer Takashi Matsuo and James M. Mayer pp 2150 - 2158; DOI: 10.1021/ic048170q |
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Reactions of Laser-Ablated Uranium Atoms with H2O in Excess Argon: A Matrix Infrared and Relativistic DFT Investigation of Uranium Oxyhydrides Binyong Liang, Rodney D. Hunt, Gary P. Kushto, Lester Andrews, Jun Li, and Bruce E. Bursten pp 2159 - 2168; DOI: 10.1021/ic0483951 |
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Synthesis, Crystal Structures, and Magnetism of Cobalt Coordination Polymers Based on Dicyanamide and Pyrazine-dioxide Derivatives Hao-Ling Sun, Zhe-Ming Wang, and Song Gao pp 2169 - 2176; DOI: 10.1021/ic048342j |
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Tb4FeGe8 Grown in Liquid Gallium: Trans-Cis Chains from the Distortion of a Planar Ge Square Net Marina A. Zhuravleva, Daniel Bilc, Robert J. Pcionek, S. D. Mahanti, and Mercouri G. Kanatzidis pp 2177 - 2188; DOI: 10.1021/ic0487878 |
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Complex Magnetic Ordering in Eu3InP3: A New Rare Earth Metal Zintl Compound Jiong Jiang, Amy C. Payne, Marilyn M. Olmstead, Han-oh Lee, Peter Klavins, Zachary Fisk, Susan M. Kauzlarich, Raphaël P. Hermann, Fernande Grandjean, and Gary J. Long pp 2189 - 2197; DOI: 10.1021/ic048507o |
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Rhenium Tricarbonyl Core Complexes of Thymidine and Uridine Derivatives Lihui Wei, John Babich, William C. Eckelman, and Jon Zubieta pp 2198 - 2209; DOI: 10.1021/ic048301n |
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Structural Trends and Chemical Bonding in Te-Doped Silicon Clathrates Nicolas Jaussaud, Michel Pouchard, Pierre Gravereau, Stanislas Pechev, Graziella Goglio, Christian Cros, Alfonso San Miguel, and Pierre Toulemonde pp 2210 - 2214; DOI: 10.1021/ic040112h |
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Variation of Oxo-Transfer Reactivity of (Nitro)Cobalt Picket Fence Porphyrin with Oxygen-Donating Ligands John Goodwin, Tigran Kurtikyan, Jean Standard, Rosa Walsh, Bin Zheng, Diedre Parmley, James Howard, Shaun Green, Arthur Mardyukov, and David E. Przybyla pp 2215 - 2223; DOI: 10.1021/ic048701a |
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Lead(II) Thiocyanate Complexes with Bibracchial Lariat Ethers: An X-ray and DFT Study Carlos Platas-Iglesias, David Esteban-Gómez, Teresa Enríquez-Pérez, Fernando Avecilla, Andrés de Blas, and Teresa Rodríguez-Blas pp 2224 - 2233; DOI: 10.1021/ic048768y |
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Solid-Supported Synthesis of Polymerizable Lanthanide-Ion Chelating Lipids for Protein Detection Suad Nadi, Marina Santos, Manas K. Haldar, Bidhan C. Roy, Sanku Mallik, and Andres D. Campiglia pp 2234 - 2244; DOI: 10.1021/ic048885t |
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Performance of Nonrelativistic and Quasi-Relativistic Hybrid DFT for the Prediction of Electric and Magnetic Hyperfine Parameters in 57Fe Mössbauer Spectra Sebastian Sinnecker, Leonardo D. Slep, Eckhard Bill, and Frank Neese pp 2245 - 2254; DOI: 10.1021/ic048609e |
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Theoretical Investigations of Uranyl-Ligand Bonding: Four- and Five-Coordinate Uranyl Cyanide, Isocyanide, Carbonyl, and Hydroxide Complexes Jason L. Sonnenberg, P. Jeffrey Hay, Richard L. Martin, and Bruce E. Bursten pp 2255 - 2262; DOI: 10.1021/ic048567u |
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New d0 Transition Metal Iodates: Synthesis, Structure, and Characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4·(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4·H2O Kang Min Ok and P. Shiv Halasyamani pp 2263 - 2271; DOI: 10.1021/ic048428c |
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Structure and Physical Properties of Ternary Rare-Earth Cobalt Bismuth Intermetallics (RE)12Co5Bi (RE = Y, Gd, Tb, Dy, Ho, Er, Tm) Andriy V. Tkachuk and Arthur Mar pp 2272 - 2281; DOI: 10.1021/ic048195p |
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Structure and Properties of the Thorium Vanadyl Tellurate, Th(VO2)2(TeO6)(H2O)2 Tyler A. Sullens and Thomas E. Albrecht-Schmitt pp 2282 - 2286; DOI: 10.1021/ic048256j |
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Synthesis and Characterization of Hydrogen-Bonded Assemblies of W6S8L6 Clusters Catherine M. Oertel, Ryan D. Sweeder, Sonal Patel, Craig M. Downie, and Francis J. DiSalvo pp 2287 - 2296; DOI: 10.1021/ic0487225 |
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Photophysical, Spectroscopic, and Computational Studies of a Series of Re(I) Tricarbonyl Complexes Containing 2,6-Dimethylphenylisocyanide and 5- and 6-Derivatized Phenanthroline Ligands John M. Villegas, Stanislav R. Stoyanov, Wei Huang, and D. Paul Rillema pp 2297 - 2309; DOI: 10.1021/ic048786f |
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Efficient Plasmid DNA Cleavage by a Mononuclear Copper(II) Complex Claudia Sissi, Fabrizio Mancin, Maddalena Gatos, Manlio Palumbo, Paolo Tecilla, and Umberto Tonellato pp 2310 - 2317; DOI: 10.1021/ic049316o |
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Behavior of Tri(n-butyl)ammonium Bis[citrato(3-)-O1,O3,O6]silicate in Aqueous Solution: Analysis of a Sol-Gel Process by Small-Angle Neutron Scattering Oliver Seiler, Christian Burschka, Dietmar Schwahn, and Reinhold Tacke pp 2318 - 2325; DOI: 10.1021/ic048748w |
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Architecture of Supramolecular Metal Complexes for Photocatalytic CO2 Reduction: Ruthenium-Rhenium Bi- and Tetranuclear Complexes Bobak Gholamkhass, Hiroaki Mametsuka, Kazuhide Koike, Toyoaki Tanabe, Masaoki Furue, and Osamu Ishitani pp 2326 - 2336; DOI: 10.1021/ic048779r |
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Synthesis and Structural Characterization of Novel Neutral Hexacoordinate Silicon(IV) Complexes with SiO2N4 Skeletons Containing Cyanato-N or Thiocyanato-N Ligands Oliver Seiler, Christian Burschka, Markus Fischer, Martin Penka, and Reinhold Tacke pp 2337 - 2346; DOI: 10.1021/ic0485211 |
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Solubility, Complex Formation, and Redox Reactions in the Tl2O3-HCN/CN--H2O System. Crystal Structures of the Cyano Compounds Tl(CN)3·H2O, Na[Tl(CN)4]·3H2O, K[Tl(CN)4], and TlI[TlIII(CN)4] and of TlI2C2O4 Péter Nagy, Andreas Fischer, Julius Glaser, Andrey Ilyukhin, Mikhail Maliarik, and Imre Tóth pp 2347 - 2357; DOI: 10.1021/ic0485918 |
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Structural, Magnetic, and Electrical Characterization of New Polycrystalline Phases of Nickel- and Platinum-Doped [(DT-TTF)n][Au(mnt)2] (n = 1, 2) Xavi Ribas, Angelo Sironi, Norberto Masciocchi, Elsa B. Lopes, Manuel Almeida, Jaume Veciana, and Concepció Rovira pp 2358 - 2366; DOI: 10.1021/ic048484d |
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Mechanistic Insights from Reactions between Copper(II)-Phenoxyl Complexes and Substrates with Activated C-H Bonds Russell C. Pratt and T. Daniel P. Stack pp 2367 - 2375; DOI: 10.1021/ic048695i |
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Copper Hydroxydiphosphate with a One-Dimensional Arrangement of Copper Polyhedra: Cu3[P2O6OH]2 Radu Baies, Vincent Caignaert, Valerie Pralong, and Bernard Raveau pp 2376 - 2380; DOI: 10.1021/ic0485209 |
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Reactivity of Rhenium(V) Oxo Schiff Base Complexes with Phosphine Ligands: Rearrangement and Reduction Reactions Paul D. Benny, Jenny L. Green, Hendrik P. Engelbrecht, Charles L. Barnes, and Silvia S. Jurisson pp 2381 - 2390; DOI: 10.1021/ic048670j |
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Magneto-Structural Correlations: Synthesis of a Family of End-On Azido-Bridged Manganese(II) Dinuclear Compounds with S = 5 Spin Ground State Tapan K. Karmakar, Barindra K. Ghosh, A. Usman, Hoong-Kun Fun, Eric Rivière, Talal Mallah, Guillem Aromí, and Swapan K. Chandra pp 2391 - 2399; DOI: 10.1021/ic048542v |
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Structures of Bisphosphonate Metal Complexes: Zinc and Cadmium Complexes of Clodronate and Its Partial Ester Derivatives Mervi Kontturi, Elina Laurila, Riikka Mattsson, Sirpa Peräniemi, Jouko J. Vepsäläinen, and Markku Ahlgrén pp 2400 - 2406; DOI: 10.1021/ic048329z |
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Analysis of the Spin Exchange Interactions and the Ordered Magnetic Structures of Lithium Transition Metal Phosphates LiMPO4 (M = Mn, Fe, Co, Ni) with the Olivine Structure D. Dai, M.-H. Whangbo, H.-J. Koo, X. Rocquefelte, S. Jobic, and A. Villesuzanne pp 2407 - 2413; DOI: 10.1021/ic048431w |
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Synthesis, Characterization, Physicochemical, and Photophysical Studies of Redox Switchable NIR Dye Derived from a Ruthenium-Dioxolene-Porphyrin System D. Amilan Jose, Atindra D. Shukla, D. Krishna Kumar, Bishwajit Ganguly, Amitava Das, G. Ramakrishna, Dipak K. Palit, and Hirendra N. Ghosh pp 2414 - 2425; DOI: 10.1021/ic048805l |
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Hydrothermal Syntheses and Crystal Structures of Two Novel, Hybrid Materials Based on Secondary Transition-Metal-Incorporated Polyoxovanadate Cluster Backbones: [Cd(dien)2]2[(dien)CdAs8V13O41(H2O)]·4H2O and [Cd(en)2]2[(en)2Cd2As8V12O40] Shou-Tian Zheng, Jie Zhang, and Guo-Yu Yang pp 2426 - 2430; DOI: 10.1021/ic0486015 |
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Cluster Oxalate Complexes [M3(3-Q)(2-Q2)3(C2O4)3]2- and [Mo3(3-Q)(2-Q)3(C2O4)3(H2O)3]2- (M = Mo, W; Q = S, Se): Mechanochemical Synthesis and Crystal Structure Maxim N. Sokolov, Artyom L. Gushchin, Dmitrii Yu. Naumov, Olga A. Gerasko, and Vladimir P. Fedin pp 2431 - 2436; DOI: 10.1021/ic0488637 |
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An Investigation on the Role of the Nature of Sulfonate Ancillary Ligands on the Strength and Concentration Dependence of the Second-Order NLO Responses in CHCl3 of Zn(II) Complexes with 4,4'-trans-NC5H4CH=CHC6H4NMe2 and 4,4'-trans,trans-NC5H4(CH=CH)2C6H4NMe2 Francesca Tessore, Danika Locatelli, Stefania Righetto, Dominique Roberto, Renato Ugo, and Patrizia Mussini pp 2437 - 2442; DOI: 10.1021/ic0487124 |
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Synthesis, Structural Characterization, and Photophysical Properties of Palladium and Platinum(II) Complexes Containing 7,8-Benzoquinolinate and Various Phosphine Ligands Alvaro Díez, Juan Forniés, Ana García, Elena Lalinde, and M. Teresa Moreno pp 2443 - 2453; DOI: 10.1021/ic048272g |
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Ligand-Field Excited States of Metal Hexacarbonyls Patrick Hummel, Jonas Oxgaard, William A. Goddard III, and Harry B. Gray pp 2454 - 2458; DOI: 10.1021/ic048215n |
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Synthesis and X-ray and Neutron Structures of Zr{(-H)2BC8H14}4 Errun Ding, Bin Du, Edward A. Meyers, Sheldon G. Shore, Muhammed Yousufuddin, Robert Bau, and Garry J. McIntyre pp 2459 - 2464; DOI: 10.1021/ic048629g |
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Oxidation of Triarylphosphines and Aryl Methyl Sulfides with Hydrogen Peroxide Catalyzed by Dioxovanadium(V) Ion Guodong Du and James H. Espenson pp 2465 - 2471; DOI: 10.1021/ic048290y |
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Electrochemically Informed Synthesis and Characterization of Salts of the [Pt2(-As,C-C6H3-5-Me-2-AsPh2)4]+ Lantern Complex Containing a Pt-Pt Bond of Order 1/2 Martin A. Bennett, Suresh K. Bhargava, John F. Boas, René T. Boeré, Alan M. Bond, Alison J. Edwards, Si-Xuan Guo, Anton Hammerl, John R. Pilbrow, Steven H. Privér, and Peter Schwerdtfeger pp 2472 - 2482; DOI: 10.1021/ic048660i |
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Chemistry of Ruthenium(II) Monohydride and Dihydride Complexes Containing Pyridyl Donor Ligands Including Catalytic Ketone H2-Hydrogenation1 Kamaluddin Abdur-Rashid, Robert Abbel, Alen Hadzovic, Alan J. Lough, and Robert H. Morris pp 2483 - 2492; DOI: 10.1021/ic0489387 |
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d-Electron-Induced Negative Magnetoresistance of a -d Interaction System Based on a Brominated-TTF Donor Junichi Nishijo, Akira Miyazaki, Toshiaki Enoki, Ryoji Watanabe, Yoshiyuki Kuwatani, and Masahiko Iyoda pp 2493 - 2506; DOI: 10.1021/ic048548k |
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Kinetics and Mechanism of the Mercury(II)-Assisted Hydrolysis of Methyl Iodide Valbona Celo and Susannah L. Scott pp 2507 - 2512; DOI: 10.1021/ic050154l |
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Mononuclear and Dinuclear Complexes of Isoeilatin Sheba D. Bergman, Israel Goldberg, Andrea Barbieri, and Moshe Kol pp 2513 - 2523; DOI: 10.1021/ic050002q |
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Cyclic Polyvanadates Incorporating Template Transition Metal Cationic Species: Synthesis and Structures of Hexavanadate [PdV6O18]4-, Octavanadate [Cu2V8O24]4-, and Decavanadate [Ni4V10O30(OH)2(H2O)6]4- Taisei Kurata, Akira Uehara, Yoshihito Hayashi, and Kiyoshi Isobe pp 2524 - 2530; DOI: 10.1021/ic048751f |
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Coordination Modes between Copper(II) and N-Acetylneuraminic (Sialic) Acid from a 2D-Simulation Analysis of EPR Spectra. Implications for Copper Mediation of Sialoglycoconjugate Chemistry Relevant to Human Biology Marina Fainerman-Melnikova, Terézia Szabó-Plánka, Antal Rockenbauer, and Rachel Codd pp 2531 - 2543; DOI: 10.1021/ic049126d |
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Flexible Ligands and Structural Diversity: Isomerism in Cd(NO3)2 Coordination Polymers David B. Cordes, Andrew S. Bailey, Paula L. Caradoc-Davies, Duncan H. Gregory, Lyall R. Hanton, Kitty Lee, and Mark D. Spicer pp 2544 - 2552; DOI: 10.1021/ic048473k |
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Synthesis, Structure, and Large Optical Limiting Effect of the First Coordination Polymeric Cluster Based on an {I@[AgI(inh)]6} Hexagram Block Yunyin Niu, Yinglin Song, Hongwei Hou, and Yu Zhu pp 2553 - 2559; DOI: 10.1021/ic0487023 |
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New Oxorhenium(V) Compound for Catalyzed Oxygen Atom Transfer from Picoline N-Oxide to Triarylphosphines Yang Cai, Arkady Ellern, and James H. Espenson pp 2560 - 2565; DOI: 10.1021/ic048598p |
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Tetramanganese(II) Cluster with Centered Trigonal Topology: Structure and Magnetic Properties En-Qing Gao, Shi-Qiang Bai, Zheng He, and Chun-Hua Yan: pp 2566 - 2566; DOI: 10.1021/ic058001l |
Issue 8
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Hydrothermal Synthesis of Ultralong and Single-Crystalline Cd(OH)2 Nanowires Using Alkali Salts as Mineralizers Bo Tang, Linhai Zhuo, Jiechao Ge, Jinye Niu, and Zhiqiang Shi pp 2568 - 2569; DOI: 10.1021/ic049195s |
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Spin Density Distribution in Five- and Six-Coordinate Iron(II)-Porphyrin NO Complexes Evidenced by Magnetic Circular Dichroism Spectroscopy V. K. K. Praneeth, Frank Neese, and Nicolai Lehnert pp 2570 - 2572; DOI: 10.1021/ic050144k |
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Pb(II) Coordination and Synergistic Ion-Exchange Extraction by Combinations of Sulfonamide Chelates and 2,2'-Bipyridine Konstantinos Kavallieratos, Jay M. Rosenberg, and Jeffrey C. Bryan pp 2573 - 2575; DOI: 10.1021/ic050047r |
Preparation and Solid-State Characterization of the Novel Mixed Biradical  NSNSC-CNSSNT. Stanley Cameron, Martin T. Lemaire, Jack Passmore, Jeremy M. Rawson, Konstantin V. Shuvaev, and Laurence K. Thompson pp 2576 - 2578; DOI: 10.1021/ic048306k |
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High-Resolution X-ray Emission Spectroscopy of Molybdenum Compounds Christian J. Doonan, Limei Zhang, Charles G. Young, Simon J. George, Aniruddha Deb, Uwe Bergmann, Graham N. George, and Stephen P. Cramer pp 2579 - 2581; DOI: 10.1021/ic050129f |
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Photosensitizer in a Molecular Bowl: Steric Protection Enhancing the Photonuclease Activity of Copper(II) Scorpionates Shanta Dhar and Akhil R. Chakravarty pp 2582 - 2584; DOI: 10.1021/ic050085a |
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Self-Assembly of a Fluorescent Chiral Zinc(II) Complex That Leads to Supramolecular Helices Maddela Prabhakar, Panthapally S. Zacharias, and Samar K. Das pp 2585 - 2587; DOI: 10.1021/ic048236h |
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Binding of Propylene Oxide to Porphyrin- and Salen-M(III) Cations, Where M = Al, Ga, Cr, and Co Peter Chen, Malcolm H. Chisholm, Judith C. Gallucci, Xiangyang Zhang, and Zhiping Zhou pp 2588 - 2595; DOI: 10.1021/ic048597x |
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Mononuclear Titanium(IV)-Citrate Complexes from Aqueous Solutions: pH-Specific Synthesis and Structural and Spectroscopic Studies in Relevance to Aqueous Titanium(IV)-Citrate Speciation E. T. Kefalas, P. Panagiotidis, C. P. Raptopoulou, A. Terzis, T. Mavromoustakos, and A. Salifoglou pp 2596 - 2605; DOI: 10.1021/ic049276o |
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Low-Coordinate Chromium Siloxides: The "Box" [Cr(-Cl)(-OSitBu3)]4, Distorted Trigonal [(tBu3SiO)3Cr][Na(benzene)] and [(tBu3SiO)3Cr][Na(dibenzo-18-c-6)], and Trigonal (tBu3SiO)3Cr Orson L. Sydora, Peter T. Wolczanski, Emil B. Lobkovsky, Corneliu Buda, and Thomas R. Cundari pp 2606 - 2618; DOI: 10.1021/ic0488334 |
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A Platinum Acetylide Polymer with Sterically Demanding Substituents: Effect of Aggregation on the Triplet Excited State Xiaoming Zhao, Thomas Cardolaccia, Richard T. Farley, Khalil A. Abboud, and Kirk S. Schanze pp 2619 - 2627; DOI: 10.1021/ic048961s |
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Facile Synthesis, Structure, and Luminescence Properties of Pt(diimine)bis(arylacetylide) Chromophore-Donor Dyads Thaddeus J. Wadas, Soma Chakraborty, Rene J. Lachicotte, Quan-Ming Wang, and Richard Eisenberg pp 2628 - 2638; DOI: 10.1021/ic048886l |
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Crystal Growth and Magnetic Properties of Lanthanide-Containing Osmium Double Perovskites, Ln2NaOsO6 (Ln = La, Pr, Nd) William R. Gemmill, Mark D. Smith, Ruslan Prozorov, and Hans-Conrad zur Loye pp 2639 - 2646; DOI: 10.1021/ic048637x |
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Coordination Polymers from Silver(I) and Bifunctional Pyridyl Ligands Moonhyun Oh, Charlotte L. Stern, and Chad A. Mirkin pp 2647 - 2653; DOI: 10.1021/ic0482990 |
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Ligand-Free Deltahedral Clusters of Silicon in Solution: Synthesis, Structure, and Electrochemistry of Si92- Jose M. Goicoechea and Slavi C. Sevov pp 2654 - 2658; DOI: 10.1021/ic0500964 |
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The Satellite-Shaped Co-15 Polyoxotungstate, [Co6(H2O)30{Co9Cl2(OH)3(H2O)9(-SiW8O31)3}]5- Bassem S. Bassil, Saritha Nellutla, Ulrich Kortz, Ashley C. Stowe, Johan van Tol, Naresh S. Dalal, Bineta Keita, and Louis Nadjo pp 2659 - 2665; DOI: 10.1021/ic048269x |
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Group 13 and Lanthanide Complexes with Mixed O,S Anionic Ligands Derived from Maltol Vishakha Monga, Brian O. Patrick, and Chris Orvig pp 2666 - 2677; DOI: 10.1021/ic048693y |
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Vanadium Complexes with Mixed O,S Anionic Ligands Derived from Maltol: Synthesis, Characterization, and Biological Studies Vishakha Monga, Katherine H. Thompson, Violet G. Yuen, Vijay Sharma, Brian O. Patrick, John H. McNeill, and Chris Orvig pp 2678 - 2688; DOI: 10.1021/ic0486926 |
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Coordination Chemistry and Insulin-Enhancing Behavior of Vanadium Complexes with Maltol C6H6O3 Structural Isomers Katayoun Saatchi, Katherine H. Thompson, Brian O. Patrick, Maren Pink, Violet G. Yuen, John H. McNeill, and Chris Orvig pp 2689 - 2697; DOI: 10.1021/ic048186g |
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Carbohydrate-Appended 2,2'-Dipicolylamine Metal Complexes as Potential Imaging Agents Tim Storr, Yuko Sugai, Cheri A. Barta, Yuji Mikata, Michael J. Adam, Shigenobu Yano, and Chris Orvig pp 2698 - 2705; DOI: 10.1021/ic048528i |
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Release of Iron from Ferritin by Aceto- and Benzohydroxamic Acids Natividad Gálvez, Beatriz Ruiz, Rafael Cuesta, Enrique Colacio, and José M. Domínguez-Vera pp 2706 - 2709; DOI: 10.1021/ic048840s |
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Bis(Cyclopentadienyl)Titanium Complexes of Naphthalene-1,8-Dithiolates, Biphenyl 2,2'-Dithiolates, and Related Ligands Stephen M. Aucott, Petr Kilian, Heather L. Milton, Stuart D. Robertson, Alexandra M. Z. Slawin, and J. Derek Woollins pp 2710 - 2718; DOI: 10.1021/ic048483l |
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Five New Zinc Phosphite Structures: Tertiary Building Blocks in the Construction of Hybrid Materials Jian Fan, Carla Slebodnick, Diego Troya, Ross Angel, and Brian E. Hanson pp 2719 - 2727; DOI: 10.1021/ic048204u |
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A Sugar's Choice: Coordination to a Mononuclear or a Dinuclear Copper(II) Complex? Susanne Striegler and Michael Dittel pp 2728 - 2733; DOI: 10.1021/ic048724p |
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Isophthalato-Based 2D Coordination Polymers of Eu(III), Gd(III), and Tb(III): Enhancement of the Terbium-Centered Luminescence through Thiophene Derivatization Ana de Bettencourt-Dias pp 2734 - 2741; DOI: 10.1021/ic048499b |
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Wheel-Shaped [Mn12] Single-Molecule Magnets Evan M. Rumberger, Sonali J. Shah, Christopher C. Beedle, Lev N. Zakharov, Arnold L. Rheingold, and David N. Hendrickson pp 2742 - 2752; DOI: 10.1021/ic048316l |
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Temperature Dependence of the Crystal Structure and g-Values of [(HC(Ph2PO)3)2Cu](ClO4)2·2H2O: Influence of Dynamic Jahn-Teller Coupling and Lattice Strain Interactions Charles J. Simmons, Horst Stratemeier, Graeme R. Hanson, and Michael A. Hitchman pp 2753 - 2760; DOI: 10.1021/ic048604h |
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Field-Induced Magnetic Transitions in Metal Phosphonates with Ladderlike Chain Structures: (NH3C6H4NH3)M2(hedpH)2·H2O [M = Fe, Co, Mn, Zn; hedp = C(CH3)(OH)(PO3)2] Ping Yin, Song Gao, Zhe-Ming Wang, Chun-Hua Yan, Li-Min Zheng, and Xin-Quan Xin pp 2761 - 2765; DOI: 10.1021/ic048437l |
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Transformation of 4-Phosphinidenes at an Ru5 Center: Isolation and Structural Characterization of Hydroxyphosphinidene Cluster Acids, Fluorophosphinidenes, and a Novel 5-Phosphide Ludmila Scoles, Brian T. Sterenberg, Konstantin A. Udachin, and Arthur J. Carty pp 2766 - 2773; DOI: 10.1021/ic040077e |
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Synthesis and Characterization of Ge(II), Sn(II), and Pb(II) Monoamides with -NH2 Ligands Corneliu Stanciu, Shirley S. Hino, Matthias Stender, Anne F. Richards, Marilyn M. Olmstead, and Philip P. Power pp 2774 - 2780; DOI: 10.1021/ic048362l |
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Release of NO from Reduced Nitroprusside Ion. Iron-Dinitrosyl Formation and NO-Disproportionation Reactions Federico Roncaroli, Rudi van Eldik, and José A. Olabe pp 2781 - 2790; DOI: 10.1021/ic050070c |
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Lewis Acid Properties of Zinc(II) in Its Cyclen Complex. The Structure of [Zn(Cyclen)(S=C(NH2)2](ClO4)2 and the Bonding of Thiourea to Metal Ions. Some Implications for Zinc Metalloenzymes Michael H. Salter, Jr., Joseph H. Reibenspies, S. Bart Jones, and Robert D. Hancock pp 2791 - 2797; DOI: 10.1021/ic048705f |
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Synthesis and Structures of cis- and trans-Bis(alkyneselenolato)platinum(II) Complexes Sven Schäfer, Carmen Moser, Jürgen J. Tirrée, Martin Nieger, and Rudolf Pietschnig pp 2798 - 2802; DOI: 10.1021/ic048454a |
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Six-Coordinate Titanium Complexes of a Tripodal Aminetris(phenoxide) Ligand: Synthesis, Structure, and Dynamics Kevin C. Fortner, Julian P. Bigi, and Seth N. Brown pp 2803 - 2814; DOI: 10.1021/ic048403d |
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Reactions of the Dianion [1,1,1-(CO)3-2-Ph-closo-1,2-MnCB9H9]2- with Transition-Metal Cations: Facile Insertion and Then Extrusion of Cluster Vertexes Shaowu Du, John C. Jeffery, Jason A. Kautz, Xiu Lian Lu, Thomas D. McGrath, Thomas A. Miller, T. Riis-Johannessen, and F. Gordon A. Stone pp 2815 - 2825; DOI: 10.1021/ic048345w |
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Synthesis, Characterization, and Photochemical Behavior of {Ru(arene)}2+ Derivatives of -[PW11O39]7-: An Organometallic Way to Ruthenium-Substituted Heteropolytungstates V. Artero, D. Laurencin, R. Villanneau, R. Thouvenot, P. Herson, P. Gouzerh, and A. Proust pp 2826 - 2835; DOI: 10.1021/ic0482180 |
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Synthesis, Characterization, and Photophysical Properties of a Free Base and a Biszinc(II) Complex of 1,3-Bisporphyrincalix[4]arene: Evidence for "Tunable Intramolecular Open and Closed Conformations" Jean-Philipe Tremblay-Morin, Sébastien Faure, Dalila Samar, Christine Stern, Roger Guilard, and Pierre D. Harvey pp 2836 - 2842; DOI: 10.1021/ic048261n |
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The Redox Series [M(bpy)2(Q)]n+, M = Ru or Os, Q = 3,5-Di-tert-butyl-N-phenyl-1,2-benzoquinonemonoimine. Isolation and a Complete X and W Band EPR Study of the Semiquinone States (n = 1) Shengfa Ye, Biprajit Sarkar, Carole Duboc, Jan Fiedler, and Wolfgang Kaim pp 2843 - 2847; DOI: 10.1021/ic048407i |
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Magnetic Resonance Spectroscopic Investigations of the Electronic Ground and Excited States in Strongly Nonplanar Iron(III) Dodecasubstituted Porphyrins Liliya A. Yatsunyk, Nikolai V. Shokhirev, and F. Ann Walker pp 2848 - 2866; DOI: 10.1021/ic049089q |
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Kinetics of Ring Inversion in Strongly Nonplanar Iron(III) Octaalkyltetraphenylporphyrinates Liliya A. Yatsunyk, Hiroshi Ogura, and F. Ann Walker pp 2867 - 2881; DOI: 10.1021/ic049090p |
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New Titanium Imido Synthons: Syntheses and Supramolecular Structures Nico Adams, Helen R. Bigmore, Timothy L. Blundell, Catherine L. Boyd, Stuart R. Dubberley, Andrew J. Sealey, Andrew R. Cowley, Michael E. G. Skinner, and Philip Mountford pp 2882 - 2894; DOI: 10.1021/ic050011z |
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Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP = 2,6-(CH2PtBu2)2C6H3) with Substrates That Possess Polar Bonds Jubo Zhang, T. Brent Gunnoe, and Jeffrey L. Petersen pp 2895 - 2907; DOI: 10.1021/ic0483592 |
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Conformations, Protonation Sites, and Metal Complexation of Benzohydroxamic Acid. A Theoretical and Experimental Study Begoña García, Saturnino Ibeas, José M. Leal, Fernando Secco, Marcella Venturini, Maria L. Senent, Alfonso Niño, and Camelia Muñoz pp 2908 - 2919; DOI: 10.1021/ic049438g |
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A Ladderlike Chain Aluminum Fluoride ([Al2F8]2-)n with Edge-Sharing AlF6 Octahedra Thierry Loiseau, Hervé Muguerra, Jerôme Marrot, Gérard Férey, Mohamed Haouas, and Francis Taulelle pp 2920 - 2925; DOI: 10.1021/ic048461z |
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The Insertion of Carbodiimides into Al and Ga Amido Linkages. Guanidinates and Mixed Amido Guanidinates of Aluminum and Gallium Amanda P. Kenney, Glenn P. A. Yap, Darrin S. Richeson, and Seán T. Barry pp 2926 - 2933; DOI: 10.1021/ic048433g |
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Chromium(V) Complexes of Hydroxamic Acids: Formation, Structures, and Reactivities Swetlana Gez, Robert Luxenhofer, Aviva Levina, Rachel Codd, and Peter A. Lay pp 2934 - 2943; DOI: 10.1021/ic048317d |
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Kinetic and Mechanistic Study of the Pt(II) versus Pt(IV) Effect in the Platinum-Mediated Nitrile-Hydroxylamine Coupling Konstantin V. Luzyanin, Vadim Yu. Kukushkin, Alexander D. Ryabov, Matti Haukka, and Armando J. L. Pombeiro pp 2944 - 2953; DOI: 10.1021/ic048388c |
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Ground States, Excited States, and Metal-Ligand Bonding in Rare Earth Hexachloro Complexes: A DFT-Based Ligand Field Study M. Atanasov, C. Daul, H. U. Güdel, T. A. Wesolowski, and M. Zbiri pp 2954 - 2963; DOI: 10.1021/ic040105t |
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Thermodynamics of the As(III)-Thiol Interaction: Arsenite and Monomethylarsenite Complexes with Glutathione, Dihydrolipoic Acid, and Other Thiol Ligands Anne M. Spuches, Harriet G. Kruszyna, Anne M. Rich, and Dean E. Wilcox pp 2964 - 2972; DOI: 10.1021/ic048694q |
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Formation of N-I Charge-Transfer Bonds and Ion Pairs in Polyiodides with Imidotellurium Cations Jari Konu, Tristram Chivers, Gabriele Schatte, Masood Parvez, and Risto S. Laitinen pp 2973 - 2982; DOI: 10.1021/ic050058k |
Issue 9
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[Zn7{(2-C5H4N)CH(OH)PO3}6(H2O)6]SO4·4H2O: A Zinc Phosphonate Cluster with a Drum-like Cage Structure Deng-Ke Cao, Yi-Zhi Li, and Li-Min Zheng pp 2984 - 2985; DOI: 10.1021/ic0500659 |
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Mica Surfaces Stabilize Pentavalent Uranium Eugene S. Ilton, Anca Haiduc, Christopher L. Cahill, and Andrew R. Felmy pp 2986 - 2988; DOI: 10.1021/ic0487272 |
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Supramolecular Recognition Forces: An Examination of Weak Metal-Metal Interactions in Host-Guest Formation James D. Crowley, Ian M. Steele, and B. Bosnich pp 2989 - 2991; DOI: 10.1021/ic0481531 |
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Rb3In(H2O)Si5O13: A Novel Indium Silicate with a CdSO4-Topological-Type Structure Ling-I Hung, Sue-Lein Wang, Chia-Yi Chen, Bor-Chen Chang, and Kwang-Hwa Lii pp 2992 - 2994; DOI: 10.1021/ic048296n |
An Unprecedented Coordination Mode of the Tris(pyrazolyl)methane Donor Set in {[Ph2(O)POCH2C(pz)3Ag]2(THF)2}(BF4)2: 2-1 Bimetallic, N /N ChelatingDaniel L. Reger, Radu F. Semeniuc, Burjor Captain, and Mark D. Smith pp 2995 - 2997; DOI: 10.1021/ic0501162 |
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Metal-Organic Frameworks Based on Trigonal Prismatic Building Blocks and the New "acs" Topology Andrea C. Sudik, Adrien P. Côté, and Omar M. Yaghi pp 2998 - 3000; DOI: 10.1021/ic050064g |
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Synthesis, Crystal Structure, and Properties of MnNCN, the First Carbodiimide of a Magnetic Transition Metal Xiaohui Liu, Manuel Krott, Paul Müller, Chunhua Hu, Heiko Lueken, and Richard Dronskowski pp 3001 - 3003; DOI: 10.1021/ic050050a |
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A Surprisingly Stable Macrochelate Formed from the Reaction of Cis Dinuclear Platinum Antitumor Compounds with Reduced Glutathione Michael E. Oehlsen, Alexander Hegmans, Yun Qu, and Nicholas Farrell pp 3004 - 3006; DOI: 10.1021/ic0501972 |
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On the Existence and Stability of Branched Selenium Chains: Isomers of Me2Se3 and Et2Se3 Ralf Steudel and Yana Steudel pp 3007 - 3009; DOI: 10.1021/ic048220r |
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The First -Diketiminate-Ag(I) Complexes. Macrocyclic Dinuclear and Tetranuclear Ag(I)-Complexes and Linear Coordination Polymer Ag(I)-Complex Chizu Shimokawa and Shinobu Itoh pp 3010 - 3012; DOI: 10.1021/ic0501014 |
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Ni-Pt Multilayered Nanowire Arrays with Enhanced Coercivity and High Remanence Ratio Han-Pu Liang, Yu-Guo Guo, Jin-Song Hu, Chuan-Feng Zhu, Li-Jun Wan, and Chun-Li Bai pp 3013 - 3015; DOI: 10.1021/ic0500917 |
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Reduction Pathway of End-On Terminally Coordinated Dinitrogen. IV. Geometric, Electronic, and Vibrational Structure of a W(IV) Dialkylhydrazido Complex and Its Two-Electron-Reduced Derivative Undergoing N-N Cleavage upon Protonation Kay H. Horn, Natascha Böres, Nicolai Lehnert, Klaus Mersmann, Christian Näther, Gerhard Peters, and Felix Tuczek pp 3016 - 3030; DOI: 10.1021/ic048675g |
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Reduction Pathway of End-On Terminally Coordinated Dinitrogen. V. N-N Bond Cleavage in Mo/W Hydrazidium Complexes with Diphosphine Coligands. Comparison with Triamidoamine Systems Klaus Mersmann, Kay H. Horn, Natascha Böres, Nicolai Lehnert, Felix Studt, Florian Paulat, Gerhard Peters, Ivana Ivanovic-Burmazovic, Rudi van Eldik, and Felix Tuczek pp 3031 - 3045; DOI: 10.1021/ic048674o |
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Concentration of Carbon Dioxide by Electrochemically Modulated Complexation with a Binuclear Copper Complex Aaron M. Appel, Rachel Newell, Daniel L. DuBois, and M. Rakowski DuBois pp 3046 - 3056; DOI: 10.1021/ic050023k |
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Metal-Rich Chalcogenides. Synthesis, Structure, and Bonding of the Layered Lu11Te4. Comparison with the Similar Sc8Te3 and Ti11Se4 Ling Chen, Sheng-Qing Xia, and John D. Corbett pp 3057 - 3062; DOI: 10.1021/ic0401142 |
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New Materials Derived from Ybco: CrSr2RECu2O8 (RE = La, Pr, Nd, Eu, Gd, Tb, Dy, Y, Ho, Er, Lu) Rocío Ruiz-Bustos, Myriam H. Aguirre, and Miguel Á. Alario-Franco pp 3063 - 3069; DOI: 10.1021/ic048929y |
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A Phenolate-Induced Trans Influence: Crystallographic Evidence for Unusual Asymmetric Coordination of an -Diimine in Ternary Complexes of Iron(III) Possessing Biologically Relevant Hetero-Donor N-Centered Tripodal Ligands Musa S. Shongwe, Catherine H. Kaschula, Michael S. Adsetts, Eric W. Ainscough, Andrew M. Brodie, and Michael J. Morris pp 3070 - 3079; DOI: 10.1021/ic048835o |
Synthesis and Structure of K+[iPrN=C=P]-, a 1-Aza-3 3-phospha-3-allenideGerd Becker, Heike Brombach, Stephen T. Horner, Edgar Niecke, Wolfgang Schwarz, Rainer Streubel, and Ernst-Ulrich Würthwein pp 3080 - 3086; DOI: 10.1021/ic048162+ |
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Synthesis, Crystal Structure, Magnetic Properties, and Electronic Structure of the New Ternary Vanadate CuMnVO4 Hamdi Ben Yahia, Etienne Gaudin, Jacques Darriet, Michael Banks, Reinhard K. Kremer, Antoine Villesuzanne, and Myung-Hwan Whangbo pp 3087 - 3093; DOI: 10.1021/ic048244y |
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Synthesis and Spectroscopic and X-ray Structural Characterization of R2SnIV-Oxydiacetate and -Iminodiacetate Complexes Corrado Di Nicola, Agustin Galindo, John V. Hanna, Fabio Marchetti, Claudio Pettinari, Riccardo Pettinari, Eleonora Rivarola, Brian W. Skelton, and Allan H. White pp 3094 - 3102; DOI: 10.1021/ic048240t |
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Square Planar vs Tetrahedral Geometry in Four Coordinate Iron(II) Complexes Eric J. Hawrelak, Wesley H. Bernskoetter, Emil Lobkovsky, Gordon T. Yee, Eckhard Bill, and Paul J. Chirik pp 3103 - 3111; DOI: 10.1021/ic048202+ |
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Esterase-Activated Two-Fluorophore System for Ratiometric Sensing of Biological Zinc(II) Carolyn C. Woodroofe, Annie C. Won, and Stephen J. Lippard pp 3112 - 3120; DOI: 10.1021/ic048789s |
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Salt-Inclusion Synthesis of Two New Polar Solids, Ba6Mn4Si12O34Cl3 and Ba6Fe5Si11O34Cl3 Xunhua Mo, Erin Ferguson, and Shiou-Jyh Hwu pp 3121 - 3126; DOI: 10.1021/ic050228t |
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Solution Calorimetric and Stopped-Flow Kinetic Studies of the Reaction of Cr(CO)3C5Me5 with PhSe-SePh and PhTe-TePh. Experimental and Theoretical Estimates of the Se-Se, Te-Te, H-Se, and H-Te Bond Strengths James E. McDonough, John J. Weir, Matthew J. Carlson, Carl D. Hoff, Olga P. Kryatova, Elena V. Rybak-Akimova, Christopher R. Clough, and Christopher C. Cummins pp 3127 - 3136; DOI: 10.1021/ic048321p |
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The Gas Phase Structure of Ethynylferrocene Using Microwave Spectroscopy Ranga Subramanian, Chandana Karunatilaka, Kristen S. Keck, and Stephen G. Kukolich pp 3137 - 3145; DOI: 10.1021/ic048516x |
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Well-Resolved, New Water Morphologies Obtained by Modification of the Hydrophilic/Hydrophobic Character and Shapes of the Supporting Layers Jie-Peng Zhang, Yan-Yong Lin, Xiao-Chun Huang, and Xiao-Ming Chen pp 3146 - 3150; DOI: 10.1021/ic0483186 |
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Relationship between the Ratio of Ligand to Metal and the Coordinating Ability of Anions. Synthesis and Structural Properties of AgX-Bearing Bis(4-pyridyl)dimethylsilane (X- = NO2-, NO3-, CF3SO3-, and PF6-) Jung Woon Lee, Eun Ae Kim, Yun Ju Kim, Young-A Lee, Youngshang Pak, and Ok-Sang Jung pp 3151 - 3155; DOI: 10.1021/ic048537r |
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Coordination Polymers of La(III) as Bunched Infinite Nanotubes and Their Conversion into an Open-Framework Structure Sujit K. Ghosh and Parimal K. Bharadwaj pp 3156 - 3161; DOI: 10.1021/ic048159q |
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Dihydrogen Complexes of Rhodium: [RhH2(H2)x(PR3)2]+ (R = Cy, iPr; x = 1, 2) Michael J. Ingleson, Simon K. Brayshaw, Mary F. Mahon, Giuseppe D. Ruggiero, and Andrew S. Weller pp 3162 - 3171; DOI: 10.1021/ic0482739 |
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Rhenium(V) and Technetium(V) Complexes with Phosphoraneimine and Phosphoraneiminato Ligands Maren Hecht, Sonia Saucedo Anaya, Adelheid Hagenbach, and Ulrich Abram pp 3172 - 3180; DOI: 10.1021/ic048210q |
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High-Nuclearity Mixed-Chelate Ferric Complexes from a New Family of Polynuclear Precursors Colette Boskovic, Hans U. Güdel, Gaël Labat, Antonia Neels, Wolfgang Wernsdorfer, Boujemaa Moubaraki, and Keith S. Murray pp 3181 - 3189; DOI: 10.1021/ic048411u |
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Influence of Pt Nanocrystallinity on Electrochromism of TiO2 Kyung-Won Park pp 3190 - 3193; DOI: 10.1021/ic049021a |
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Structural and Magnetic Diversity in Tetraalkylammonium Salts of Anionic M[N(CN)2]3- (M = Mn and Ni) Three-Dimensional Coordination Polymers John A. Schlueter, Jamie L. Manson, and Urs Geiser pp 3194 - 3202; DOI: 10.1021/ic0484598 |
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Nanophase Iron Phosphate, Iron Arsenate, Iron Vanadate, and Iron Molybdate Minerals Synthesized within the Protein Cage of Ferritin Jup Polanams, Alisha D. Ray, and Richard K. Watt pp 3203 - 3209; DOI: 10.1021/ic048819r |
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Sensitive Oxidation State Ambivalence in Unsymmetrical Three-Center (M/Q/M) Systems [(acac)2Ru(-Q)Ru(acac)2]n, Q = 1,10-Phenanthroline-5,6-dione or 1,10-Phenanthroline-5,6-diimine (n = +, 0, -, 2-) Sandeep Ghumaan, Biprajit Sarkar, Srikanta Patra, Joris van Slageren, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri pp 3210 - 3214; DOI: 10.1021/ic048309x |
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A New Strategy for the Improvement of Photophysical Properties in Ruthenium(II) Polypyridyl Complexes. Synthesis and Photophysical and Electrochemical Characterization of Six Mononuclear Ruthenium(II) Bisterpyridine-Type Complexes Maria Abrahamsson, Henriette Wolpher, Olof Johansson, Jan Larsson, Mikael Kritikos, Lars Eriksson, Per-Ola Norrby, Jonas Bergquist, Licheng Sun, Björn Åkermark, and Leif Hammarström pp 3215 - 3225; DOI: 10.1021/ic048247a |
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Homodinuclear Iron Thiolate Nitrosyl Compounds [(ON)Fe(S,S-C6H4)2Fe(NO)2]- and [(ON)Fe(SO2,S-C6H4)(S,S-C6H4)Fe(NO)2]- with {Fe(NO)}7-{Fe(NO)2}9 Electronic Coupling: New Members of a Class of Dinitrosyl Iron Complexes Hao-Wen Chen, Chin-Wei Lin, Chiao-Chun Chen, Li-Bo Yang, Ming-Hsi Chiang, and Wen-Feng Liaw pp 3226 - 3232; DOI: 10.1021/ic049105j |
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Structural Variability and Dynamics in Carboxylato- and Carbamatomagnesium Bromides. Relationship to the Carboxylate Shift M. Tyler Caudle, William W. Brennessel, and Victor G. Young, Jr. pp 3233 - 3240; DOI: 10.1021/ic048442p |
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New Members of an Old Family: Isolation of IC(O)Cl and IC(O)Br and Evidence for the Formation of Weakly Bound Br···CO Rosana M. Romano, Carlos O. Della Védova, Anthony J. Downs, Yeny A. Tobón, and Helge Willner pp 3241 - 3248; DOI: 10.1021/ic0484046 |
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Coordination Behavior toward Copper(II) and Zinc(II) Ions of Three Ligands Joining 3-Hydroxy-2-pyridinone and Polyaza Fragments Gianluca Ambrosi, Mauro Formica, Vieri Fusi, Luca Giorgi, Annalisa Guerri, Simone Lucarini, Mauro Micheloni, Paola Paoli, Patrizia Rossi, and Giovanni Zappia pp 3249 - 3260; DOI: 10.1021/ic0484607 |
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Mixed-Metal Cluster Chemistry. 28. Core Enlargement of Tungsten-Iridium Clusters with Alkynyl, Ethyndiyl, and Butadiyndiyl Reagents Gulliver T. Dalton, Lydie Viau, Susan M. Waterman, Mark G. Humphrey, Michael I. Bruce, Paul J. Low, Rachel L. Roberts, Anthony C. Willis, George A. Koutsantonis, Brian W. Skelton, and Allan H. White pp 3261 - 3269; DOI: 10.1021/ic050040+ |
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Synthesis, Structures, and Magnetic Properties of Tri- and Dinuclear Copper(II)-Gadolinium(III) Complexes of Linear Oligooxime Ligands Shigehisa Akine, Takashi Matsumoto, Takanori Taniguchi, and Tatsuya Nabeshima pp 3270 - 3274; DOI: 10.1021/ic0481677 |
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Auration, Argentation, and Mercuration Reactions of an Iridaphosphirene Markus Brym, Cameron Jones, and James D. E. T. Wilton-Ely pp 3275 - 3282; DOI: 10.1021/ic048532u |
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Characterization of the Low-Energy Electronic Excited States of Benzoyl-Substituted Ruthenocenes Cynthia T. Sanderson, Jessica A. Quinlan, Richard C. Conover, Michael K. Johnson, Michael Murphy, Richard A. Dluhy, and Charles Kutal pp 3283 - 3289; DOI: 10.1021/ic0482178 |
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Platinum(II) and Palladium(II) Complexes of Bisphosphine Ligands Bearing o-N,N-Dimethylanilinyl Substituents: A Hint of Catalytic Olefin Hydration Nathan D. Jones, Patric Meessen, Udo Losehand, Brian O. Patrick, and Brian R. James pp 3290 - 3298; DOI: 10.1021/ic048639h |
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Sparkle Model for the Calculation of Lanthanide Complexes: AM1 Parameters for Eu(III), Gd(III), and Tb(III) Ricardo O. Freire, Gerd B. Rocha, and Alfredo M. Simas pp 3299 - 3310; DOI: 10.1021/ic048530+ |
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Copper-Zinc Superoxide Dismutase: Theoretical Insights into the Catalytic Mechanism Vladimir Pelmenschikov and Per E. M. Siegbahn pp 3311 - 3320; DOI: 10.1021/ic050018g |
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Zinc Complex Chemistry of N,N,O Ligands Providing a Hydrophobic Cavity Florian Gross and Heinrich Vahrenkamp pp 3321 - 3329; DOI: 10.1021/ic050042u |
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Syntheses, Crystal Structures, and Magnetic Properties of Novel Manganese(II) Complexes with Flexible Tripodal Ligand 1,3,5-Tris(imidazol-1-ylmethyl)-2,4,6-trimethylbenzene Wei Zhao, You Song, Taka-aki Okamura, Jian Fan, Wei-Yin Sun, and Norikazu Ueyama pp 3330 - 3336; DOI: 10.1021/ic048816e |
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Synthesis, Structural Characterization, and Magnetic Studies of Polynuclear Iron Complexes with a New Disubstituted Pyridine Ligand Hayley A. Burkill, Neil Robertson, Ramón Vilar, Andrew J. P. White, and David J. Williams pp 3337 - 3346; DOI: 10.1021/ic048620e |
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Redox-Active Dithiafulvenyldiphenylphosphine as a Mono- or Bidentate Ligand: Intramolecular Coupling Reaction in the Coordination Sphere of a Metal Carbonyl Fragment Michel Guerro, Thierry Roisnel, Pascal Pellon, and Dominique Lorcy pp 3347 - 3355; DOI: 10.1021/ic0501465 |
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Gas-Phase Reactivity of Heterobinuclear Oxometalate Anions [CrMoO6(OR)]-, [CrWO6(OR)]-, and [MoWO6(OR)]- (R = H, nBu) Tom Waters, Richard A. J. O'Hair, and Anthony G. Wedd pp 3356 - 3366; DOI: 10.1021/ic050288z |
Issue 10
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A Monomeric Thallium(I) Amide in the Solid State: Synthesis and Structure of TlN(Me)ArMes2 (ArMes2 = C6H3-2,6-Mes2) Robert J. Wright, Marcin Brynda, and Philip P. Power pp 3368 - 3370; DOI: 10.1021/ic0500255 |
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A Unique Cyanide-Bridged Three-Dimensional (3-D) Copper(II)-Copper(I) Mixed-Valence Polymer Containing 1-D Water Tapes with Cyclic Pentamer Units Ji-Min Zheng, Stuart R. Batten, and Miao Du pp 3371 - 3373; DOI: 10.1021/ic0483491 |
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The First Cobalt Metallacrowns: Preparation and Characterization of Mixed-Valence Cobalt(II/III), Inverse 12-Metallacrown-4 Complexes Theocharis C. Stamatatos, Stavroula Dionyssopoulou, Georgios Efthymiou, Panayotis Kyritsis, Catherine P. Raptopoulou, Aris Terzis, Ramon Vicente, Albert Escuer, and Spyros P. Perlepes pp 3374 - 3376; DOI: 10.1021/ic050208r |
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One-Dimensional Chain of Tetranuclear Manganese Single-Molecule Magnets Jae Yoo, Wolfgang Wernsdorfer, En-Che Yang, Motohiro Nakano, Arnold L. Rheingold, and David N. Hendrickson pp 3377 - 3379; DOI: 10.1021/ic048212a |
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A Straightforward Synthesis of Diverse Nickel Dithiolene Complexes Appended with Hydrogen-Bond Donor/Acceptor Groups Stéphane A. Baudron, Narcis Avarvari, and Patrick Batail pp 3380 - 3382; DOI: 10.1021/ic050174n |
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Evidence for Static Quenching of MLCT Excited States by Iodide Christopher C. Clark, Andras Marton, and Gerald J. Meyer pp 3383 - 3385; DOI: 10.1021/ic050077u |
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A 3-D Noninterpenetrating Diamondoid Network of a Decanuclear Copper(I) Complex Jian-Kai Cheng, Yu-Biao Chen, Ling Wu, Jian Zhang, Yi-Hang Wen, Zhao-Ji Li, and Yuan-Gen Yao pp 3386 - 3388; DOI: 10.1021/ic050301f |
Magnetic Polyoxometalates: Anisotropic Exchange Interactions in the  Moiety of [(NaOH2)Co3(H2O)(P2W15O56)2]17-Juan Modesto Clemente-Juan, Eugenio Coronado, Alejandro Gaita-Ariño, Carlos Giménez-Saiz, Hans-Ulrich Güdel, Andreas Sieber, Roland Bircher, and Hannu Mutka pp 3389 - 3395; DOI: 10.1021/ic048552w |
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Electropolymerization of Vinylbipyridine Complexes of Ruthenium(II) and Osmium(II) in SiO2 Sol-Gel Films John Yang, Milan Sykora, and Thomas J. Meyer pp 3396 - 3404; DOI: 10.1021/ic048623r |
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Use of Phosphorus Ligand NMR Probes To Investigate Electronic and Second-Sphere Solvent Effects in Ligand Substitution Reactions at Manganese(II) and Manganese(III) Jack S. Summers, Karel Base, Hakim Boukhalfa, Jason E. Payne, Barbara Ramsay Shaw, and Alvin L. Crumbliss pp 3405 - 3411; DOI: 10.1021/ic048618n |
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Influence of a Gold(I)-Acetylide Subunit on the Photophysics of Re(Phen)(CO)3Cl Irina E. Pomestchenko, Dmitry E. Polyansky, and Felix N. Castellano pp 3412 - 3421; DOI: 10.1021/ic048376r |
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An Asymmetric Dizinc Phosphodiesterase Model with Phenolate and Carboxylate Bridges Jingwen Chen, Xiaoyong Wang, Yangguang Zhu, Jun Lin, Xiaoliang Yang, Yizhi Li,, Yi Lu, and Zijian Guo pp 3422 - 3430; DOI: 10.1021/ic048654m |
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Titanium(IV) Citrate Speciation and Structure under Environmentally and Biologically Relevant Conditions Joseph M. Collins, Ritika Uppal, Christopher D. Incarvito, and Ann M. Valentine pp 3431 - 3440; DOI: 10.1021/ic048158y |
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Synthesis and Structural Characterization of Some Selenoruthenates and Telluroruthenates Sergey M. Dibrov, Bin Deng, Donald E. Ellis, and James A. Ibers pp 3441 - 3448; DOI: 10.1021/ic0483646 |
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Silylchalcogenolates MESiRtBu2 (M = Na, Cu, Zn, Fe; E = S, Se, Te; R = tBu, Ph) and Disilyldichalcogenides tBu2RSiE-ESiRtBu2 (E = S, Se, Te; R = tBu, Ph): Synthesis, Properties, and Structures Theresa I. Kückmann, Melina Hermsen, Michael Bolte, Matthias Wagner, and Hans-Wolfram Lerner pp 3449 - 3458; DOI: 10.1021/ic048710j |
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Multielectron Donors Based on TTF-Phosphine and Ferrocene-Phosphine Hybrid Complexes of a Hexarhenium(III) Octahedral Cluster Core Sandrine Perruchas, Narcis Avarvari, David Rondeau, Eric Levillain, and Patrick Batail pp 3459 - 3465; DOI: 10.1021/ic0486217 |
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Metal-Metal Interactions in Platinum(II)/Gold(I) or Platinum(II)/Silver(I) Salts Containing Planar Cations and Linear Anions Jay R. Stork, Daniel Rios, David Pham, Vincent Bicocca, Marilyn M. Olmstead, and Alan L. Balch pp 3466 - 3472; DOI: 10.1021/ic048333a |
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Aerobic Catechol Oxidation Catalyzed by a Bis(-oxo)dimanganese(III,III) Complex via a Manganese(II)-Semiquinonate Complex Yutaka Hitomi, Akira Ando, Hajime Matsui, Tomoyuki Ito, Tsunehiro Tanaka, Seiji Ogo, and Takuzo Funabiki pp 3473 - 3478; DOI: 10.1021/ic050109d |
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Synthesis and Properties of Calcium Alanate and Two Solvent Adducts Maximilian Fichtner, Christoph Frommen, and Olaf Fuhr pp 3479 - 3484; DOI: 10.1021/ic048291q |
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The Reaction between ZnO and Molten Na2S2O7 or K2S2O7 Forming Na2Zn(SO4)2 or K2Zn(SO4)2, Studied by Raman Spectroscopy and X-ray Diffraction Rolf W. Berg and Niels Thorup pp 3485 - 3493; DOI: 10.1021/ic0500513 |
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Synthesis and Characterization of a Twin Cubane-Type Molybdenum-Rhodium-Sulfur Cluster, [{Mo3RhCp*S4(H2O)7(O)}2]8+. X-ray Structure of [{Mo3RhCp*S4(H2O)7(O)}2](CH3C6H4SO3)8·14H2O Haruo Akashi, Kiyoshi Isobe, and Takashi Shibahara pp 3494 - 3498; DOI: 10.1021/ic048733y |
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Effect of 2-(2-Pyridyl)azole-Based Ancillary Ligands (L1-4) on the Electrophilicity of the Nitrosyl Function in [RuII(trpy)(L1-4)(NO)]3+ [trpy = 2,2':6',2' '-Terpyridine]. Synthesis, Structures, and Spectroscopic, Electrochemical, and Kinetic Aspects Nripen Chanda, Debamita Paul, Sanjib Kar, Shaikh M. Mobin, Anindya Datta, Vedavati G. Puranik, K. Krishnamurthy Rao, and Goutam Kumar Lahiri pp 3499 - 3511; DOI: 10.1021/ic048184w |
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New Hydrothermal Synthesis and Structure of Th2(PO4)2(HPO4)·H2O: the First Structurally Characterized Thorium Hydrogenphosphate Miguel A. Salvadó, Pilar Pertierra, Anatoly I. Bortun, Camino Trobajo, and José R. García pp 3512 - 3517; DOI: 10.1021/ic048216f |
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Zinc-Thiolate Complexes of the Bis(pyrazolyl)(thioimidazolyl)hydroborate Tripods for the Modeling of Thiolate Alkylating Enzymes Mian Ji, Boumahdi Benkmil, and Heinrich Vahrenkamp pp 3518 - 3523; DOI: 10.1021/ic0484147 |
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Syntheses, Structures, and Magnetic Properties of Diphenoxo-Bridged MIILnIII Complexes Derived from N,N'-Ethylenebis(3-ethoxysalicylaldiimine) (M = Cu or Ni; Ln = Ce-Yb): Observation of Surprisingly Strong Exchange Interactions Rajesh Koner, Hsin-Huang Lin, Ho-Hsiang Wei, and Sasankasekhar Mohanta pp 3524 - 3536; DOI: 10.1021/ic048196h |
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OH Functionality of Germanium(II) Compounds for the Formation of Heterobimetallic Oxides Leslie W. Pineda, Vojtech Jancik, Herbert W. Roesky, and Regine Herbst-Irmer pp 3537 - 3540; DOI: 10.1021/ic048383f |
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Catalytic and Direct Oxidation of Cysteine by Octacyanomolybdate(V) Meiling Hung and David M. Stanbury pp 3541 - 3550; DOI: 10.1021/ic050427c |
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Complexes of Functionalized Dipyrido[3,2-a:2',3'-c]-phenazine: A Synthetic, Spectroscopic, Structural, and Density Functional Theory Study Natasha J. Lundin, Penny J. Walsh, Sarah L. Howell, John J. McGarvey, Allan G. Blackman, and Keith C. Gordon pp 3551 - 3560; DOI: 10.1021/ic050179k |
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Separation and Characterization of the Two Diastereomers for [Gd(DTPA-bz-NH2)(H2O)]2-, a Common Synthon in Macromolecular MRI Contrast Agents: Their Water Exchange and Isomerization Kinetics László Burai, Éva Tóth, Angélique Sour, and André E. Merbach pp 3561 - 3568; DOI: 10.1021/ic048645d |
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Influence of Steric and Electronic Properties of the Defect Site, Lanthanide Ionic Radii, and Solution Conditions on the Composition of Lanthanide(III) 1-P2W17O6110- Polyoxometalates Cheng Zhang, Robertha C. Howell, Qun-Hui Luo, Heidi L. Fieselmann, Louis J. Todaro, and Lynn C. Francesconi pp 3569 - 3578; DOI: 10.1021/ic050103o |
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Density Functional Theory Study of 11-Atom Germanium Clusters: Effect of Electron Count on Cluster Geometry R. B. King, I. Silaghi-Dumitrescu, and A. Lupan pp 3579 - 3588; DOI: 10.1021/ic040110x |
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Analysis of the Refractive Indices of TiO2, TiOF2, and TiF4: Concept of Optical Channel as a Guide To Understand and Design Optical Materials Xavier Rocquefelte, Fabrice Goubin, Yvan Montardi, Nicolas Viadere, Alain Demourgues, Alain Tressaud, Myung-Hwan Whangbo, and Stéphane Jobic pp 3589 - 3593; DOI: 10.1021/ic048259w |
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Structural and Electronic Factors Controlling the Refractive Indices of the Chalcogenides ZnQ and CdQ (Q = O, S, Se, Te) Xavier Rocquefelte, Myung-Hwan Whangbo, and Stéphane Jobic pp 3594 - 3598; DOI: 10.1021/ic048352k |
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Three-, Two-, and One-Dimensional Metal Phosphonates Based on [Hydroxy(4-pyridyl)methyl]phosphonate: M{(4-C5H4N)CH(OH)PO3}(H2O) (M = Ni, Cd) and Gd{(4-C5H4N)CH(OH)P(OH)O2}3·6H2O Deng-Ke Cao, Yi-Zhi Li, You Song, and Li-Min Zheng pp 3599 - 3604; DOI: 10.1021/ic0484248 |
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Spectroscopic and Computational Studies on [Ni(tmc)CH3]OTf: Implications for Ni-Methyl Bonding in the A Cluster of Acetyl-CoA Synthase Ralph Schenker, Michael T. Mock, Matthew T. Kieber-Emmons, Charles G. Riordan, and Thomas C. Brunold pp 3605 - 3617; DOI: 10.1021/ic0483996 |
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A Second-Order Nonlinear Optical Material Prepared through In Situ Hydrothermal Ligand Synthesis Qiong Ye, Yong-Hua Li, Yu-Mei Song, Xue-Feng Huang, Ren-Gen Xiong, and Ziling Xue pp 3618 - 3625; DOI: 10.1021/ic0500098 |
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Multinuclear Fe(III) Complexes with Polydentate Ligands of the Family of Dicarboxyimidazoles: Nuclearity- and Topology-Controlled Syntheses and Magneto-Structural Correlations Panagiotis Angaridis, Jeff W. Kampf, and Vincent L. Pecoraro pp 3626 - 3635; DOI: 10.1021/ic0481879 |
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Square Planar vs Tetrahedral Coordination in Diamagnetic Complexes of Nickel(II) Containing Two Bidentate -Radical Monoanions Sebastien Blanchard, Frank Neese, Eberhard Bothe, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardt pp 3636 - 3656; DOI: 10.1021/ic040117e |
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Iminic N-Bound Iminophosphorano versus Nitrilic N-Bound Iminophosphorano Os(IV) Complexes: A New Double Derivatization of the Nitrido Ligand My Hang V. Huynh, Thomas J. Meyer, and Donald L. Jameson pp 3657 - 3663; DOI: 10.1021/ic050203u |
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Acetic Acid Induced Self-Assembly of Supramolecular Compounds [Et4N]3[(WS4Cu2)2(-CN)3]·2MeCN and [PPh4][WS4Cu3(-CN)2]·MeCN from Preformed Clusters [A]2[WS4(CuCN)2] (A = Et4N, PPh4) Jian-Ping Lang, Chang-Mei Jiao, Shan-Bao Qiao, Wen-Hua Zhang, and Brendan F. Abrahams pp 3664 - 3668; DOI: 10.1021/ic048224w |
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Synthesis, Structure, and Characterization of New Mononuclear Mn(II) Complexes. Electrochemical Conversion into New Oxo-Bridged Mn2(III,IV) Complexes. Role of Chloride Ions Christelle Hureau, Geneviève Blondin, Marie-France Charlot, Christian Philouze, Martine Nierlich, Michèle Césario, and Elodie Anxolabéhère-Mallart pp 3669 - 3683; DOI: 10.1021/ic050243y |
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La9Sb16Br3 and Ce9Sb16Cl3: Stars and Stripes in Rare Earth Halide and Intermetallic Compounds Chong Zheng, Hansjürgen Mattausch, and Arndt Simon pp 3684 - 3689; DOI: 10.1021/ic049220u |
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Rhenium(V) Complexes with Thiolato and Dithiolato Ligands: Synthesis, Structures, and Monomerization Reactions Ming Li, Arkady Ellern, and James H. Espenson pp 3690 - 3699; DOI: 10.1021/ic0501871 |
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High-Valent Imido Complexes of Manganese and Chromium Corroles Nicola Y. Edwards, Rebecca A. Eikey, Megan I. Loring, and Mahdi M. Abu-Omar pp 3700 - 3708; DOI: 10.1021/ic0484506 |
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Structural Characterization of Four Members of the Electron-Transfer Series [PdII(L)2)2]n (L = o-Iminophenolate Derivative; n = 2-, 1-, 0, 1+, 2+). Ligand Mixed Valency in the Monocation and Monoanion with S = 1/2 Ground States Swarnalatha Kokatam, Thomas Weyhermüller, Eberhard Bothe, Phalguni Chaudhuri, and Karl Wieghardt pp 3709 - 3717; DOI: 10.1021/ic048292i |
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Self-Assembly of Chiral Coordination Polymers and Macrocycles: A Metal Template Effect on the Polymer-Macrocycle Equilibrium Tara J. Burchell and Richard J. Puddephatt pp 3718 - 3730; DOI: 10.1021/ic050097w |
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A Series of Single, Double, and Triple Me2biim-Bridged Dinuclear, Trinuclear, and Polymeric Complexes: Syntheses, Crystal Structures, and Luminescent Properties Ruili Sang and Li Xu pp 3731 - 3737; DOI: 10.1021/ic048280x |
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Kinetic and Thermodynamic Characterization of the Cobalt and Manganese Oxyhydroxide Cores Formed in Horse Spleen Ferritin Bo Zhang, John N. Harb, Robert C. Davis, Jae-Woo Kim, Sang-Hyon Chu, Sang Choi, Tim Miller, and Gerald D. Watt pp 3738 - 3745; DOI: 10.1021/ic049085l |
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Structural Increments for 11-Vertex nido-Phospha- and Aza(carba)boranes and -borates; Dependence of Energy Penalties on the Extent of Electron Localization Farooq A. Kiani and Matthias Hofmann pp 3746 - 3754; DOI: 10.1021/ic0483803 |
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Synthesis, Structure, and Thermal Properties of Soluble Hydrazinium Germanium(IV) and Tin(IV) Selenide Salts David B. Mitzi pp 3755 - 3761; DOI: 10.1021/ic048276l |
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Low-Dimensional Ferromagnetic Properties of SrCuV2O7 and BaCuV2O7 Alexei A. Belik, Masaki Azuma, Akira Matsuo, Koichi Kindo, and Mikio Takano pp 3762 - 3766; DOI: 10.1021/ic050164m |
Issue 11
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Cleavage of Hydrazine N-N Bonds by RuMo3S4 Cubane-Type Clusters Izuru Takei, Keita Dohki, Koji Kobayashi, Toshiaki Suzuki, and Masanobu Hidai pp 3768 - 3770; DOI: 10.1021/ic0500560 |
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[Ni(cyclam)(1,3-dca)2Cu(1,5-dca)2]: A Genuine 3D Bimetallic Coordination Polymer Containing Both 1,3- and 1,5-Bidentate Dicyanamide Bridges and a Ferromagnetic Interaction between Copper(II) and Nickel(II) Ions Enrique Colacio, Ikram Ben Maimoun, Francesc Lloret, and José Suárez-Varela pp 3771 - 3773; DOI: 10.1021/ic050369v |
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Oxygen-Induced Ligand Dehydrogenation of a Planar Bis--Chloronickel(I) Dimer Featuring an NHC Ligand Benjamin R. Dible, Matthew S. Sigman, and Atta M. Arif pp 3774 - 3776; DOI: 10.1021/ic050445u |
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N-H···S Hydrogen Bonds in a Ferredoxin Model Marc A. Walters, Cara L. Roche, Arnold L. Rheingold, and Scott W. Kassel pp 3777 - 3779; DOI: 10.1021/ic048208z |
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Tuning the Reactivity of Dioxoruthenium(VI) Porphyrins toward an Arylimine by Altering Porphyrin Substituents Jie-Sheng Huang, Sarana Ka-Yan Leung, Zhong-Yuan Zhou, Nianyong Zhu, and Chi-Ming Che pp 3780 - 3788; DOI: 10.1021/ic0484102 |
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Electrochemistry of [(TMpyP)MII]4+(X-)4 (X- = Cl- or BPh4-) and [(TMpyP)MIIICl]4+(Cl-)4 in N,N-Dimethylformamide Where M Is One of 15 Different Metal Ions E. Van Caemelbecke, A. Derbin, P. Hambright, Rachel Garcia, Anass Doukkali, Ahmed Saoiabi, K. Ohkubo, S. Fukuzumi, and K. M. Kadish pp 3789 - 3798; DOI: 10.1021/ic048820q |
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Substituent-Directed Structural and Physicochemical Controls of Diruthenium Catecholate Complexes with Ligand-Unsupported Ru-Ru Bonds Ho-Chol Chang, Katsunori Mochizuki, and Susumu Kitagawa pp 3799 - 3809; DOI: 10.1021/ic048251m |
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Effects of Countercations on the Structures and Redox and Spectroscopic Properties of Diruthenium Catecholate Complexes with Ligand-Unsupported Ru-Ru Bonds Ho-Chol Chang, Katsunori Mochizuki, and Susumu Kitagawa pp 3810 - 3817; DOI: 10.1021/ic048250u |
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Definitive Assignments of the Visible-Near-IR Bands of Porphyrin-Naphthalocyanine Rare-Earth Sandwich Double- and Triple-Decker Compounds by Magnetic Circular Dichroism Spectroscopy Atsuya Muranaka, Yotaro Matsumoto, Masanobu Uchiyama, Jianzhuang Jiang, Yongzhong Bian, Arnout Ceulemans, and Nagao Kobayashi pp 3818 - 3826; DOI: 10.1021/ic0502325 |
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Single-Molecule Magnets: High-Field Electron Paramagnetic Resonance Evaluation of the Single-Ion Zero-Field Interaction in a ZnII3NiII Complex En-Che Yang, Cem Kirman, Jon Lawrence, Lev N. Zakharov, Arnold L. Rheingold, Stephen Hill, and David N. Hendrickson pp 3827 - 3836; DOI: 10.1021/ic0482279 |
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The Role of Amine Sulfates in Hydrothermal Uranium Chemistry Alexander J. Norquist, Michael B. Doran, and Dermot O'Hare pp 3837 - 3843; DOI: 10.1021/ic0484452 |
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Ni11As8 Single-Crystalline Nanosheets via Hydrothermal Redox Route Shuo Wei, Jun Lu, Weichao Yu, Houbo Zhang, and Yitai Qian pp 3844 - 3849; DOI: 10.1021/ic048448e |
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Synthesis, Structure and Luminescent Properties of Rare Earth Coordination Polymers Constructed from Paddle-Wheel Building Blocks Xiaodan Guo, Guangshan Zhu, Qianrong Fang, Ming Xue, Ge Tian, Jinyu Sun, Xiaotian Li, and Shilun Qiu pp 3850 - 3855; DOI: 10.1021/ic0500457 |
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Mn(II) Staircase Structures Stitched by Water Clusters to a 3D Metal-Organic Open Framework: X-ray Structural and Magnetic Studies Sujit K. Ghosh, Joan Ribas, M. Salah El Fallah, and Parimal K. Bharadwaj pp 3856 - 3862; DOI: 10.1021/ic050102w |
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Redox Site Confinement in Highly Unsymmetric Dimanganese Complexes Tianlu Sheng, Sebastian Dechert, Isabella Hyla-Kryspin, Rainer F. Winter, and Franc Meyer pp 3863 - 3874; DOI: 10.1021/ic0503683 |
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[Os(bpy)2(CO)(enIA)][OTf]2: A Novel Sulfhydryl-Specific Metal-Ligand Complex Claudio Garino, Simona Ghiani, Roberto Gobetto, Carlo Nervi, Luca Salassa, Valentina Ancarani, Paolo Neyroz, Laurie Franklin, J. B. Alexander Ross, and Eleanore Seibert pp 3875 - 3879; DOI: 10.1021/ic048452q |
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Copper(II) Mediated Anion Dependent Formation of Schiff Base Complexes Sachindranath Pal, Anil Kumar Barik, Samik Gupta, Arijit Hazra, Susanta Kumar Kar, Shie-Ming Peng, Gene-Hsiang Lee, Ray J. Butcher, M. Salah El Fallah, and Joan Ribas pp 3880 - 3889; DOI: 10.1021/ic0501420 |
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First Hydrotalcite-like Sulfonate Coordination Network Incorporating Robust Cationic Layers and Flexible Interlayer Interactions Yufeng Liu, Jiachun Su, Weihong Li, and Jinguang Wu pp 3890 - 3895; DOI: 10.1021/ic0501418 |
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Self-Assembly and Interconversion of Tetranuclear Copper(II) Complexes Katharina Isele, Patrick Franz, Christina Ambrus, Gérald Bernardinelli, Silvio Decurtins, and Alan F. Williams pp 3896 - 3906; DOI: 10.1021/ic0500762 |
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Coordination Polymers of Copper(I) Halides and Neutral Heterocyclic Thiones with New Coordination Modes Dan Li, Wen-Juan Shi, and Lei Hou pp 3907 - 3913; DOI: 10.1021/ic050209j |
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High-Temperature, High-Pressure Hydrothermal Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of Cs2(UO2)(Si2O6) and Variable-Temperature Powder X-ray Diffraction Study of the Hydrate Phase Cs2(UO2)(Si2O6)·0.5H2O Chih-Shan Chen, Ray-Kuang Chiang, Hsien-Ming Kao, and Kwang-Hwa Lii pp 3914 - 3918; DOI: 10.1021/ic0500199 |
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Mixed-Metal Tellurites: Synthesis, Structure, and Characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16 Kang Min Ok and P. Shiv Halasyamani pp 3919 - 3925; DOI: 10.1021/ic050256b |
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UV-Blocking Property of Dumbbell-Shaped ZnO Crystallites on Cotton Fabrics R. H. Wang, J. H. Xin, and X. M. Tao pp 3926 - 3930; DOI: 10.1021/ic0503176 |
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Mechanism of Oxidation of Benzaldehyde by Polypyridyl Oxo Complexes of Ru(IV) Won K. Seok and Thomas J. Meyer pp 3931 - 3941; DOI: 10.1021/ic040119z |
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Chiral Osmium Complexes with Sterically Bulky Schiff-Base Ligands. Crystal Structures of Os(IV) Derivatives and the Reactivity and Catalytic Cyclopropanation of Alkenes with EDA Jing Zhang, Jiang-Lin Liang, Xian-Ru Sun, Hai-Bing Zhou, Nian-Yong Zhu, Zhong-Yuan Zhou, Philip Wai Hong Chan, and Chi-Ming Che pp 3942 - 3954; DOI: 10.1021/ic0481935 |
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Hydrothermal Syntheses and Structures of Two Mixed-Valence Copper(I,II) 2-Pyrazinecarboxylate Coordination Polymers Xian-Ming Zhang and Rui-Qin Fang pp 3955 - 3959; DOI: 10.1021/ic050118m |
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Synthesis and Crystallographic Characterization of Low-Dimensional and Porous Coordination Compounds Capable of Supramolecular Aromatic Interaction Using the 4,4'-Azobis(pyridine) Ligand Shin-ichiro Noro, Susumu Kitagawa, Takayoshi Nakamura, and Tatsuo Wada pp 3960 - 3971; DOI: 10.1021/ic048371u |
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Heterobimetallic Complexes of Cobalt(IV) Porphyrin-Corrole Dyads. Synthesis, Physicochemical Properties, and X-ray Structural Characterization Roger Guilard, Fabien Burdet, Jean-Michel Barbe, Claude P. Gros, Enrique Espinosa, Jianguo Shao, Zhongping Ou, Riqiang Zhan, and Karl M. Kadish pp 3972 - 3983; DOI: 10.1021/ic0501622 |
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Isotropic Magnetic Exchange between Anisotropic Yb(III) Ions. Study of Cs3Yb2Cl9 and Cs3Yb2Br9 Crystals Andrei V. Palii, Boris S. Tsukerblat, Juan M. Clemente-Juan, and Eugenio Coronado pp 3984 - 3992; DOI: 10.1021/ic0482382 |
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Facile Syntheses of Unsolvated UI3 and Tetramethylcyclopentadienyl Uranium Halides William J. Evans, Stosh A. Kozimor, Joseph W. Ziller, Anatolii A. Fagin, and Mikhail N. Bochkarev pp 3993 - 4000; DOI: 10.1021/ic0482685 |
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Solution and Solid-State Variation of Cupric Phenanthroline Complexes Jason A. Aligo, Laura Smith, Judith L. Eglin, and Laura E. Pence pp 4001 - 4007; DOI: 10.1021/ic049069o |
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Inorganic-Organic Hybrids Formed by P,P'-Diphenylmethylenediphosphinate, pcp2-, with the Cu2+ Ion. X-ray Crystal Structures of [Cu(pcp)(H2O)2]·H2O and [Cu(pcp)(bipy)(H2O)] Samuele Ciattini, Ferdinando Costantino, Pablo Lorenzo-Luis, Stefano Midollini, Annabella Orlandini, and Alberto Vacca pp 4008 - 4016; DOI: 10.1021/ic050171a |
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Outer-Sphere Association of p-Sulfonatothiacalix[4]arene and Tetrasulfonatomethylated Calix[4]resorcinarene with Cobalt(III) Tris(dipyridyl): The Effect on the Spectral and Electrochemical Properties of the Latter Asiya R. Mustafina, Viktoriya V. Skripacheva, Aidar T. Gubaidullin, Shamil K. Latipov, Asiya V. Toropchina, Vitaly V. Yanilkin, Svetlana E. Solovieva, Igor S. Antipin, and Alexander I. Konovalov pp 4017 - 4023; DOI: 10.1021/ic050038i |
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Theoretical Reduction Potentials for Nitrogen Oxides from CBS-QB3 Energetics and (C)PCM Solvation Calculations Andrew S. Dutton, Jon M. Fukuto, and Kendall N. Houk pp 4024 - 4028; DOI: 10.1021/ic048734q |
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Reversible Luminescence Switching in a Ruthenium(II) Bis(2,2':6',2' '-terpyridine)-Benzoquinone Dyad Andrew C. Benniston, Glen M. Chapman, Anthony Harriman, and Sarah A. Rostron pp 4029 - 4036; DOI: 10.1021/ic050059c |
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Relation between Intramolecular NH···S Hydrogen Bonds and Coordination Number in Mercury(II) Complexes with Carbamoylbenzenethiol Derivatives Masahiro Kato, Kazunori Kojima, Taka-aki Okamura, Hitoshi Yamamoto, Takeshi Yamamura, and Norikazu Ueyama pp 4037 - 4044; DOI: 10.1021/ic0481780 |
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Novel Rhenium(V) Oxo Complexes Containing Bis(pyrazol-1-yl)acetate and Bis(pyrazol-1-yl) Sulfonate as Tripodal N,N,O-heteroscorpionate Ligands Marina Porchia, Grazia Papini, Carlo Santini, Giancarlo Gioia Lobbia, Maura Pellei, Francesco Tisato, Giuliano Bandoli, and Alessandro Dolmella pp 4045 - 4054; DOI: 10.1021/ic050193x |
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Synthesis, Photophysics, and Optical Limiting of Platinum(II) 4'-Tolylterpyridyl Arylacetylide Complexes Fengqi Guo, Wenfang Sun, Yao Liu, and Kirk Schanze pp 4055 - 4065; DOI: 10.1021/ic049266n |
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Conformational Control of Excited-State Dynamics in Highly Distorted Ru(II) Polypyridyl Complexes Sherri A. McFarland, Douglas Magde, and Nathaniel S. Finney pp 4066 - 4076; DOI: 10.1021/ic0502729 |
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New Structural Motifs, Unusual Quenching of the Emission, and Second Harmonic Generation of Copper(I) Iodide Polymeric or Oligomeric Adducts with Para-Substituted Pyridines or trans-Stilbazoles Elena Cariati, Dominique Roberto, Renato Ugo, Peter C. Ford, Simona Galli, and Angelo Sironi pp 4077 - 4085; DOI: 10.1021/ic050143s |
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New Magnetic Copper(II) Coordination Polymers with the Polynitrile Ligand (C[C(CN)2]3)2- and N-Donor Co-ligands Smaïl Triki, Franck Thétiot, Fanny Vandevelde, Jean Sala-Pala, and Carlos J. Gómez-García pp 4086 - 4093; DOI: 10.1021/ic050235h |
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Sequential Protonation and Methylation of a Hydride-Osmium Complex Containing a Cyclopentadienyl Ligand with a Pendant Amine Group Miguel A. Esteruelas, Ana M. López, Enrique Oñate, and Eva Royo pp 4094 - 4103; DOI: 10.1021/ic0502933 |
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Influence of Pt Nanocrystallinity on Electrochromism of TiO2 Kyung-Won Park  and Yung-Eun Sung*, :pp 4104 - 4104; DOI: 10.1021/ic058002d |
Issue 12
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Reduction of Tris(benzene-1,2-dithiolate)molybdenum(VI) by Water. A Functional Mo-Hydroxylase Analogue System Antonio Cervilla, Francisco Pérez-Pla, Elisa Llopis, and María Piles pp 4106 - 4108; DOI: 10.1021/ic0483242 |
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Protein-Surfactant Film Voltammetry of Wild-Type and Mutant Cytochrome P450 BM3 Andrew K. Udit, Nareen Hindoyan, Michael G. Hill, Frances H. Arnold, and Harry B. Gray pp 4109 - 4111; DOI: 10.1021/ic0483747 |
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DNA Mismatch Detection by Resonance Energy Transfer between Ruthenium(II) and Osmium(II) Tris(2,2'-bipyridyl) Chromophores Elena V. Bichenkova, Xuan Yu, Pranab Bhadra, Helena Heissigerova, Simon J. A. Pope, Benjamin J. Coe, Stephen Faulkner, and Kenneth T. Douglas pp 4112 - 4114; DOI: 10.1021/ic050586w |
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Metal-Driven and Covalent Synthesis of Supramolecular Grids from Racks: A Convergent Approach to Heterometallic and Heteroleptic Nanostructures Michael Schmittel, Venkateshwarlu Kalsani, and Jan W. Bats pp 4115 - 4117; DOI: 10.1021/ic050088n |
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(S)-(2-(2'-Pyridyl)ethyl)cysteamine and (S)-(2-(2'-Pyridyl)ethyl)-D,L-homocysteine as Ligands for the "fac-[M(CO)3]+" (M = Re, 99mTc) Core O. Karagiorgou, G. Patsis, M. Pelecanou, C. P. Raptopoulou, A. Terzis, T. Siatra-Papastaikoudi, R. Alberto, I. Pirmettis, and M. Papadopoulos pp 4118 - 4120; DOI: 10.1021/ic050254r |
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Topotactic Oxidation of TiGaPO-1, a Pyridine-Templated Titanium Gallophosphate with a New Octahedral-Tetrahedral 3-D Framework Structure Containing TiIII/TiIV Ann M. Chippindale, Mark R. Grimshaw, Anthony V. Powell, and Andrew R. Cowley pp 4121 - 4123; DOI: 10.1021/ic050399y |
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Room-Temperature Hydrogen Uptake by TiO2 Nanotubes San Hua Lim, Jizhong Luo, Ziyi Zhong, Wei Ji, and Jianyi Lin pp 4124 - 4126; DOI: 10.1021/ic0501723 |
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Group 10 Metal Complexes of meso-Aryl-Substituted [26]Hexaphyrins with a Metal-Carbon Bond Shigeki Mori, Soji Shimizu, Ryuichiro Taniguchi, and Atsuhiro Osuka pp 4127 - 4129; DOI: 10.1021/ic050447e |
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Two Novel Nanoporous Supramolecular Architectures Based on Copper(I) Coordination Polymers with Uniform (8, 3) and (8210) Nets: In Situ Formation of Tetrazolate Ligands Tao Wu, Bi-Hua Yi, and Dan Li pp 4130 - 4132; DOI: 10.1021/ic050063o |
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Synthesis and Crystal Structure of Unprecedented Oxo/Hydroxo-Bridged Polynuclear Gallium(III) Aqua Complexes Olga A. Gerasko, Ekaterina A. Mainicheva, Dmitry Yu. Naumov, Natalia V. Kuratieva, Maxim N. Sokolov, and Vladimir P. Fedin pp 4133 - 4135; DOI: 10.1021/ic0502271 |
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An Unusual Zinc-Promoted Decomposition of a Bis(2-{pyrid-2-yl}ethyl)amine Derivative Q. Folshade Mokuolu, Colin A. Kilner, Simon A. Barrett, Patrick C. McGowan, and Malcolm A. Halcrow pp 4136 - 4138; DOI: 10.1021/ic050270o |
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Self-Assembly of Heteroleptic [Cu(dipyrrinato)(hfacac)] Complexes Directed by Fluorine-Fluorine Interactions Sara R. Halper and Seth M. Cohen pp 4139 - 4141; DOI: 10.1021/ic0504442 |
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Crystal Structure and Luminescence of Lanthanide Monodentate Complexes [Ln(C4N4H6O)2(H2O)6]Cl3 and [Ln(C4N4H6O)2(H2O)3(NO3)3] (Ln = Tb or Eu) Ga-Lai Law, Ka-Leung Wong, Xianju Zhou, Wing-Tak Wong, and Peter A. Tanner pp 4142 - 4144; DOI: 10.1021/ic050115+ |
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Highly Electrophilic, 16-Electron [Ru(P(OMe)(OH)2)(dppe)2]2+ Complex Turns H2(g) into a Strong Acid and Splits a Si-H Bond Heterolytically. Synthesis and Structure of the Novel Phosphorous Acid Complex [Ru(P(OH)3)(dppe)2]2+ C. M. Nagaraja, Munirathinam Nethaji, and Balaji R. Jagirdar pp 4145 - 4147; DOI: 10.1021/ic050026x |
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A Solvothermally in Situ Generated Mixed-ligand Approach for NLO-Active Metal-Organic Framework Materials Yong-Tao Wang, Hai-Hua Fan, He-Zhou Wang, and Xiao-Ming Chen pp 4148 - 4150; DOI: 10.1021/ic0504137 |
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Exploratory Synthesis in Molten Salts: Role of Flux Basicity in the Stabilization of the Complex Thiogermanates Cs4Pb4Ge5S16, K2PbGe2S6, and K4Sn3Ge3S14 Oleg Palchik, Gregory M. Marking, and Mercouri G. Kanatzidis pp 4151 - 4153; DOI: 10.1021/ic050087v |
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Synthesis and Structure of Cuboctahedral and Anticuboctahedral Cages Containing 12 Quadruply Bonded Dimolybdenum Units Yanxiong Ke, David J. Collins, and Hong-Cai Zhou pp 4154 - 4156; DOI: 10.1021/ic050460z |
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Chromium(III) Complexes for Photochemical Nitric Oxide Generation from Coordinated Nitrite: Synthesis and Photochemistry of Macrocyclic Complexes with Pendant Chromophores, trans-[Cr(L)(ONO)2]BF4 Frank DeRosa, Xianhui Bu, and Peter C. Ford pp 4157 - 4165; DOI: 10.1021/ic048311o |
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Synthesis and Luminescence Properties of Cr(III) Complexes with Cyclam-Type Ligands Having Pendant Chromophores, trans-[Cr(L)Cl2]Cl1 Frank DeRosa, Xianhui Bu, Kristina Pohaku, and Peter C. Ford pp 4166 - 4174; DOI: 10.1021/ic048312g |
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Is It True Dioxygenase or Classic Autoxidation Catalysis? Re-Investigation of a Claimed Dioxygenase Catalyst Based on a Ru2-Incorporated, Polyoxometalate Precatalyst Cindy-Xing Yin and Richard G. Finke pp 4175 - 4188; DOI: 10.1021/ic050090e |
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Homoleptic, -Bonded Octahedral [M(CO)6]2+ Cations of Iron(II), Ruthenium(II), and Osmium(II): Part 1: Syntheses, Thermochemical and Vibrational Characterizations, and Molecular Structures as [Sb2F11]- and [SbF6]- Salts. A Comprehensive, Comparative Study Eduard Bernhardt, Christian Bach, Bianca Bley, Rudolf Wartchow, Ulrich Westphal, Iona H. T. Sham, Britta von Ahsen, Chanqing Wang, Helge Willner, Robert C. Thompson, and Friedhelm Aubke pp 4189 - 4205; DOI: 10.1021/ic040115u |
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Homoleptic, -Bonded Octahedral Superelectrophilic Metal Carbonyl Cations of Iron(II), Ruthenium(II), and Osmium(II). Part 2: Syntheses and Characterizations of [M(CO)6][BF4]2 (M = Fe, Ru, Os) Maik Finze, Eduard Bernhardt, Helge Willner, Christian W. Lehmann, and Friedhelm Aubke pp 4206 - 4214; DOI: 10.1021/ic0482483 |
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Cobalt(III) Carbonate and Bicarbonate Chelate Complexes of Tripodal Tetraamine Ligands Containing Pyridyl Donors: The Steric Basis for the Stability of Chelated Bicarbonate Complexes Paul M. Jaffray, Lisa F. McClintock, Kay E. Baxter, and Allan G. Blackman pp 4215 - 4225; DOI: 10.1021/ic0482537 |
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Computational Exploration of the Catalytic Mechanism of Dopamine -Monooxygenase: Modeling of Its Mononuclear Copper Active Sites Takashi Kamachi, Naoki Kihara, Yoshihito Shiota, and Kazunari Yoshizawa pp 4226 - 4236; DOI: 10.1021/ic048477p |
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Derivatives of 1,5-Diamino-1H-tetrazole: A New Family of Energetic Heterocyclic-Based Salts Juan Carlos Gálvez-Ruiz, Gerhard Holl, Konstantin Karaghiosoff, Thomas M. Klapötke, Karolin Löhnwitz, Peter Mayer, Heinrich Nöth, Kurt Polborn, Christoph J. Rohbogner, Max Suter, and Jan J. Weigand pp 4237 - 4253; DOI: 10.1021/ic050104g |
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Structural and Photophysical Properties of Lathanide(III) Complexes with a Novel Octadentate Iminophenolate Bibracchial Lariat Ether Marina González-Lorenzo, Carlos Platas-Iglesias, Fernando Avecilla, Stephen Faulkner, Simon J. A. Pope, Andrés de Blas, and Teresa Rodríguez-Blas pp 4254 - 4262; DOI: 10.1021/ic048172a |
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Effect of the Semirigid Capping Ligand on the Structure Formation of Cyano-Bridged Bimetallic Assemblies: Syntheses, Crystal Structures, and Magnetic Properties Xiao-Yan Chen, Wei Shi, Jun Xia, Peng Cheng, Bin Zhao, Hai-Bin Song, Hong-Gen Wang, Shi-Ping Yan, Dai-Zheng Liao, and Zong-Hui Jiang pp 4263 - 4269; DOI: 10.1021/ic050099g |
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Syntheses, Structures, Photoluminescence, and Theoretical Studies of a Class of Beryllium(II) Compounds of Aromatic N,O-Chelate Ligands Yi-Ping Tong, Shao-Liang Zheng, and Xiao-Ming Chen pp 4270 - 4275; DOI: 10.1021/ic0501059 |
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Rhodium Cluster Complexes Containing Bridging Phenylgermanium Ligands Richard D. Adams and Jack L. Smith, Jr. pp 4276 - 4281; DOI: 10.1021/ic050372e |
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Two Halogeno(cyano)cuprates with Long-Lived and Strong Luminescence Xi Liu, Guo-Cong Guo, A-Qing Wu, Li-Zhen Cai, and Jin-Shun Huang pp 4282 - 4286; DOI: 10.1021/ic050315l |
Synthesis, Characterization, and Photophysical Properties of Os(II) Diimine Complexes [Os(N N)(CO)2I2] (NN = Bipyridine, Phenanthroline, and Pyridyl Benzoxazole)Yao-Lun Chen, Shih-Wen Lee, Yun Chi, Kuo-Chu Hwang, Sujit Baran Kumar, Ya-Hui Hu, Yi-Ming Cheng, Pi-Tai Chou, Shie-Ming Peng, Gene-Hsiang Lee, Shi-Jay Yeh, and Chin-Ti Chen pp 4287 - 4294; DOI: 10.1021/ic050036y |
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Anion Binding by a Tetradipicolylamine-Substituted Resorcinarene Cavitand Joseph S. Gardner, Martin Conda-Sheridan, Dana N. Smith, Roger G. Harrison, and John D. Lamb pp 4295 - 4300; DOI: 10.1021/ic048841k |
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Steric Effects in Metathesis and Reduction Reactions of Phosphinimines with Catechol- and Pinacolboranes Sarah Hawkeswood, Pingrong Wei, James W. Gauld, and Douglas W. Stephan pp 4301 - 4308; DOI: 10.1021/ic050230k |
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Syntheses, Structures, and Magnetic Properties of Mixed-Valent Diruthenium(II,III) Diphosphonates with Discrete and One-Dimensional Structures Xiao-Yi Yi, Bin Liu, Reyes Jiménez-Aparicio, Francisco A. Urbanos, Song Gao, Wei Xu, Jie-Sheng Chen, You Song, and Li-Min Zheng pp 4309 - 4314; DOI: 10.1021/ic048340z |
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Synthesis and Spectroscopic Characterization of a New Family of Ni4 Spin Clusters Andreas Sieber, Colette Boskovic, Roland Bircher, Oliver Waldmann, Stefan T. Ochsenbein, Grégory Chaboussant, Hans U. Güdel, Nadeschda Kirchner, Joris van Slageren, Wolfgang Wernsdorfer, Antonia Neels, Helen Stoeckli-Evans, Stefan Janssen, Fanni Juranyi, and Hannu Mutka pp 4315 - 4325; DOI: 10.1021/ic050134j |
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Synthesis, Structure, and Ligand-Based Reduction Reactivity of Trivalent Organosamarium Benzene Chalcogenolate Complexes (C5Me5)2Sm(EPh)(THF) and [(C5Me5)2Sm(-EPh)]2 William J. Evans, Kevin A. Miller, David S. Lee, and Joseph W. Ziller pp 4326 - 4332; DOI: 10.1021/ic0502170 |
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Synthesis, Structure, and Electrochemical Properties of Copper(I) Complexes with S/N Homoscorpionate and Heteroscorpionate Ligands Roberto Cammi, Marcello Gennari, Marco Giannetto, Maurizio Lanfranchi, Luciano Marchiò, Giovanni Mori, Cristiano Paiola, and Maria Angela Pellinghelli pp 4333 - 4345; DOI: 10.1021/ic048221j |
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Ligand Orientation Control in Low-Spin Six-Coordinate (Porphinato)iron(II) Species Chuanjiang Hu, Bruce C. Noll, Charles E. Schulz, and W. Robert Scheidt pp 4346 - 4358; DOI: 10.1021/ic050320p |
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Importance of Supersuperexchange Interactions in Determining the Dimensionality of Magnetic Properties. Determination of Strongly Interacting Spin Exchange Paths in A2Cu(PO4)2 (A = Ba, Sr), ACuP2O7 (Ba, Ca, Sr, Pb), CaCuGe2O6, and Cu2UO2(PO4)2 on the Basis of Qualitative Spin Dimer Analysis H.-J. Koo, D. Dai, and M.-H. Whangbo pp 4359 - 4365; DOI: 10.1021/ic050159i |
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Stability of [RuII(tpy)(bpy)(OH2)]2+-Modified Graphite Electrodes during Indirect Electrolyses Florence Geneste, Claude Moinet, Soraya Ababou-Girard, and Francine Solal pp 4366 - 4371; DOI: 10.1021/ic048231k |
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Proton NMR Spectroscopy and Magnetic Properties of a Solution-Stable Dicopper(II) Complex Bearing a Single -Hydroxo Bridge Iryna A. Koval, Karlijn van der Schilden, Anna Maria Schuitema, Patrick Gamez, Catherine Belle, Jean-Louis Pierre, Matthias Lüken, Bernt Krebs, Olivier Roubeau, and Jan Reedijk pp 4372 - 4382; DOI: 10.1021/ic0501770 |
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Novel Examples of High-Dimensional Mixed-Valence Copper Cyanide Complexes Do-hyeon Kim, Ja-eung Koo, Chang Seop Hong, Sangjun Oh, and Youngkyu Do pp 4383 - 4390; DOI: 10.1021/ic048267c |
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Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a New Open-Framework Aluminophosphate (NH4)2Al4(PO4)4(HPO4)·H2O Dan Zhou, Lei Chen, Jihong Yu, Yi Li, Wenfu Yan, Feng Deng, and Ruren Xu pp 4391 - 4397; DOI: 10.1021/ic048476x |
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Boron-Induced Hydrogen Localization in the Novel Metal Hydride LaNi3BHx (x = 2.5-3.0) Yaroslav E. Filinchuk and Klaus Yvon pp 4398 - 4406; DOI: 10.1021/ic050416j |
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Analysis of the Uniaxial Magnetic Properties of High-Spin d6 Ions at Trigonal Prism and Linear Two-Coordinate Sites: Uniaxial Magnetic Properties of Ca3Co2O6 and Fe[C(SiMe3)3]2 Dadi Dai and Myung-Hwan Whangbo pp 4407 - 4414; DOI: 10.1021/ic050185g |
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Properties of Chloroformyl Peroxynitrate, ClC(O)OONO2 Plácido García, Holger Pernice, Helge Willner, Heinz Oberhammer, and Gustavo A. Argüello pp 4415 - 4420; DOI: 10.1021/ic050229l |
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Ca1-xNa2xAl2B2O7: A Structure with Tunable Density of Na+ Vacancies Meng He, Hiroki Okudera, and Arndt Simon pp 4421 - 4426; DOI: 10.1021/ic0500863 |
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Oxygen Atom Transfer Reactions from Dioxygen to Phosphines via a Bridging Sulfur Dioxide in a Trinuclear Cluster Complex of Rhenium, [(Ph3P)2N][Re3(3-S)(-S)2(-SO2)Cl6(PMe2Ph)3] Taro Saito, Tomoaki Sunaga, Nobuaki Sakai, Yoichi Nakamura, Saori Yamamoto, Daisuke Iriuchijima, and Kenji Yoza pp 4427 - 4432; DOI: 10.1021/ic050461r |
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Reactions of Pyrazolylborate-Zinc-Hydroxide Complexes Related to -Lactamase Activity Florian Gross and Heinrich Vahrenkamp pp 4433 - 4440; DOI: 10.1021/ic050220j |
Issue 13
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[(ONN)PtX] Complexes as a New Class of Light-Emitting Materials for Electrophosphorescent Devices Chi-Chung Kwok, Hugo M. Y. Ngai, Siu-Chung Chan, Iona H. T. Sham, Chi-Ming Che, and Nianyong Zhu pp 4442 - 4444; DOI: 10.1021/ic050365q |
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Photophysical and Electrochemical Properties of Heteroleptic Tris-Cyclometalated Iridium(III) Complexes Kenneth Dedeian, Jianmin Shi, Nigel Shepherd, Eric Forsythe, and David C. Morton pp 4445 - 4447; DOI: 10.1021/ic050324u |
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A Three-Dimensional Coordination Polymer Featuring Effective Ferrimagnetic Hydroxide-Bridged Manganese(II) Chains Jin-Tang Li, Jun Tao, Rong-Bin Huang, Lan-Sun Zheng, Tan Yuen, C. L. Lin, Princy Varughese, and Jing Li pp 4448 - 4450; DOI: 10.1021/ic050043m |
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High-Frequency and -Field EPR Investigation of a Manganese(III) N-Confused Porphyrin Complex, [Mn(NCTPP)(py)2] John D. Harvey, Christopher J. Ziegler, Joshua Telser, Andrew Ozarowski, and J. Krzystek pp 4451 - 4453; DOI: 10.1021/ic0506759 |
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Magnetism of [Ni(dmit)2] Salts with [Meso- and (1S, 2S)-Diphenyl-1,2-Ethanediammonium]([18]crown-6)2 Supramolecular Cations Tomoyuki Akutagawa, Kazumasa Matsuura, Asako Hashimoto, and Takayoshi Nakamura pp 4454 - 4456; DOI: 10.1021/ic050241d |
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Molecular Tectonics: Self-Complementary Supramolecular Se···N Synthons Directing Assembly of 1D Silver Chains into 3D Porous Molecular Architectures Ai-Ju Zhou, Shao-Liang Zheng, Yue Fang, and Ming-Liang Tong pp 4457 - 4459; DOI: 10.1021/ic050472k |
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A Giant Supramolecular Light-Harvesting Antenna-Acceptor Composite Daisuke Furutsu, Akiharu Satake, and Yoshiaki Kobuke pp 4460 - 4462; DOI: 10.1021/ic050029+ |
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1,4-Di(1,2,3-triazol-1-yl)butane as Building Block for the Preparation of the Iron(II) Spin-Crossover 2D Coordination Polymer Robert Bronisz pp 4463 - 4465; DOI: 10.1021/ic050449z |
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Diastereoisomerically Selective Enantiomerically Pure Titanium Complexes of Salan Ligands: Synthesis, Structure, and Preliminary Activity Studies Adi Yeori, Stanislav Groysman, Israel Goldberg, and Moshe Kol pp 4466 - 4468; DOI: 10.1021/ic050745b |
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Metal-Organotetraphosphonate Inorganic-Organic Hybrids: Crystal Structure and Anticorrosion Effects of Zinc Hexamethylenediaminetetrakis(methylenephosphonate) on Carbon Steels Konstantinos D. Demadis, Christos Mantzaridis, Raphael G. Raptis, and Gellert Mezei pp 4469 - 4471; DOI: 10.1021/ic050572q |
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Structural and Kinetic Studies on Uranyl(V) Carbonate Complex Using 13C NMR Spectroscopy Koichiro Mizuoka, Ingmar Grenthe, and Yasuhisa Ikeda pp 4472 - 4474; DOI: 10.1021/ic050308x |
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On the Nature of Carbon-Hydrogen Bond Activation at Rhodium and Related Reactions William D. Jones pp 4475 - 4484; DOI: 10.1021/ic050007n |
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Synthesis, Characterization, and Physicochemical Properties of Manganese(III) and Manganese(V)-Oxo Corrolazines David E. Lansky, Beaven Mandimutsira, Bobby Ramdhanie, Maria Clausén, James Penner-Hahn, S. A. Zvyagin, Joshua Telser, J. Krzystek, Riqiang Zhan, Zhongping Ou, Karl M. Kadish, Lev Zakharov, Arnold L. Rheingold, and David P. Goldberg pp 4485 - 4498; DOI: 10.1021/ic0503636 |
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The First Coordination Polymers and Hydrogen Bonded Networks Containing Octahedral Nb6 Clusters and Alkaline Earth Metal Complexes Zhihua Yan, Cynthia S. Day, and Abdessadek Lachgar pp 4499 - 4505; DOI: 10.1021/ic048453i |
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cis-Dioxomolybdenum(VI) and Oxo(phosphine oxide)molybdenum(IV) Complexes: Steric and Electronic Fine-Tuning of cis-[MoOS]2+ Precursors Christian J. Doonan, Andrew J. Millar, David J. Nielsen, and Charles G. Young pp 4506 - 4514; DOI: 10.1021/ic050052v |
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3D Coordination Polymers with Nitrilotriacetic and 4,4'-Bipyridyl Mixed Ligands: Structural Variation Based on Dinuclear or Tetranuclear Subunits Assisted by Na-O and/or O-H···O Interactions Xing-Qiang Lü, Ji-Jun Jiang, Chun-Long Chen, Bei-Sheng Kang, and Cheng-Yong Su pp 4515 - 4521; DOI: 10.1021/ic050125a |
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1H NMR Investigation of High-Spin and Low-Spin Iron(III) meso-Ethynylporphyrins Anna Berlicka, Lechos  aw Latos-Gra y ski, and Tadeusz Lispp 4522 - 4533; DOI: 10.1021/ic050158q |
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Rational Synthesis and Magnetic Properties of a Family of Low-Dimensional Heterometallic Cr-Mn Complexes Based on the Versatile Building Block [Cr(2,2'-bipyridine)(CN)4]- Yuan-Zhu Zhang, Song Gao, Zhe-Ming Wang, Gang Su, Hao-Ling Sun, and Feng Pan pp 4534 - 4545; DOI: 10.1021/ic0484194 |
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X-ray Absorption Spectroscopic Study of the Reduced Hydroxylases of Methane Monooxygenase and Toluene/o-Xylene Monooxygenase: Differences in Active Site Structure and Effects of the Coupling Proteins MMOB and ToMOD Deanne Jackson Rudd, Matthew H. Sazinsky, Stephen J. Lippard, Britt Hedman, and Keith O. Hodgson pp 4546 - 4554; DOI: 10.1021/ic048794w |
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New Polynuclear Manganese Clusters from the Use of the Hydrophobic Carboxylate Ligand 2,2-Dimethylbutyrate Nicole E. Chakov, Lev N. Zakharov, Arnold L. Rheingold, Khalil A. Abboud, and George Christou pp 4555 - 4567; DOI: 10.1021/ic050201+ |
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Model for Acetylene Reduction by Nitrogenase Derived from Density Functional Theory Johannes Kästner and Peter E. Blöchl pp 4568 - 4575; DOI: 10.1021/ic0500311 |
Crystal Structure, Chemical Bonding, and Phase Relations of the Novel Compound Co4Al7+xSi2-x (0.27  x 1.05)Klaus W. Richter, Yurii Prots, and Yuri Grin pp 4576 - 4585; DOI: 10.1021/ic0401243 |
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Synthesis and Characterization of the Face-Sharing Bioctahedral [Mo2O6F3]3- Anion Janet E. Kirsch, Heather K. Izumi, Charlotte L. Stern, and Kenneth R. Poeppelmeier pp 4586 - 4593; DOI: 10.1021/ic0502877 |
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Dual Room-Temperature Fluorescent and Phosphorescent Emission in 8-Quinolinolate Osmium(II) Carbonyl Complexes: Rationalization and Generalization of Intersystem Crossing Dynamics Yi-Ming Cheng, Yu-Shan Yeh, Mei-Lin Ho, Pi-Tai Chou, Po-Shen Chen, and Yun Chi pp 4594 - 4603; DOI: 10.1021/ic0505347 |
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Assembly of Helical Hydrogen Bonds in a New Layered Aluminophosphate [C6N3H17][Al2(HPO4)(PO4)2] Mei Wang, Ji-yang Li, Ji-hong Yu, Qin-he Pan, Xiao-wei Song, and Ru-ren Xu pp 4604 - 4607; DOI: 10.1021/ic050124i |
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Synthesis, Structure, and Stereochemistry of Trinuclear Metal Complexes Formed from the Phosphorus-Based Achiral Tripodal Ligand {P(S)[N(Me)N=CHC6H4-o-OH]3} (LH3): Luminescent Properties of L2Cd3·2H2O Vadapalli Chandrasekhar, Ramachandran Azhakar, Stefano Zacchini, Jamie F. Bickley, and Alexander Steiner pp 4608 - 4615; DOI: 10.1021/ic050395t |
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Synthesis and Molecular and Extended Structures for a Diaminonaphthalene-Derived Bis(amido)stannylene Patrick Bazinet, Glenn P. A. Yap, Gino A. DiLabio, and Darrin S. Richeson pp 4616 - 4621; DOI: 10.1021/ic050238u |
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Effective, Selective Coupling of Propylene Oxide and Carbon Dioxide to Poly(Propylene Carbonate) Using (Salen)CrN3 Catalysts Donald J. Darensbourg and Andrea L. Phelps pp 4622 - 4629; DOI: 10.1021/ic050443+ |
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Enantiomerically Pure Pentagonal-Bipyramidal Metal Complexes with Predetermined Helicity in the Solid and Solution States Michael Seitz, Anja Kaiser, Sabine Stempfhuber, Manfred Zabel, and Oliver Reiser pp 4630 - 4636; DOI: 10.1021/ic050014b |
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Geometrical and Electronic Structures of Dinuclear Complex Ions {(-bpym)[Cu(EAr3)2]2}2+ with Intramolecular "Organic Sandwich" Formation (E = P or As; Ar = Aryl; bpym = 2,2'-Bipyrimidine) Monika Sieger, Conny Vogler, Axel Klein, Axel Knödler, Matthias Wanner, Jan Fiedler, Stanislav Záli , Theo L. Snoeck, and Wolfgang Kaimpp 4637 - 4643; DOI: 10.1021/ic050207z |
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Structural, Magnetic, and Spectroscopic Comparative Studies on Four New Derivatives of DIMMAL (2-Di1H-2-imidazolylmethylmalonate): A Novel Generator of Multidimensional Networks Hugo Núñez, Lucía Soto, Juan Server-Carrió, Julia García-Lozano, Amparo Sancho, Rafael Acerete, and Emilio Escrivà pp 4644 - 4655; DOI: 10.1021/ic048234x |
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Structural and Photophysical Properties of Coordination Networks Combining [Ru(bipy)(CN)4]2- Anions and Lanthanide(III) Cations: Rates of Photoinduced Ru-to-Lanthanide Energy Transfer and Sensitized Near-Infrared Luminescence Graham M. Davies, Simon J. A. Pope, Harry Adams, Stephen Faulkner, and Michael D. Ward pp 4656 - 4665; DOI: 10.1021/ic050512k |
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Tetraphosphinite Resorcinarene Complexes: Silver(I) Capsule Complexes Dana J. Eisler and Richard J. Puddephatt pp 4666 - 4678; DOI: 10.1021/ic050095b |
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Synthesis and Characterization of New Coordination Polymers Generated from Bent Bis(Cyanophenyl)oxadiazole Ligands and Ag(I) Salts Yu-Bin Dong, Hai-Ying Wang, Jian-Ping Ma, Da-Zhong Shen, and Ru-Qi Huang pp 4679 - 4692; DOI: 10.1021/ic050218s |
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Light-Driven Expulsion of the Sterically Hindering Ligand L in Tris-diimine Ruthenium(II) Complexes of the Ru(phen)2(L)2+ Family: A Pronounced Ring Effect Jean-Paul Collin, Damien Jouvenot, Masatoshi Koizumi, and Jean-Pierre Sauvage pp 4693 - 4698; DOI: 10.1021/ic050246a |
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Tuning the Band Gap in Hybrid Tin Iodide Perovskite Semiconductors Using Structural Templating Jeremy L. Knutson, James D. Martin, and David B. Mitzi pp 4699 - 4705; DOI: 10.1021/ic050244q |
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Rodlike Bimetallic Ruthenium and Osmium Complexes Bridged by Phenylene Spacers. Synthesis, Electrochemistry, and Photophysics Steve Welter, Nunzio Salluce, Arianna Benetti, Nicolette Rot, Peter Belser, Prashant Sonar, Andrew C. Grimsdale, Klaus Müllen, Martin Lutz, Anthony L. Spek, and Luisa De Cola pp 4706 - 4718; DOI: 10.1021/ic0483141 |
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The Reactions of Nitrosyl Complexes with Cysteine Federico Roncaroli and José A. Olabe pp 4719 - 4727; DOI: 10.1021/ic048156d |
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Assembly of Azido- or Cyano-Bridged Binuclear Complexes Containing the Bulky [Mn(phen)2]2+ Building Block: Syntheses, Crystal Structures, and Magnetic Properties Zhong-Hai Ni, Hui-Zhong Kou, Lei Zheng, Yi-Hua Zhao, Li-Fang Zhang, Ru-Ji Wang, Ai-Li Cui, and Osamu Sato pp 4728 - 4736; DOI: 10.1021/ic050181b |
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Syntheses and Properties of Emissive Iridium(III) Complexes with Tridentate Benzimidazole Derivatives Tomona Yutaka, Shinya Obara, Satoshi Ogawa, Koichi Nozaki, Noriaki Ikeda, Takeshi Ohno, Youichi Ishii, Ken Sakai, and Masa-aki Haga pp 4737 - 4746; DOI: 10.1021/ic048622z |
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Dinuclear, Bishydrated GdIII Polyaminocarboxylates with a Rigid Xylene Core Display Remarkable Proton Relaxivities Jérôme Costa, Éva Tóth, Lothar Helm, and André E. Merbach pp 4747 - 4755; DOI: 10.1021/ic0500309 |
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Controlled Hydrolysis of Lanthanide Complexes of the N-Donor Tripod Tris(2-pyridylmethyl)amine versus Bisligand Complex Formation Louise Natrajan, Jacques Pécaut, Marinella Mazzanti, and Colette LeBrun pp 4756 - 4765; DOI: 10.1021/ic0502224 |
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New Approach to the Chemistry of Technetium(V) and Rhenium(V) Phenylimido Complexes: Novel [M(NPh)PNP]3+ Metal Fragments (M = Tc, Re; PNP = Aminodiphosphine) Suitable for the Synthesis of Stable Mixed-Ligand Compounds Marina Porchia, Francesco Tisato, Fiorenzo Refosco, Cristina Bolzati, Mario Cavazza-Ceccato, Giuliano Bandoli, and Alessandro Dolmella pp 4766 - 4776; DOI: 10.1021/ic048486y |
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Arylzinc Alkoxides: [ArZnOCHPr2i]2 and Ar2Zn3(OCHPr2i)4 When Ar = C6H5, p-CF3C6H4, 2,4,6-Me3C6H2, and C6F5 Malcolm H. Chisholm, Judith C. Gallucci, Hongfeng Yin, and Hongshi Zhen pp 4777 - 4785; DOI: 10.1021/ic048332i |
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Proton Electroreduction Catalyzed by Cobaloximes: Functional Models for Hydrogenases Mathieu Razavet, Vincent Artero, and Marc Fontecave pp 4786 - 4795; DOI: 10.1021/ic050167z |
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Aromatic Interactions in Unusual Backbone Nitrogen-Coordinated Zinc Peptide Complexes: A Crystallographic and Spectroscopic Study Slobodan Novokmet, Frank W. Heinemann, Achim Zahl, and Ralf Alsfasser pp 4796 - 4805; DOI: 10.1021/ic0500053 |
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Photoinduced Electron Tranfer in Platinum(II) Terpyridinyl Acetylide Complexes Connected to a Porphyrin Unit Cyrille Monnereau, Julio Gomez, Errol Blart, Fabrice Odobel, Staffan Wallin, Anna Fallberg, and Leif Hammarström pp 4806 - 4817; DOI: 10.1021/ic048573q |
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pH-Specific Aqueous Synthetic Chemistry in the Binary Cadmium(II)-Citrate System. Gaining Insight into Cadmium(II)-Citrate Speciation with Relevance to Cadmium Toxicity E. T. Kefalas, M. Dakanali, P. Panagiotidis, C. P. Raptopoulou, A. Terzis, T. Mavromoustakos, I. Kyrikou, N. Karligiano, A. Bino, and A. Salifoglou pp 4818 - 4828; DOI: 10.1021/ic050286e |
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Theoretical Designs for Planar Tetracoordinated Carbon in Cu, Ag, and Au Organometallic Chemistry: A New Target for Synthesis Ming-Der Su pp 4829 - 4833; DOI: 10.1021/ic050046z |
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Reactions of Methane with Titanium Atoms: CH3TiH, CH2=TiH2, Agostic Bonding, and (CH3)2TiH2 Lester Andrews, Han-Gook Cho, and Xuefeng Wang pp 4834 - 4842; DOI: 10.1021/ic0502574 |
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Activation of Metallocenes for Olefin Polymerization As Monitored by IR Spectroscopy Jan L. Eilertsen, Jon A. St vneng, Martin Ystenes, and Erling Rytterpp 4843 - 4851; DOI: 10.1021/ic0482638 |
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Aqueous Reductive Dechlorination of Chlorinated Ethylenes with Tetrakis(4-carboxyphenyl)porphyrin Cobalt Joseph M. Fritsch and Kristopher McNeill pp 4852 - 4861; DOI: 10.1021/ic0504339 |
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Synthesis and Structures of Monomeric Magnesium, Calcium, Strontium, and Barium Amides Involving the N,N-(2,4,6-Trimethylphenyl)(trimethylsilyl)amido Ligand Miriam Gillett-Kunnath, Weijie Teng, Wilda Vargas, and Karin Ruhlandt-Senge pp 4862 - 4870; DOI: 10.1021/ic0500614 |
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Preparation and Crystal Structures of a Series of Titanium(III) 9-BBN Hydroborate Complexes Containing Ti···H Agostic Interactions Errun Ding, Bin Du, Fu-Chen Liu, Shengming Liu, Edward A. Meyers, and Sheldon G. Shore pp 4871 - 4878; DOI: 10.1021/ic050422f |
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Synthesis, X-ray Diffraction Studies, and DFT Calculations on Hexacoordinated Germanium Derivatives: The Case of Germaspirobis(ocanes) Sergey S. Karlov, Elmira Kh. Lermontova, Maxim V. Zabalov, Anastasia A. Selina, Andrei V. Churakov, Judith A. K. Howard, Mikhail Yu. Antipin, and Galina S. Zaitseva pp 4879 - 4886; DOI: 10.1021/ic048165m |
Issue 14
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A New Aluminum Hydroxide Octamer, [Al8(OH)14(H2O)18](SO4)5.16H2O William H. Casey, Marilyn M. Olmstead, and Brian L. Phillips pp 4888 - 4890; DOI: 10.1021/ic050426k |
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Sequestering Perrhenate with a Borate-Based Coordination Polymer: A Model for Pertechnetate Separation Barton H. Hamilton, Todd A. Wagler, Matthew P. Espe, and Christopher J. Ziegler pp 4891 - 4893; DOI: 10.1021/ic050213v |
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Weak Carbon-Hydrogen-Nitrogen Interactions Affect the Heterocyclic Ligand Bonding Modes in Barium Complexes Containing 2-Tetrazolato and 2-Pentazolato Ligands Issam Kobrsi, John E. Knox, Mary Jane Heeg, H. Bernhard Schlegel, and Charles H. Winter pp 4894 - 4896; DOI: 10.1021/ic048171i |
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Structure-Function Relationships within Keppler-Type Antitumor Ruthenium(III) Complexes: the Case of 2-Aminothiazolium[trans-tetrachlorobis(2-aminothiazole)ruthenate(III)] Pasquale Mura, Francesca Piccioli, Chiara Gabbiani, Mercedes Camalli, and Luigi Messori pp 4897 - 4899; DOI: 10.1021/ic050194p |
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Phenanthroline-Polyoxometalate Hybrid Compounds and the Observation of Intramolecular Charge Transfer Itsik Bar-Nahum, K. V. Narasimhulu, Lev Weiner, and Ronny Neumann pp 4900 - 4902; DOI: 10.1021/ic050473c |
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Single-Molecule Magnets Constructed from Cyanometalates: {[Tp*FeIII(CN)3MII(DMF)4]2[OTf]2}·2DMF (MII = Co, Ni) Dongfeng Li, Sean Parkin, Guangbin Wang, Gordon T. Yee, Andrey V. Prosvirin, and Stephen M. Holmes pp 4903 - 4905; DOI: 10.1021/ic048367i |
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Ferrocenylalanes: Solid-State and Solution Structures of Some New Aluminum-Bridged ansa-Ferrocenes Holger Braunschweig, Christian Burschka, Guy K. B. Clentsmith, Thomas Kupfer, and Krzysztof Radacki pp 4906 - 4908; DOI: 10.1021/ic0501925 |
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Controlled Decomposition of an Indium Trihydride Adduct: Synthesis and Characterization of the First Mixed-Oxidation-State Indium Sub-halide Complex Anion, [In5Br8(quinuclidine)4]- Marcus L. Cole, Cameron Jones, and Marc Kloth pp 4909 - 4911; DOI: 10.1021/ic050415r |
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Microporous Pillared Paddle-Wheel Frameworks Based on Mixed-Ligand Coordination of Zinc Ions Bao-Qing Ma, Karen L. Mulfort, and Joseph T. Hupp pp 4912 - 4914; DOI: 10.1021/ic050452i |
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Mössbauer, Electron Paramagnetic Resonance, and Crystallographic Characterization of a High-Spin Fe(I) Diketiminate Complex with Orbital Degeneracy Sebastian A. Stoian, Ying Yu, Jeremy M. Smith, Patrick L. Holland, Emile L. Bominaar, and Eckard Münck pp 4915 - 4922; DOI: 10.1021/ic050321h |
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XAFS Spectral Analysis of the Cadmium Coordination Geometry in Cadmium Thiolate Clusters in Metallothionein Jayna Chan, Maureen E. Merrifield, Alexander V. Soldatov, and Martin J. Stillman pp 4923 - 4933; DOI: 10.1021/ic048871n |
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Structural Characterization of a Lanthanum Bistriflimide Complex, La(N(SO2CF3)2)3(H2O)3, and an Investigation of La, Sm, and Eu Electrochemistry in a Room-Temperature Ionic Liquid, [Me3NnBu][N(SO2CF3)2] Anand I. Bhatt, Iain May, Vladimir A. Volkovich, David Collison, Madeleine Helliwell, Ilya B. Polovov, and Robert G. Lewin pp 4934 - 4940; DOI: 10.1021/ic048199u |
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Density Functional Study on Dihydrogen Activation at the H Cluster in Fe-Only Hydrogenases Taijin Zhou, Yirong Mo, Zhaohui Zhou, and Khirui Tsai pp 4941 - 4946; DOI: 10.1021/ic0484699 |
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Spectroscopic and DFT Investigation of [M{HB(3,5-iPr2pz)3}(SC6F5)] (M = Mn, Fe, Co, Ni, Cu, and Zn) Model Complexes: Periodic Trends in Metal-Thiolate Bonding Serge I. Gorelsky, Lipika Basumallick, Josh Vura-Weis, Ritimukta Sarangi, Keith O. Hodgson, Britt Hedman, Kiyoshi Fujisawa, and Edward I. Solomon pp 4947 - 4960; DOI: 10.1021/ic050371m |
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Geometry of Simple Molecules. 2. Modeling the Geometry of AX3E and AX2E2 Molecules through the Nonbonded Interaction (NBI) Model Ronald F. See, Thomas A. Baker, and Pamela Kahler pp 4961 - 4968; DOI: 10.1021/ic048211i |
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Competitive Complexation of Gaseous MnII by 1,10-Phenanthroline, 2,2'-Bipyridine, and 4,5-Diazafluorene Nikos G. Tsierkezos, Martin Diefenbach, Jana Roithová, Detlef Schröder, and Helmut Schwarz pp 4969 - 4978; DOI: 10.1021/ic048543n |
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Sr2MnSb2: A New Ternary Transition Metal Zintl Phase Seon-Mi Park, Sung-Jin Kim, and Mercouri G. Kanatzidis pp 4979 - 4982; DOI: 10.1021/ic048252e |
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Directed Supramolecular Assembly of Infinite 1-D M(II)-Containing Chains (M = Cu, Co, Ni) Using Structurally Bifunctional Ligands Christer B. Aakeröy, Nate Schultheiss, and John Desper pp 4983 - 4991; DOI: 10.1021/ic048405y |
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Synthetic Applications of (Me3SiNSN)2E (E = S, Se) in Chalcogen-Nitrogen Chemistry: Formation and Structural Characterization of Cl2TeESN2 (E = S, Se) and [PPh4]2[Pd2(-Se2N2S)X4] (X = Cl, Br) Jari Konu, Markku Ahlgrén, Stephen M. Aucott, Tristram Chivers, Sophie H. Dale, Mark R. J. Elsegood, Kathryn E. Holmes, Sarah L. M. James, Paul F. Kelly, and Risto S. Laitinen pp 4992 - 5000; DOI: 10.1021/ic050261f |
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Corroborative Models of the Cobalt(II) Inhibited Fe/Mn Superoxide Dismutases Marciela Scarpellini, Amy J. Wu, Jeff W. Kampf, and Vincent L. Pecoraro pp 5001 - 5010; DOI: 10.1021/ic050281h |
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Unexpected Ferromagnetic Interaction in a New Tetranuclear Copper(II) Complex: Synthesis, Crystal Structure, Magnetic Properties, and Theoretical Studies Matilde Fondo, Ana M. García-Deibe, Monstserrat Corbella, Eliseo Ruiz, Javier Tercero, Jesús Sanmartín, and Manuel R. Bermejo pp 5011 - 5020; DOI: 10.1021/ic0482741 |
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Intermolecular Interactions in Polymorphs of Trinuclear Gold(I) Complexes: Insight into the Solvoluminescence of AuI3(MeN=COMe)3 Rochelle L. White-Morris, Marilyn M. Olmstead, Saeed Attar, and Alan L. Balch pp 5021 - 5029; DOI: 10.1021/ic050381n |
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Oxygen-Bridged Borate Anions from Tris(pentafluorophenyl)borane: Synthesis, NMR Characterization, and Reactivity Alessia Di Saverio, Francesca Focante, Isabella Camurati, Luigi Resconi, Tiziana Beringhelli, Giuseppe D'Alfonso, Daniela Donghi, Daniela Maggioni, Pierluigi Mercandelli, and Angelo Sironi pp 5030 - 5041; DOI: 10.1021/ic0502168 |
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Synthesis, Structure, and Magnetic Properties of the Layered Copper(II) Oxide Na2Cu2TeO6 Jianxiao Xu, Abdeljalil Assoud, Navid Soheilnia, Shahab Derakhshan, Heather L. Cuthbert, John E. Greedan, Mike H. Whangbo, and Holger Kleinke pp 5042 - 5046; DOI: 10.1021/ic0502832 |
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Synthesis and Characterization of Diverse Coordination Polymers. Linear and Zigzag Chains Involving Their Structural Transformation via Intermolecular Hydrogen-Bonded, Interpenetrating Ladders Polycatenane, and Noninterpenetrating Square Grid from Long, Rigid N,N'-Bidentate Ligands: 1,4-Bis[(x-pyridyl)ethynyl]benzene (x = 3 and 4) Md. Badruz Zaman, Konstantin Udachin, John A. Ripmeester, Mark D. Smith, and Hans-Conrad zur Loye pp 5047 - 5059; DOI: 10.1021/ic050080d |
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Magneto-Structural Relationships in a Series of Dinuclear Oxalato-Bridged (Diphenyldipyrazolylmethane)copper(II) Complexes Janet L. Shaw, Gordon T. Yee, Guangbin Wang, David E. Benson, Cagil Gokdemir, and Christopher J. Ziegler pp 5060 - 5067; DOI: 10.1021/ic048229t |
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Energetic Azolium Azolate Salts Hong Xue, Ye Gao, Brendan Twamley, and Jean'ne M. Shreeve pp 5068 - 5072; DOI: 10.1021/ic050284u |
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Vanadium(III) and Vanadium(V) Amine Tris(Phenolate) Complexes Stanislav Groysman, Israel Goldberg, Zeev Goldschmidt, and Moshe Kol pp 5073 - 5080; DOI: 10.1021/ic050084i |
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Metal-Metal Interactions in Mixed-Valence [M2Cl9]2- Species: Electronic Structure of d1d2 (V, Nb, Ta) and d4d5 (Fe, Ru, Os) Face-Shared Systems Germán Cavigliasso and Robert Stranger pp 5081 - 5091; DOI: 10.1021/ic050175f |
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The Stability and Eventual Lone Pair Distortion of the Hexahalide Complexes and Molecules of the Fifth to Eighth Main-Group Elements with One Lone Pair, as Isolated Entities or in Oligomeric Clusters: A Vibronic Coupling and DFT Study Mihail Atanasov and Dirk Reinen pp 5092 - 5103; DOI: 10.1021/ic040125v |
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Acid-Base and Metal-Ion-Binding Properties of 9-[2-(2-Phosphonoethoxy)ethyl]adenine (PEEA), a Relative of the Antiviral Nucleotide Analogue 9-[2-(Phosphonomethoxy)ethyl]adenine (PMEA). An Exercise on the Quantification of Isomeric Complex Equilibria in Solution Alfonso Fernández-Botello, Rolf Griesser, Antonín Hol  , Virtudes Moreno, and Helmut Sigelpp 5104 - 5117; DOI: 10.1021/ic050341j |
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Lanthanide Clusters with Internal Ln: Fragmentation and the Formation of Dimers with Bridging Se2- and Se22- Ligands Louise Huebner, Anna Kornienko, Thomas J. Emge, and John G. Brennan pp 5118 - 5122; DOI: 10.1021/ic050150g |
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Voltammetric Studies on the Reduction of Polyoxometalate Anions in Ionic Liquids Jie Zhang, Alan M. Bond, Douglas R. MacFarlane, Stewart A. Forsyth, Jennifer M. Pringle, Andrew W. A. Mariotti, Abigail F. Glowinski, and Anthony G. Wedd pp 5123 - 5132; DOI: 10.1021/ic050032t |
Carbon-Bridged Bis(phenolato)lanthanide Alkoxides: Syntheses, Structures, and Their Application in the Controlled Polymerization of  -CaprolactoneYingming Yao, Xiaoping Xu, Bao Liu, Yong Zhang, Qi Shen, and Wing-Tak Wong pp 5133 - 5140; DOI: 10.1021/ic050022s |
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Platinum(II) Complex as an Artificial Peptidase: Selective Cleavage of Peptides and a Protein by cis-[Pt(en)(H2O)2]2+ Ion under Ultraviolet and Microwave Irradiation Laura-Mirela Dutc  , Kwang-Seuk Ko, Nicola L. Pohl, and Nenad M. Kostipp 5141 - 5146; DOI: 10.1021/ic050137w |
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Zirconium and Hafnium Complexes Containing Bidentate Diarylamido-Phosphine Ligands Pin-Shu Chien and Lan-Chang Liang pp 5147 - 5151; DOI: 10.1021/ic050599+ |
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Nitrile-Amidine Coupling at Pt(IV) and Pt(II) Centers. An Easy Entry to Imidoylamidine Complexes Nadezhda A. Bokach, Tatyana V. Kuznetsova, Svetlana A. Simanova, Matti Haukka, Armando J. L. Pombeiro, and Vadim Yu. Kukushkin pp 5152 - 5160; DOI: 10.1021/ic050037q |
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Tuning Tetranuclear Manganese-Oxo Core Electronic Properties: Adamantane-Shaped Complexes Synthesized by Ligand Exchange Christopher E. Dubé, Sumitra Mukhopadhyay, Peter J. Bonitatebus, Jr., Richard J. Staples, and William H. Armstrong pp 5161 - 5175; DOI: 10.1021/ic050183w |
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Water Exchange from the Oxo-Centered Rhodium(III) Trimer [Rh3(3-O)(-O2CCH3)6(OH2)3]+: A High-Pressure 17O NMR Study Jacqueline R. Houston, Ping Yu, and William H. Casey pp 5176 - 5182; DOI: 10.1021/ic050537j |
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Effect of Ligand Structure on the Pathways for Iron Release from Human Serum Transferrin Claire E. Brook, Wesley R. Harris, Christopher D. Spilling, Wang Peng, J. Jonathan Harburn, and Sujittra Srisung pp 5183 - 5191; DOI: 10.1021/ic050411m |
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Derivatives of 1,5-Diamino-1H-tetrazole: A New Family of Energetic Heterocyclic-Based Salts Inorganic Chemistry 2005, 44 (12), 4237-4253. Juan Carlos Galvez-Ruiz, Gerhard Holl, Konstantin Karaghiosoff, Thomas M. Klapotke, Karolin Loehnwitz, PeterMayer, Heinrich Noeth, Kurt Polborn, Christoph J. Rohbogner, Max Suter, and Jan J. Weigand: pp 5192 - 5192; DOI: 10.1021/ic058004y |
Issue 15
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Synthesis of Homoleptic Barium Alkoxides and Aryloxides and Their Reactions with Al(CH3)3: a Convenient Route to Heterometallic Species Józef Utko, S awomir Szafert, Lucjan B. Jerzykiewicz, and Piotr Sobotapp 5194 - 5196; DOI: 10.1021/ic0503129 |
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Characterization of Novel Vanadium(III)/Acetate Clusters Formed in Aqueous Solution Fiona H. Fry, Brenda A. Dougan, Nichola McCann, Christopher J. Ziegler, and Nicola E. Brasch pp 5197 - 5199; DOI: 10.1021/ic050336f |
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A Nearly Planar Water Sheet Sandwiched between Strontium-Imidazolium Carboxylate Coordination Polymers Zhaofu Fei, Tilmann J. Geldbach, Dongbin Zhao, Rosario Scopelliti, and Paul J. Dyson pp 5200 - 5202; DOI: 10.1021/ic0504238 |
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CopC Protein from Pseudomonas syringae: Intermolecular Transfer of Copper from Both the Copper(I) and Copper(II) Sites Melissa Koay, Lianyi Zhang, Binsheng Yang, Megan J. Maher, Zhiguang Xiao, and Anthony G. Wedd pp 5203 - 5205; DOI: 10.1021/ic0506198 |
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Switching of the Electronic Communication between Two {Ru(trpy)(bpy)} (trpy = 2,2':6',2' '-Terpyridine and bpy = 2,2'-Bipyridine) Centers by Protonation on the Bridging Dimercaptothiadiazolato Ligand Hidenori Tannai, Kiyoshi Tsuge, and Yoichi Sasaki pp 5206 - 5208; DOI: 10.1021/ic050672w |
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Structural Characterization of the First Hydroxo-Bridged Plutonium Compound, (PuO2)2(IO3)(2-OH)3 Amanda C. Bean, Kent Abney, Brian L. Scott, and Wolfgang Runde pp 5209 - 5211; DOI: 10.1021/ic0507464 |
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One-Electron Reduction of Aqueous Nitric Oxide: A Mechanistic Revision Sergei V. Lymar, Vladimir Shafirovich, and Gregory A. Poskrebyshev pp 5212 - 5221; DOI: 10.1021/ic0501317 |
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Anion-Controlled Nuclearity in Nickel Complexes with Potentially Dinucleating, Poly(oxime) Amine Ligands Elizabeth A. Deters, Michael J. Goldcamp, Jeanette A. Krause Bauer, and Michael J. Baldwin pp 5222 - 5228; DOI: 10.1021/ic048355x |
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Heterocyclic Thionates as a New Class of Bridging Ligands in Oxo-Centered Triangular Cyclopentadienylchromium(III) Complexes Victor Wee Lin Ng, Seah Ling Kuan, Weng Kee Leong, Lip Lin Koh, Geok Kheng Tan, Lai Yoong Goh, and Richard D. Webster pp 5229 - 5240; DOI: 10.1021/ic048287e |
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Three-Dimensional 3d-4f Heterometallic Coordination Polymers: Synthesis, Structures, and Magnetic Properties Qi Yue, Jin Yang, Guang-Hua Li, Guo-Dong Li, Wei Xu, Jie-Sheng Chen, and, and Su-Ning Wang pp 5241 - 5246; DOI: 10.1021/ic048266k |
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Pyridine-Carboxylate Complexes of Platinum. Effect of N,O-Chelate Formation on Model Bifunctional DNA-DNA and DNA-Protein Interactions Susana M. O. Quintal, Yun Qu, Adorácion G. Quiroga, Joseph Moniodis, Helena I. S. Nogueira, and Nicholas Farrell pp 5247 - 5253; DOI: 10.1021/ic050062w |
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Kinetic and Donor Stabilization of Organotellurenyl Iodides and Azides Thomas M. Klapötke, Burkhard Krumm, Heinrich Nöth, Juan Carlos Gálvez-Ruiz, Kurt Polborn, Ingo Schwab, and Max Suter pp 5254 - 5265; DOI: 10.1021/ic048219s |
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The Electronic Structure of Inorganic Benzenes: Valence Bond and Ring-Current Descriptions Jeroen J. Engelberts, Remco W. A. Havenith, Joop H. van Lenthe, Leonardus W. Jenneskens, and Patrick W. Fowler pp 5266 - 5272; DOI: 10.1021/ic050017o |
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Pillared Layered Structures Based upon M(III) Ethylene Diphosphonates: The Synthesis and Crystal Structures of MIII(H2O)(HO3P(CH2)2PO3) (M = Fe, Al, Ga) Crystal A. Merrill and Anthony K. Cheetham pp 5273 - 5277; DOI: 10.1021/ic0502269 |
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Syntheses, Crystal Structures, and Luminescent Properties of Three Novel Zinc Coordination Polymers with Tetrazolyl Ligands Xi-Sen Wang, Yun-Zhi Tang, Xue-Feng Huang, Zhi-Rong Qu, Chi-Ming Che, Philip Wai Hong Chan, and Ren-Gen Xiong pp 5278 - 5285; DOI: 10.1021/ic050354x |
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Solvation and Structure of LiAlH4 in Ethereal Solvents Damián E. Bikiel, Florencia Di Salvo, Mariano C. González Lebrero, Fabio Doctorovich, and Darío A. Estrin pp 5286 - 5292; DOI: 10.1021/ic050330q |
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On the Lamellar Compounds CuBiP2Se6, AgBiP2Se6 and AgBiP2S6. Antiferroelectric Phase Transitions Due to Cooperative Cu+ and Bi3+ Ion Motion Matthew A. Gave, Daniel Bilc, S. D. Mahanti, Jean D. Breshears, and Mercouri G. Kanatzidis pp 5293 - 5303; DOI: 10.1021/ic050357+ |
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Single-Molecule Magnets: Structural Characterization, Magnetic Properties, and 19F NMR Spectroscopy of a Mn12 Family Spanning Three Oxidation Levels Nicole E. Chakov, Mònica Soler, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 5304 - 5321; DOI: 10.1021/ic050379w |
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Negative Magnetoresistance in a Magnetic Semiconducting Zintl Phase: Eu3In2P4 Jiong Jiang, Marilyn M. Olmstead, Susan M. Kauzlarich, Han-Oh Lee, Peter Klavins, and Zachary Fisk pp 5322 - 5327; DOI: 10.1021/ic0504036 |
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Syntheses, Crystal Structures, and Properties of Six New Lanthanide(III) Transition Metal Tellurium(IV) Oxyhalides with Three Types of Structures Yue-Ling Shen and Jiang-Gao Mao pp 5328 - 5335; DOI: 10.1021/ic050420v |
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First Complexes of Scandium and Yttrium with NNO and NNS Heteroscorpionate Ligands Antonio Otero, Juan Fernández-Baeza, Antonio Antiñolo, Juan Tejeda, Agustín Lara-Sánchez, Luis Sánchez-Barba, Emilia Martínez-Caballero, Ana M. Rodríguez, and Isabel López-Solera pp 5336 - 5344; DOI: 10.1021/ic050525y |
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Electronic Structure of Square Planar Bis(benzene-1,2-dithiolato)metal Complexes [M(L)2]z (z = 2-, 1-, 0; M = Ni, Pd, Pt, Cu, Au): An Experimental, Density Functional, and Correlated ab Initio Study Kallol Ray, Thomas Weyhermüller, Frank Neese, and Karl Wieghardt pp 5345 - 5360; DOI: 10.1021/ic0507565 |
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Heavy-Metal Aromatic and Conjugated Species: Rings, Oligomers, and Chains of Tin in Li9-xEuSn6+x, Li9-xCaSn6+x, Li5Ca7Sn11, Li6Eu5Sn9, LiMgEu2Sn3, and LiMgSr2Sn3 Iliya Todorov and Slavi C. Sevov pp 5361 - 5369; DOI: 10.1021/ic050803t |
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Synthesis, Characterization, Biocide and Toxicological Activities of Di-n-butyl- and Diphenyl-tinIV-Salicyliden--Amino Alcohol Derivatives Luis S. Zamudio-Rivera, Rocio George-Tellez, Gerson López-Mendoza, Adela Morales-Pacheco, Eugenio Flores, Herbert Höpfl, Victor Barba, Francisco J. Fernández, Nathalie Cabirol, and Hiram I. Beltrán pp 5370 - 5378; DOI: 10.1021/ic048628o |
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Probing the Cytochrome P450-like Reactivity of High-Valent Oxo Iron Intermediates in the Gas Phase M. Elisa Crestoni and S. Fornarini pp 5379 - 5387; DOI: 10.1021/ic048595c |
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Photoinduced One-Electron Reduction of Alkyl Halides by Dirhodium(II,II) Tetraformamidinates and a Related Complex with Visible Light Daniel A. Lutterman, Natalya N. Degtyareva, Dean H. Johnston, Judith C. Gallucci, Judith L. Eglin, and Claudia Turro pp 5388 - 5396; DOI: 10.1021/ic048377j |
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Methyltriskaidecazirconates, Molecular Forms of Zirconia Victor W. Day, Walter G. Klemperer, and Margaret Mary Pafford pp 5397 - 5404; DOI: 10.1021/ic048307c |
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Amino Acid and Peptide Bioconjugates of Copper(II) and Zinc(II) Complexes with a Modified N,N-Bis(2-picolyl)amine Ligand Sre ko I. Kirin, Pierre Dübon, Thomas Weyhermüller, Eckhard Bill, and Nils Metzler-Noltepp 5405 - 5415; DOI: 10.1021/ic048343b |
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Aqueous Chemistry of the VanadiumIII (VIII) and the VIII-Dipicolinate Systems and a Comparison of the Effect of Three Oxidation States of Vanadium Compounds on Diabetic Hyperglycemia in Rats Péter Buglyó, Debbie C. Crans, Eszter M. Nagy, Ruby Lisa Lindo, Luqin Yang, Jason J. Smee, Wenzheng Jin, Lai-Har Chi, Michael E. Godzala III, and Gail R. Willsky pp 5416 - 5427; DOI: 10.1021/ic048331q |
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Lateral Macrobicyclic Architectures: Toward New Lead(II) Sequestering Agents David Esteban-Gómez, Raquel Ferreirós, Susana Fernández-Martínez, Fernando Avecilla, Carlos Platas-Iglesias, Andrés de Blas, and Teresa Rodríguez-Blas pp 5428 - 5436; DOI: 10.1021/ic0482032 |
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Re(CO)3 Complexes Synthesized via an Improved Preparation of Aqueous fac-[Re(CO)3(H2O)3]+ as an Aid in Assessing 99mTc Imaging Agents. Structural Characterization and Solution Behavior of Complexes with Thioether-Bearing Amino Acids as Tridentate Ligands Haiyang He, Malgorzata Lipowska, Xiaolong Xu, Andrew T. Taylor, Maria Carlone, and Luigi G. Marzilli pp 5437 - 5446; DOI: 10.1021/ic0501869 |
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Controlled Synthesis of Ternary II-II'-VI Nanoclusters and the Effects of Metal Ion Distribution on Their Spectral Properties Marty W. DeGroot, Nicholas J. Taylor, and John F. Corrigan pp 5447 - 5458; DOI: 10.1021/ic0481576 |
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Heterometallic Compounds Assembled from Ferrocene-Containing Bisthiosemicarbazone Clips Ming-xue Li, Yan Bai, Bing-guang Zhang, Chun-ying Duan, Jian Xu, and Qing-jin Meng pp 5459 - 5466; DOI: 10.1021/ic0502067 |
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Trinuclear Nickel Complexes with Triplesalen Ligands: Simultaneous Occurrence of Mixed Valence and Valence Tautomerism in the Oxidized Species Thorsten Glaser, Maik Heidemeier, Roland Fröhlich, Peter Hildebrandt, Eberhart Bothe, and Eckhard Bill pp 5467 - 5482; DOI: 10.1021/ic050268x |
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Methyl Transfer from CH3CoIIIPc to Thiophenoxides Revisited: Remote Substituent Effect on the Rates Wlodzimierz Galezowski pp 5483 - 5494; DOI: 10.1021/ic0503378 |
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Synthetic and Structural Studies of Cyclodistib(V)azanes May C. Copsey, Sabrina B. Gallon, Sara K. Grocott, John C. Jeffery, Christopher A. Russell, and John M. Slattery pp 5495 - 5500; DOI: 10.1021/ic050127v |
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Asymmetric Azido-Copper(II) Bridges: Ferro- or Antiferromagnetic? Experimental and Theoretical Magneto-Structural Studies Smaïl Triki, Carlos J. Gómez-García, Eliseo Ruiz, and Jean Sala-Pala pp 5501 - 5508; DOI: 10.1021/ic0504543 |
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Multinuclear PGSE Diffusion and Overhauser NMR Studies on a Variety of Salts in THF Solution Ignacio Fernández, Eloísa Martínez-Viviente, and Paul S. Pregosin pp 5509 - 5513; DOI: 10.1021/ic050523d |
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Oxidation of Vanadium(III) by Hydrogen Peroxide and the Oxomonoperoxo Vanadium(V) Ion in Acidic Aqueous Solutions: A Kinetics and Simulation Study Guodong Du and James H. Espenson pp 5514 - 5522; DOI: 10.1021/ic050502j |
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Anthracene-Induced Turnover Enhancement in the Manganese Porphyrin-Catalyzed Epoxidation of Olefins Melissa L. Merlau, So-Hye Cho, Shih-Sheng Sun, SonBinh T. Nguyen, and Joseph T. Hupp pp 5523 - 5529; DOI: 10.1021/ic0505596 |
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Time-Resolved Spectroscopy of the Metal-to-Metal Charge Transfer Excited State in Dinuclear Cyano-Bridged Mixed-Valence Complexes Brendan P. Macpherson, Paul V. Bernhardt, Andreas Hauser, Stéphane Pagès, and Eric Vauthey pp 5530 - 5536; DOI: 10.1021/ic0506512 |
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P-S Bond Scission by Bis(cyclopentadienyl)molybdenum(IV) Dichloride, Cp2MoCl2(aq): First Documented Example of an Organometallic Complex Hydrolyzing Thiophosphinates Louis Y. Kuo, Angela P. Blum, and Michal Sabat pp 5537 - 5541; DOI: 10.1021/ic050819j |
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Studies Relevant to Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Triamidoamine Complexes Inorg. Chem. 2005, 44, 1103-1117. Dmitry V. Yandulov and and Richard R. Schrock: pp 5542 - 5542; DOI: 10.1021/ic0580036 |
Issue 16
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Solvent Dependent Conformational Isomerism and Ligand Oxidation of Novel Ru(II) Cyclen Complexes Kleber Q. Ferreira, Luciana N. Cardoso, Sofia Nikolaou, Zênis N. da Rocha, Roberto S. da Silva, and Elia Tfouni pp 5544 - 5546; DOI: 10.1021/ic050006v |
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Synthesis, Structural and Computational Investigations of UO2I42-: A Structurally Characterized U(VI)-I Anion Margaret-Jane Crawford and Peter Mayer pp 5547 - 5549; DOI: 10.1021/ic050231c |
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Dual Electron Uptake by Simultaneous Iron and Ligand Reduction in an N-Heterocyclic Carbene Substituted [FeFe] Hydrogenase Model Compound Jesse W. Tye, Jonghyuk Lee, Hsiao-Wan Wang, Rosario Mejia-Rodriguez, Joseph H. Reibenspies, Michael B. Hall, and Marcetta Y. Darensbourg pp 5550 - 5552; DOI: 10.1021/ic050402d |
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Metal-Organic Framework H-Bonded Like a Polycatenane: Coexistence of Acyclic Water Trimer and Nonamer Sujit K. Ghosh and Parimal K. Bharadwaj pp 5553 - 5555; DOI: 10.1021/ic050727u |
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Unusual Anions [LAl(SH)(S)]- and [LAl(S)2]2- Stabilized by Weakly Coordinating Imidazolium Cations. Synthesis of LAl(SSiMe2)2O (L = HC[C(Me)N(Ar)]2, Ar = 2,6-iPr2C6H3) Vojtech Jancik and Herbert W. Roesky pp 5556 - 5558; DOI: 10.1021/ic050693q |
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"Oxidative Addition" to a Zirconium(IV) Redox-Active Ligand Complex Karen J. Blackmore, Joseph W. Ziller, and Alan F. Heyduk pp 5559 - 5561; DOI: 10.1021/ic050997c |
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Normal-Mode Analysis of FeCl4- and Fe2S2Cl42- via Vibrational Mössbauer, Resonance Raman, and FT-IR Spectroscopies Matt C. Smith, Yuming Xiao, Hongxin Wang, Simon J. George, Dimitri Coucouvanis, Markos Koutmos, Wolfgang Sturhahn, Ercan E. Alp, Jiyong Zhao, and Stephen P. Cramer pp 5562 - 5570; DOI: 10.1021/ic0482584 |
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Oxalate-Bridged Dinuclear M2 Units: Dimers of Dimers, Cyclotetramers, and Extended Sheets (M = Mo, W, Tc, Ru, and Rh) Bruce E. Bursten, Malcolm H. Chisholm, and Jason S. D'Acchioli pp 5571 - 5579; DOI: 10.1021/ic050053n |
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Structure and Conformation of Bis(acetylacetonato)oxovanadium(IV) and Bis(maltolato)oxovanadium(IV) in Solution Determined by Electron Nuclear Double Resonance Spectroscopy Devkumar Mustafi and Marvin W. Makinen pp 5580 - 5590; DOI: 10.1021/ic040120y |
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Crystal Structures of Lanthanide(III) Complexes with Cyclen Derivative Bearing Three Acetate and One Methylphosphonate Pendants Pavel Vojtí ek, Petr Cígler, Jan Kotek, Jakub Rudovsk, Petr Hermann, and Ivan Lukepp 5591 - 5599; DOI: 10.1021/ic048190s |
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Preparations and Characterizations of Bichromophoric Systems Composed of a Ruthenium Polypyridine Complex Connected to a Difluoroborazaindacene or a Zinc Phthalocyanine Chromophore Fabrice Odobel and Hervé Zabri pp 5600 - 5611; DOI: 10.1021/ic050078m |
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A Combined Quantum and Molecular Mechanical Study of the O2 Reductive Cleavage in the Catalytic Cycle of Multicopper Oxidases Lubomír Rulí ek, Edward I. Solomon, and Ulf Rydepp 5612 - 5628; DOI: 10.1021/ic050092z |
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Mössbauer Spectroscopy of Bucky Ferrocenes: Lattice Dynamics and Motional Anisotropy of the Metal Atom Rolfe H. Herber, Israel Nowik, Yutaka Matsuo, Motoki Toganoh, Yoichiro Kuninobu, and Eiichi Nakamura pp 5629 - 5635; DOI: 10.1021/ic050251e |
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Importance of Cations in the Properties of Zintl Phases: The Electronic Structure of and Bonding in Metallic Na6TlSb41 Anja-V. Mudring and John D. Corbett pp 5636 - 5640; DOI: 10.1021/ic050128n |
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Mesoporous Silica-Supported Uranyl: Synthesis and Photoreactivity Jennifer A. Nieweg, Kelemu Lemma, Brian G. Trewyn, Victor S.-Y. Lin, and Andreja Bakac pp 5641 - 5648; DOI: 10.1021/ic050130e |
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Silver(I) Coordination Polymers Containing Heteroditopic Ureidopyridine Ligands: The Role of Ligand Isomerism, Hydrogen Bonding, and Stacking Interactions Pascal Blondeau, Arie van der Lee, and Mihail Barboiu pp 5649 - 5653; DOI: 10.1021/ic050278y |
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Extending the Nitrogen-Heterosuperbenzene Family: The Spectroscopic, Redox, and Photophysical Properties of "Half-Cyclized" N-1/2HSB and Its Ru(II) Complex Daniel J. Gregg, Eberhard Bothe, Petra Höfer, Paolo Passaniti, and Sylvia M. Draper pp 5654 - 5660; DOI: 10.1021/ic050335n |
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Fluorescent Sensor for Cu2+ with a Tunable Emission Wavelength Andriy Mokhir, Alexander Kiel, Dirk-Peter Herten, and Roland Kraemer pp 5661 - 5666; DOI: 10.1021/ic050362d |
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Synthesis, Structure, and Spectroscopic Properties of Am(IO3)3 and the Photoluminescence Behavior of Cm(IO3)3 Richard E. Sykora, Zerihun Assefa, Richard G. Haire, and Thomas E. Albrecht-Schmitt pp 5667 - 5676; DOI: 10.1021/ic050386k |
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Efficient Red-Emitting Cyclometalated Iridium(III) Complexes Containing Lepidine-Based Ligands K. R. Justin Thomas, Marappan Velusamy, Jiann T. Lin, Chin-Hsiung Chien, Yu-Tai Tao, Yuh S. Wen, Ya-Hui Hu, and Pi-Tai Chou pp 5677 - 5685; DOI: 10.1021/ic050385s |
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Unusual Syntheses, Structures, and Electronic Properties of Compounds Containing Ternary, T3-Type Supertetrahedral M/Sn/S Anions [M5Sn(3-S)4(SnS4)4]10- (M = Zn, Co) Christian Zimmermann, Christopher E. Anson, Florian Weigend, Rodolphe Clérac, and Stefanie Dehnen pp 5686 - 5695; DOI: 10.1021/ic050466o |
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Mercury-199 NMR Studies of Thiacrown and Related Macrocyclic Complexes: The Crystal Structures of [Hg(18S6)](PF6)2 and [Hg(9N3)2](ClO4)2 Monte L. Helm, Gregory P. Helton, Donald G. VanDerveer, and Gregory J. Grant pp 5696 - 5705; DOI: 10.1021/ic050500z |
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New Phosphorescent Polynuclear Cu(I) Compounds Based on Linear and Star-Shaped 2-(2'-Pyridyl)benzimidazolyl Derivatives: Syntheses, Structures, Luminescence, and Electroluminescence Wen Li Jia, Theresa McCormick, Ye Tao, Jian-Ping Lu, and Suning Wang pp 5706 - 5712; DOI: 10.1021/ic0504893 |
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Trifluoromethoxycarbonyl Peroxynitrate, CF3OC(O)OONO2 Stefan von Ahsen, Plácido García, Helge Willner, and Gustavo A. Argüello pp 5713 - 5718; DOI: 10.1021/ic0504994 |
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Diosmium(III) Compounds Supported by 2-Anilinopyridinate and Novel Alkynyl Derivatives Yan-Hui Shi, Wei-Zhong Chen, Kevin D. John, Ryan E. Da Re, Joshua L. Cohn, Guo-Lin Xu, Judith L. Eglin, Alfred P. Sattelberger, Curtis R. Hare, and Tong Ren pp 5719 - 5727; DOI: 10.1021/ic050496r |
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Synthesis, Gas-Phase Photoelectron Spectroscopic, and Theoretical Studies of Stannylated Dinuclear Iron Dithiolates Richard S. Glass, Nadine E. Gruhn, Edward Lorance, Maya S. Singh, Nhu Y T. Stessman, and Uzma I. Zakai pp 5728 - 5737; DOI: 10.1021/ic050526q |
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Controlled Ligand Deprotonation in Lanthanide Chelates with Asymmetric Semicarbazone/Benzoylhydrazone or Semicarbazone/Thiosemicarbazone Coordination Spheres Alexander Jagst, Agustin Sanchez, Ezequiel M. Vazquez-Lopez, and Ulrich Abram pp 5738 - 5744; DOI: 10.1021/ic050556t |
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A Detailed Resonance Raman Spectrum of Nickel(II)-Substituted Pseudomonas aeruginosa Azurin Roman S. Czernuszewicz, Grazyna Fraczkiewicz, and Adelajda A. Zareba pp 5745 - 5752; DOI: 10.1021/ic050553g |
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Structure-Directing Influence of Halide in Mercury Thiolate Clusters Mohan S. Bharara, Thanhhoa H. Bui, Sean Parkin, and David A. Atwood pp 5753 - 5760; DOI: 10.1021/ic0506005 |
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Novel Binding of Beryllium to Dicarboxyimidazole-Based Model Compounds and Polymers Paul G. Plieger, Deborah S. Ehler, Brandy L. Duran, Tammy P. Taylor, Kevin D. John, Timothy S. Keizer, T. Mark McCleskey, Anthony K. Burrell, Jeffrey W. Kampf, Thomas Haase, Paul G. Rasmussen, and Jennifer Karr pp 5761 - 5769; DOI: 10.1021/ic050680c |
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Discrete and Monodimensional Heteropolynuclear Structures Formed by Tetracarboxylatodiruthenium(II,III) and Perrhenato Fragments Gema Arribas, M. Carmen Barral, Rodrigo González-Prieto, Reyes Jiménez-Aparicio, J. Luis Priego, M. Rosario Torres, and Francisco A. Urbanos pp 5770 - 5777; DOI: 10.1021/ic050757x |
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Synthesis and Structures of Aluminum and Magnesium Complexes of Tetraimidophosphates and Trisamidothiophosphates: EPR and DFT Investigations of the Persistent Neutral Radicals {Me2Al[(-NR)(-NtBu)P(-NtBu)2]Li(THF)2} (R = SiMe3, tBu) Andrea Armstrong, Tristram Chivers, Heikki M. Tuononen, and Masood Parvez pp 5778 - 5788; DOI: 10.1021/ic050689e |
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Borderline Class II/III Ligand-Centered Mixed Valency in a Porphyrinic Molecular Rectangle Peter H. Dinolfo, Suk Joong Lee, Veaceslav Coropceanu, Jean-Luc Brédas, and Joseph T. Hupp pp 5789 - 5797; DOI: 10.1021/ic050834o |
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Self-Assembly of Heterobimetallic Neutral Macrocycles Incorporating Ferrocene Spacer Groups: Spectroelectrochemical Analysis of the Double Two-Electron Oxidation of a Molecular Rectangle Neeladri Das, Atta M. Arif, Peter J. Stang, Monika Sieger, Biprajit Sarkar, Wolfgang Kaim, and Jan Fiedler pp 5798 - 5804; DOI: 10.1021/ic0481834 |
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Template-Assisted Solvothermal Synthesis of Five Copper(I)-Thioantimonate(III) Composites: Crystal Structures and Optical and Thermal Properties of (C6N2H18)0.5Cu2SbS3, (C4N3H15)0.5Cu2SbS3, (C8N4H22)0.5Cu2SbS3, (C4N3H14)Cu3Sb2S5, and (C6N4H20)0.5Cu3Sb2S5 V. Spetzler, C. Näther, and W. Bensch pp 5805 - 5812; DOI: 10.1021/ic050196+ |
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Bivalent and Trivalent Iron Complexes of Acyclic Hexadentate Ligands Providing Pyridyl/Pyrazine-Amide-Thioether Coordination Akhilesh Kumar Singh and Rabindranath Mukherjee pp 5813 - 5819; DOI: 10.1021/ic050057s |
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Trialkylboron/Lanthanide Metallocene Hydride Chemistry: Polydentate Bridging of (HBEt3)- to Lanthanum William J. Evans, Jeremy M. Perotti, and Joseph W. Ziller pp 5820 - 5825; DOI: 10.1021/ic0501061 |
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Diphosphacarbollide Analogues of the C5H5- Anion: Isolation of the nido-Di- and Triphosphacarboranes 7,8,9-P2CB8H10, [7,8,9-P2CB8H9]-, [7,8,10-P2CB8H9]-, and 7,8,9,10-P3CB7H8 Mario Bakardjiev, Josef Holub, Bohumil tíbr, Drahomír Hnyk, and Bernd Wrackmeyerpp 5826 - 5832; DOI: 10.1021/ic048232c |
Stabilities of the Aqueous Complexes Cm(CO3)33- and Am(CO3)33- in the Temperature Range 10-70  CThomas Vercouter, Pierre Vitorge, Badia Amekraz, Eric Giffaut, Solange Hubert, and Christophe Moulin pp 5833 - 5843; DOI: 10.1021/ic050214n |
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Chemical and Electrochemical Formation of Pseudorotaxanes Composed of Alkyl(ferrocenylmethyl)ammmonium and Dibenzo[24]crown-8 Masaki Horie, Yuji Suzaki, and Kohtaro Osakada pp 5844 - 5853; DOI: 10.1021/ic050215f |
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Aluminum Hydride Cations Stabilized by Weakly Coordinating Carbaalanates Andreas Stasch, Herbert W. Roesky, Mathias Noltemeyer, and Hans-Georg Schmidt pp 5854 - 5857; DOI: 10.1021/ic048594k |
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Synthesis and Complexation of "Back-to-Back" Capped Bis-dioxocyclams Jun Mo Gil, Scott David, Angela L. Reiff, and Louis S. Hegedus pp 5858 - 5865; DOI: 10.1021/ic0502731 |
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Transition Metal Carbene Chemistry. 4. Nucleophilic Attachment of DABCO to Fischer Carbene Complexes in MeCN Mahammad Ali, Abhijit Dan, Ambarish Ray, and Kaushik Ghosh pp 5866 - 5871; DOI: 10.1021/ic050349t |
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Dinitrosyl Iron Complexes (DNICs) [L2Fe(NO)2]- (L = Thiolate): Interconversion among {Fe(NO)2}9 DNICs, {Fe(NO)2}10 DNICs, and [2Fe-2S] Clusters, and the Critical Role of the Thiolate Ligands in Regulating NO Release of DNICs Fu-Te Tsai, Show-Jen Chiou, Ming-Che Tsai, Ming-Li Tsai, Hsiao-Wen Huang, Ming-Hsi Chiang, and Wen-Feng Liaw pp 5872 - 5881; DOI: 10.1021/ic0505044 |
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High-Throughput Investigation and Characterization of Cobalt Carboxy Phosphonates Sebastian Bauer, Thomas Bein, and Norbert Stock pp 5882 - 5889; DOI: 10.1021/ic0505089 |
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Stabilization of the Thermodynamically Favored Polymorph of Cadmium Chalcogenide Nanoparticles CdX (X = S, Se, Te) in the Polar Mesopores of SBA-15 Silica Maekele Yosef, Andreas K. Schaper, Michael Fröba, and Sabine Schlecht pp 5890 - 5896; DOI: 10.1021/ic050517h |
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Synthesis of cyclo-2,4,6-Triarsa-1,3,5-triazanes from cyclo-2,4-Diarsa-1,3-diazanes Demonstrating the General Influence of Substituent Steric Strain on the Relative Stability of Pnictazane Oligomers Neil Burford, Jeff C. Landry, Michael J. Ferguson, and Robert McDonald pp 5897 - 5902; DOI: 10.1021/ic050532m |
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Synthesis, Structure, and Magnetism of Heterometallic Carboxylate Complexes [MnIII2MII4O2(PhCOO)10(DMF)4], M = MnII, CoII, NiII Konstantin S. Gavrilenko, Sergey V. Punin, Olivier Cador, Stéphane Golhen, Lahcène Ouahab, and Vitaly V. Pavlishchuk pp 5903 - 5910; DOI: 10.1021/ic0505448 |
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Ligand Substituent Effect Observed for Ytterbocene 4'-Cyano-2,2':6',2' '-terpyridine Jacqueline M. Veauthier, Eric J. Schelter, Christopher J. Kuehl, Aurora E. Clark, Brian L. Scott, David E. Morris, Richard L. Martin, J. D. Thompson, Jaqueline L. Kiplinger, and Kevin D. John pp 5911 - 5920; DOI: 10.1021/ic050148p |
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Intra- and Intermolecular N-H···F-C Hydrogen-Bonding Interactions in Amine Adducts of Tris(pentafluorophenyl)borane and -alane Andrew J. Mountford, Simon J. Lancaster, Simon J. Coles, Peter N. Horton, David L. Hughes, Michael B. Hursthouse, and Mark E. Light pp 5921 - 5933; DOI: 10.1021/ic050663n |
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Speciation in the AlCl3/SO2Cl2 Catholyte System Timothy J. Boyle, Nicholas L. Andrews, Todd M. Alam, David R. Tallant, Mark A. Rodriguez, and David Ingersoll pp 5934 - 5940; DOI: 10.1021/ic050621z |
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Synthesis, Characterization, and PGSE (1H and 19F) NMR Diffusion Studies on Cationic (6- Arene)Mn(CO)3+ Complexes: Boron Counterion, Ion Pairing, and Solvent Dependences Daniele Schott, Paul S. Pregosin, Béatrice Jacques, Murielle Chavarot, Françoise Rose-Munch, and Eric Rose pp 5941 - 5948; DOI: 10.1021/ic0506409 |
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The Dianion of 5-Cyanoiminotetrazoline: C2N62- Thomas M. Klapötke, Christian Kuffer, Peter Mayer, Kurt Polborn, Axel Schulz, and Jan J. Weigand pp 5949 - 5958; DOI: 10.1021/ic050584b |
Issue 17
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Synthesis and Coordination Chemistry of a Photoswitchable Bis(phosphine) Ligand David Sud, Robert McDonald, and Neil R. Branda pp 5960 - 5962; DOI: 10.1021/ic050429x |
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Lanthanide-Potassium Wheels Michael T. Gamer and Peter W. Roesky pp 5963 - 5965; DOI: 10.1021/ic050557l |
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Observation of Electroluminescence at Room Temperature from a Ruthenium(II) Bis-Terpyridine Complex and Its Use for Preparing Light-Emitting Electrochemical Cells Henk J. Bolink, Luca Cappelli, Eugenio Coronado, and Pablo Gaviña pp 5966 - 5968; DOI: 10.1021/ic0507058 |
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Cyano-Bridged MnIII3MIII (MIII = Fe, Cr) Complexes: Synthesis, Structure, and Magnetic Properties Hitoshi Miyasaka, Hitomi Takahashi, Tomokura Madanbashi, Ken-ichi Sugiura, Rodolphe Clérac, and Hiroyuki Nojiri pp 5969 - 5971; DOI: 10.1021/ic0505753 |
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Synthesis and Structural Characterization of a Nonplanar Neutral [36]Metallacrown-12 Nickel Compound [Ni(C13H9N3O2) (CH3OH)]12 Yan Bai, Dong-bin Dang, Chun-ying Duan, You Song, and Qing-jin Meng pp 5972 - 5974; DOI: 10.1021/ic0506254 |
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Simple Route to the Doubly ortho-Palladated Azobenzenes: Building Blocks for Organometallic Polymers and Metallomesogens Manda  uri, Darko Babi, Aleksandar Vinjevac, and Kreimir Molanovpp 5975 - 5977; DOI: 10.1021/ic050747w |
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Novel Self-Assembled Chain of Water Molecules in a Metal-Organic Framework Structure of Co(II) with Tartrate Acid Jing Lu, Jie-Hui Yu, Xiao-Yan Chen, Peng Cheng, Xiao Zhang, and Ji-Qing Xu pp 5978 - 5980; DOI: 10.1021/ic0507621 |
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Isolated Magnetic Clusters of Co(II) and Ni(II) within 3-Dimensional Organic Frameworks of 6-Mercaptonicotinic Acid: Unique Structural Topologies Based on Selectivity for Hard and Soft Coordination Environments Simon M. Humphrey, Richard A. Mole, Mary McPartlin, Eric J. L. McInnes, and Paul T. Wood pp 5981 - 5983; DOI: 10.1021/ic050768q |
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2,2';9',2' '-Ter[1,10]phenanthroline Ruifa Zong and Randolph P. Thummel pp 5984 - 5986; DOI: 10.1021/ic050712w |
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Squeezing the [Cu-OH···H2O-Cu]3+ Bridge by Cryptate Encapsulation Andrew D. Bond, Sofia Derossi, Frank Jensen, Frank B. Larsen, Christine J. McKenzie, and Jane Nelson pp 5987 - 5989; DOI: 10.1021/ic0505091 |
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A5InPb8 (A = K, Rb): An Apparent Zintl Phase with Lead Tetrahedra Interbridged by 6-In Atoms1 Michael T. Klem and John D. Corbett pp 5990 - 5995; DOI: 10.1021/ic040130z |
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Ruthenium(II) Complexes of 1,12-Diazaperylene and Their Interactions with DNA Abdellatif Chouai, Sara E. Wicke, Claudia Turro, John Bacsa, Kim R. Dunbar, Dong Wang, and Randolph P. Thummel pp 5996 - 6003; DOI: 10.1021/ic0485965 |
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Crystal Structures and Magnetic Properties of Complexes of MIICl2 (M = Cu, Ni, and Co) Coordinated with 4-(N-tert-butyloxyamino)-2-(methoxymethylenyl)pyridine: 2D Magnetic Anisotropy of the Aminoxyl-CoII Complex in the Crystalline State Zhicheng Zhu, Satoru Karasawa, and Noboru Koga pp 6004 - 6011; DOI: 10.1021/ic048441x |
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A Family of Au-Tl Loosely Bound Butterfly Clusters Eduardo J. Fernández, José M. López-de-Luzuriaga, M. Elena Olmos, Javier Pérez, Antonio Laguna, and M. Cristina Lagunas pp 6012 - 6018; DOI: 10.1021/ic050060b |
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Solid-State Structures and Magnetic Properties of Halide-Bridged, Face-to-Face Bis-Nickel(II)-Macrocyclic Ligand Complexes: Ligand-Mediated Interchanges of Electronic Configuration Konrad T. Szacilowski, Puhui Xie, Aramice Y. S. Malkhasian, Mary Jane Heeg, Manawadevi Y. Udugala-Ganehenege, Lowell E. Wenger, and John F. Endicott pp 6019 - 6033; DOI: 10.1021/ic050147x |
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Sulfido-Bridged Dinuclear Molybdenum-Copper Complexes Related to the Active Site of CO Dehydrogenase: [(dithiolate)Mo(O)S2Cu(SAr)]2- (dithiolate = 1,2-S2C6H4, 1,2-S2C6H2-3,6-Cl2, 1,2-S2C2H4) Motoki Takuma, Yasuhiro Ohki, and Kazuyuki Tatsumi pp 6034 - 6043; DOI: 10.1021/ic050294v |
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Cyclopalladation of the Indole Ring in Palladium(II) Complexes of 2N1O-Donor Ligands and Its Dependence on the O-Donor Properties Yuichi Shimazaki, Minoru Tashiro, Takeshi Motoyama, Satoshi Iwatsuki, Tatsuo Yajima, Yasuo Nakabayashi, Yoshinori Naruta, and Osamu Yamauchi pp 6044 - 6051; DOI: 10.1021/ic0504801 |
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Europium(II) and Ytterbium(II) Cyclic Organohydroborates with Agostic Interactions Xuenian Chen, Soyoung Lim, Christine E. Ple nik, Shengming Liu, Bin Du, Edward A. Meyers, and Sheldon G. Shorepp 6052 - 6061; DOI: 10.1021/ic050573i |
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Self-Assembly of a Series of Extended Architectures Based on Polyoxometalate Clusters and Silver Coordination Complexes Haiyan An, Yangguang Li, Enbo Wang, Dongrong Xiao, Chunyan Sun, and Lin Xu pp 6062 - 6070; DOI: 10.1021/ic050636x |
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Charge Transport and Optical Properties of MOCVD-Derived Highly Transparent and Conductive Mg- and Sn-Doped In2O3 Thin Films Jun Ni, Lian Wang, Yu Yang, He Yan, Shu Jin, Tobin J. Marks, John R. Ireland, and Carl R. Kannewurf pp 6071 - 6076; DOI: 10.1021/ic0501364 |
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Disulfide Bond Cleavage Induced by a Platinum(II) Methionine Complex Haiying Wei, Xiaoyong Wang, Qin Liu, Yuhua Mei, Yi Lu, and Zijian Guo pp 6077 - 6081; DOI: 10.1021/ic050285m |
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Comparative Studies of Substitution Reactions of Rhenium(I) Dicarbonyl-Nitrosyl and Tricarbonyl Complexes in Aqueous Media Niklaus Marti, Bernhard Spingler, Frank Breher, and Roger Schibli pp 6082 - 6091; DOI: 10.1021/ic050442h |
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Complex Series [Ru(tpy)(dpk)(X)]n+ (tpy = 2,2':6',2' '-Terpyridine; dpk = 2,2'-Dipyridyl Ketone; X = Cl-, CH3CN, NO2-, NO+, NO, NO-): Substitution and Electron Transfer, Structure, and Spectroscopy Sounak Sarkar, Biprajit Sarkar, Nripen Chanda, Sanjib Kar, Shaikh M. Mobin, Jan Fiedler, Wolfgang Kaim, and Goutam Kumar Lahiri pp 6092 - 6099; DOI: 10.1021/ic050533e |
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Synthesis, Characterization, Crystal Structure, and Electrochemical, Photophysical, and Protein-Binding Properties of Luminescent Rhenium(I) Diimine Indole Complexes Kenneth Kam-Wing Lo, Keith Hing-Kit Tsang, Wai-Ki Hui, and Nianyong Zhu pp 6100 - 6110; DOI: 10.1021/ic050531u |
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Reactions of 2-(Arylazo) Aniline with RhCl3: Synthesis and Structure of New Cyclometalated Complexes of Rh(III) and Recognition of RhCl3 Assisted Azo (-N=N-) Cleavage Jahar lal Pratihar, Nilkamal Maiti, and Surajit Chattopadhyay pp 6111 - 6114; DOI: 10.1021/ic050551w |
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Practical Synthetic Routes to Solvates of U(OTf)3: X-ray Crystal Structure of [U(OTf)3(MeCN)3]n, a Unique U(III) Coordination Polymer Louise Natrajan, Marinella Mazzanti, Jean-Philippe Bezombes, and Jacques Pécaut pp 6115 - 6121; DOI: 10.1021/ic0505652 |
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Mononuclear and Dinuclear Copper(I) Complexes of Bis(3,5-dimethylpyrazol-1-yl)methane: Synthesis, Structure, and Reactivity Chang-Chuan Chou, Chan-Cheng Su, and Andrew Yeh pp 6122 - 6128; DOI: 10.1021/ic050568e |
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Searching for Precursors to Metal-Metal Bonded Dipalladium Species: A Study of Pd24+ Complexes John F. Berry, F. Albert Cotton, Sergey A. Ibragimov, Carlos A. Murillo, and Xiaoping Wang pp 6129 - 6137; DOI: 10.1021/ic050876c |
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On the Nature of Carbon-Hydrogen Bond Activation at Rhodium and Related Reactions William D. Jones: pp 6138 - 6138; DOI: 10.1021/ic058005q |
Issue 18
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Long-Lived Near-Infrared Luminescent Lanthanide Complexes of Imidodiphosphinate "Shell" Ligands Andrew P. Bassett, Rik Van Deun, Peter Nockemann, Peter B. Glover, Benson M. Kariuki, Kristof Van Hecke, Luc Van Meervelt, and Zoe Pikramenou pp 6140 - 6142; DOI: 10.1021/ic0482436 |
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Spontaneously Resolved Chiral Three-Fold Interpenetrating Diamondoidlike Cu(II) Coordination Polymers with Temperature-Driven Crystal-to-Crystal Transformation Jian-Ping Ma, Yu-Bin Dong, Ru-Qi Huang, Mark D. Smith, and Cheng-Yong Su pp 6143 - 6145; DOI: 10.1021/ic0505504 |
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Peroxidase Activity of the Hemeoctapeptide N-Acetylmicroperoxidase-8 Helder M. Marques pp 6146 - 6148; DOI: 10.1021/ic050856a |
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Thiol-Functionalized Undecagold Clusters by Ligand Exchange: Synthesis, Mechanism, and Properties Gerd H. Woehrle and James E. Hutchison pp 6149 - 6158; DOI: 10.1021/ic048686+ |
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Tunable DNA Photocleavage by an Acridine-Imidazole Conjugate Beth Wilson, Lourdes Gude, María-José Fernández, Antonio Lorente, and Kathryn B. Grant pp 6159 - 6173; DOI: 10.1021/ic048320x |
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Theoretical Study on the Spin-State Energy Splittings and Local Spin in Cationic [Re]-Cn-[Re] Complexes Carmen Herrmann, Johannes Neugebauer, John A. Gladysz, and Markus Reiher pp 6174 - 6182; DOI: 10.1021/ic050240l |
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Binuclear Complexes of Co(III) Containing Extended Conjugated Bis(Catecholate) Ligands Yusaku Suenaga and Cortlandt G. Pierpont pp 6183 - 6191; DOI: 10.1021/ic050250m |
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Open Metal-Organic Framework Containing Cuprate Chains Dat T. Tran, Xiaojuan Fan, Daniel P. Brennan, Peter Y. Zavalij, and Scott R. J. Oliver pp 6192 - 6196; DOI: 10.1021/ic050024c |
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Synthesis, Structure, and Magnetic Properties of the Oxalate-Based Bimetallic Ferromagnetic Chain {[K(18-crown-6)][Mn(H2O)2Cr(ox)3]} (18-crown-6 = C12H24O6, ox = C2O42-) Eugenio Coronado, José R. Galán-Mascarós, Carlos J. Gómez-García, and Carlos Martí-Gastaldo pp 6197 - 6202; DOI: 10.1021/ic050258w |
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Dynamics of a cis-Dihydrogen/Hydride Complex of Iridium H. V. Nanishankar, Saikat Dutta, Munirathinam Nethaji, and Balaji R. Jagirdar pp 6203 - 6210; DOI: 10.1021/ic050266c |
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Electronic Spectra of Pure Uranyl(V) Complexes: Characteristic Absorption Bands Due to a UVO2+ Core in Visible and Near-Infrared Regions1 Koichiro Mizuoka, Satoru Tsushima, Miki Hasegawa, Toshihiko Hoshi, and Yasuhisa Ikeda pp 6211 - 6218; DOI: 10.1021/ic0503838 |
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Syntheses, Structures, and Luminescent and Magnetic Properties of Novel Three-Dimensional Lanthanide Complexes with 1,3,5-Benzenetriacetate Zheng-Hua Zhang, Taka-aki Okamura, Yasuchika Hasegawa, Hiroyuki Kawaguchi, Ling-Yan Kong, Wei-Yin Sun, and Norikazu Ueyama pp 6219 - 6227; DOI: 10.1021/ic050453a |
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Large M4L4 (M = Al(III), Ga(III), In(III), Ti(IV)) Tetrahedral Coordination Cages: an Extension of Symmetry-Based Design Robert M. Yeh, Jide Xu, Georg Seeber, and Kenneth N. Raymond pp 6228 - 6239; DOI: 10.1021/ic0505145 |
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Lone Pair Effect in Thallium(I) Macrocyclic Compounds Anja-Verena Mudring and Franziska Rieger pp 6240 - 6243; DOI: 10.1021/ic050547k |
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Novel 1-N,2-C,C-Binding Mode between Pyridinyl-Functionalized Cyclopentadienyl Ligands and Iridium Alex S. Ionkin and William J. Marshall pp 6244 - 6247; DOI: 10.1021/ic0505854 |
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Coordination of Nitroxide and Nitronyl-nitroxide Organic Radicals to Trimeric Perfluoro-o-phenylene Mercury Mason R. Haneline and François P. Gabbaï pp 6248 - 6255; DOI: 10.1021/ic050528a |
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Organo-Tricyanoborates as Tectons: Illustrative Coordination Polymers Based on Copper(I) Derivatives Haijun Yao, Matthew L. Kuhlman, Thomas B. Rauchfuss, and Scott R. Wilson pp 6256 - 6264; DOI: 10.1021/ic0506153 |
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One-Dimensional and Two-Dimensional Coordination Polymers from Self-Assembling of Trinuclear Triangular Cu(II) Secondary Building Units Maurizio Casarin, Carlo Corvaja, Corrado Di Nicola, Daniele Falcomer, Lorenzo Franco, Magda Monari, Luciano Pandolfo, Claudio Pettinari, and Fabio Piccinelli pp 6265 - 6276; DOI: 10.1021/ic050678l |
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Molecular Dynamics of a Vanadate-Dipeptide Complex in Aqueous Solution Michael Bühl pp 6277 - 6283; DOI: 10.1021/ic050694i |
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Synthesis, Structure, Characterization, and Photophysical Studies of a New Platinum Terpyridyl-Based Triad with Covalently Linked Donor and Acceptor Groups Soma Chakraborty, Thaddeus J. Wadas, Heidi Hester, Christine Flaschenreim, Russell Schmehl, and Richard Eisenberg pp 6284 - 6293; DOI: 10.1021/ic050688m |
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Hydrothermal Synthesis and Characterization of [(UO2)2F8(H2O)2Zn2(4,4'-bpy)2]·(4,4'-bpy), a Mixed-Metal Uranyl Aquofluoride with a Pillared Layer Structure Chih-Min Wang, Chia-Hsien Liao, Hsien-Ming Kao, and Kwang-Hwa Lii pp 6294 - 6298; DOI: 10.1021/ic0507060 |
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Dinuclear Triple Helicates with Diazine Ligands: X-ray Structural, Electrochemical, and Magnetic Studies Subramanya Gupta Sreerama and Samudranil Pal pp 6299 - 6307; DOI: 10.1021/ic050704f |
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Temperature Dependent Emission of Hexarhenium(III) Clusters [Re6(3-S)8X6]4- (X = Cl-, Br-, and I-): Analysis by Four Excited Triplet-State Sublevels Noboru Kitamura, Yuichi Ueda, Shoji Ishizaka, Konatsu Yamada, Masanori Aniya, and Yoichi Sasaki pp 6308 - 6313; DOI: 10.1021/ic050855i |
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Non-Interpenetrating Transition Metal Diorganophosphate 2-Dimensional Rectangular Grids from Their 1-Dimensional Wires: Structural Transformations under Mild Conditions Ramasamy Pothiraja, Malaichamy Sathiyendiran, Ray J. Butcher, and Ramaswamy Murugavel pp 6314 - 6323; DOI: 10.1021/ic050742z |
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[Mn12O12(OMe)2(O2CPh)16(H2O)2]2- Single-Molecule Magnets and Other Manganese Compounds from a Reductive Aggregation Procedure Anastasios J. Tasiopoulos, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 6324 - 6338; DOI: 10.1021/ic050868w |
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Comparative Electronic Band Structure Study of the Intrachain Ferromagnetic versus Antiferromagnetic Coupling in the Magnetic Oxides Ca3Co2O6 and Ca3FeRhO6 Antoine Villesuzanne and Myung-Hwan Whangbo pp 6339 - 6345; DOI: 10.1021/ic0508775 |
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Addition of Palladium and Platinum Tri-tert-Butylphosphine Groups to Re-Sn and Re-Ge Bonds Richard D. Adams, Burjor Captain, Rolfe H. Herber, Mikael Johansson, Israel Nowik, Jack L. Smith, Jr., and Mark D. Smith pp 6346 - 6358; DOI: 10.1021/ic051077x |
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Volumes of Solid State Ions and Their Estimation H. Donald Brooke Jenkins and Joel F. Liebman pp 6359 - 6372; DOI: 10.1021/ic048341r |
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Synthesis, Structure, Spectroscopic Properties, and Photochemistry of Homo- and Heteropolynuclear Copper(I) Complexes Bridged by the 2,5-Bis(2-pyridyl)pyrazine Ligand Taro Tsubomura, Shinya Enoto, Shinya Endo, Tsuyoshi Tamane, Kenji Matsumoto, and Toshiaki Tsukuda pp 6373 - 6378; DOI: 10.1021/ic050098o |
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Cation-Dependent Nuclearity of the Copper-Azido Moiety: Synthesis, Structure, and Magnetic Study Sandip Saha, Subratanath Koner, Jean-Pierre Tuchagues, Athanassios K. Boudalis, Ken-Ichi Okamoto, Surajit Banerjee, and Dasarath Mal pp 6379 - 6385; DOI: 10.1021/ic050117u |
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Dioxo-Molybdenum(VI) and Mono-oxo-Molybdenum(IV) Complexes Supported by New Aliphatic Dithiolene Ligands: New Models with Weakened Mo=O Bond Characters for the Arsenite Oxidase Active Site Hideki Sugimoto, Makoto Harihara, Motoo Shiro, Kunihisa Sugimoto, Koji Tanaka, Hiroyuki Miyake, and Hiroshi Tsukube pp 6386 - 6392; DOI: 10.1021/ic050234p |
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Fabrication of ZnSe Nanoparticles in the Apoferritin Cavity by Designing a Slow Chemical Reaction System Kenji Iwahori, Keiko Yoshizawa, Masahiro Muraoka, and Ichiro Yamashita pp 6393 - 6400; DOI: 10.1021/ic0502426 |
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(2,2':6',2' '-Terpyridine)platinum(II) Complexes Containing (Thioalkyl)dicarba-closo-dodecaborane(12) Ligands Jean A. Todd, Peter Turner, Erin J. Ziolkowski, and Louis M. Rendina pp 6401 - 6408; DOI: 10.1021/ic050265k |
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Structure Determination and Relative Properties of Novel Cubic Borates MM'4(BO3)3 (M = Li, M' = Sr; M = Na, M' = Sr, Ba) L. Wu, X. L. Chen, H. Li, M. He, Y. P. Xu, and X. Z. Li pp 6409 - 6414; DOI: 10.1021/ic050299s |
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Investigating Bidentate and Tridentate Carbamoylmethylphosphine Oxide Ligand Interactions with Rare-Earth Elements Using Electrospray Ionization Quadrupole Ion Trap Mass Spectrometry Matthew C. Crowe, Ramesh N. Kapoor, Francisco Cervantes-Lee, Laszlo Párkányí, Louis Schulte, Keith H. Pannell, and Jennifer S. Brodbelt pp 6415 - 6424; DOI: 10.1021/ic0503028 |
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Synthesis, Structure, and Transformation of Novel Osmium Azine and Ylide Complexes Te-Wei Chiu, Yen-Hsiang Liu, Kai-Ming Chi, Yuh-Sheng Wen, and Kuang-Lieh Lu pp 6425 - 6430; DOI: 10.1021/ic050431o |
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Chain Structures in Alkali Metal Borophosphates: Synthesis and Characterization of K3[BP3O9(OH)3] and Rb3[B2P3O11(OH)2] Bastian Ewald, Yurii Prots, Prashanth Menezes, Srinivasan Natarajan, Hui Zhang, and Rüdiger Kniep pp 6431 - 6438; DOI: 10.1021/ic050441p |
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Ligand Exchange Reaction Between an Alkylzinc Primary Amide and a Dialkylmagnesium Compound: Crystal Structures of [(thf)MeMg--N(H)SiiPr3]2 and (tmeda)Mg[N(H)SiiPr3]2 Matthias Westerhausen, Tobias Bollwein, Nikolaos Makropoulos, and Holger Piotrowski pp 6439 - 6444; DOI: 10.1021/ic0503277 |
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Laser Photolysis Studies of the Reaction of Chromium(III) Octaethylporphyrin Complex with Triphenylphosphine and Triphenylphosphine Oxide Masahiko Inamo, Nao Matsubara, Kiyohiko Nakajima, Tsutomu S. Iwayama, Hiroshi Okimi, and Mikio Hoshino pp 6445 - 6455; DOI: 10.1021/ic0504487 |
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Heterovalent AuIII-MI (M = Cu, Ag, Au) Complexes Derived from Incorporation of [Au(tdt)2]- (tdt = Toluene-3,4-dithiolate) with [M2(dppm)2]2+ (dppm = Bis(diphenylphosphino)methane) Yan-Dan Chen, Li-Yi Zhang, Yong-Hai Qin, and Zhong-Ning Chen pp 6456 - 6462; DOI: 10.1021/ic050542n |
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Three New Phases in the K/Cu/Th/S System: KCuThS3, K2Cu2ThS4, and K3Cu3Th2S7 Hugh D. Selby, Benny C. Chan, Ryan F. Hess, Kent D. Abney, and Peter K. Dorhout pp 6463 - 6469; DOI: 10.1021/ic050561x |
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Kinetics and Mechanism of the Iron Phthalocyanine Catalyzed Reduction of Nitrite by Dithionite and Sulfoxylate in Aqueous Solution Evgeny V. Kudrik, Sergei V. Makarov, Achim Zahl, and Rudi van Eldik pp 6470 - 6475; DOI: 10.1021/ic0505955 |
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Cd(II), Zn(II), and Pd(II) Complexes of an Isoindoline Pincer Ligand: Consequences of Steric Crowding Brandon L. Dietrich, Jonathan Egbert, Aimee M. Morris, Mark Wicholas, Oren P. Anderson, and Susie M. Miller pp 6476 - 6481; DOI: 10.1021/ic0506916 |
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Highly Cross-linked Polymers Containing N,N',N' '-Chelate Ligands for the Cu(II)-Mediated Hydrolysis of Phosphoesters Alexander Schiller, Rosario Scopelliti, Meriem Benmelouka, and Kay Severin pp 6482 - 6492; DOI: 10.1021/ic0504588 |
Issue 19
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Orbital Contributions to the Molecular Charge and Energy Density Distributions in Co2(CO)8 Oliver Kluge, Markus Finger, and Joachim Reinhold pp 6494 - 6496; DOI: 10.1021/ic050361l |
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Selective Extraction of Metals from Mixed Oxide Matrixes Using Choline-Based Ionic Liquids Andrew P. Abbott, Glen Capper, David L. Davies, Raymond K. Rasheed, and Pragna Shikotra pp 6497 - 6499; DOI: 10.1021/ic0505450 |
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Solvent-Dependent Crystallization of 1-Hydro-6-carbaphosphatrane and Its Tautomer Shin-ya Nakafuji, Junji Kobayashi, Takayuki Kawashima, and Michael W. Schmidt pp 6500 - 6502; DOI: 10.1021/ic050679d |
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Bamboo-Shaped Ag-Doped TiO2 Nanowires with Heterojunctions Baomei Wen, Chunyan Liu, and Yun Liu pp 6503 - 6505; DOI: 10.1021/ic0505551 |
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Synthesis of Multi-Walled and Bamboo-like Well-Crystalline CNx Nanotubes with Controllable Nitrogen Concentration (x = 0.05-1.02) Yujie Xiong, Zhengquan Li, Qixun Guo, and Yi Xie pp 6506 - 6508; DOI: 10.1021/ic050722x |
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Structural Origin of Chirality and Properties of a Remarkable Helically Pillared Solid Bangbo Yan, Michael D. Capracotta, and Paul A. Maggard pp 6509 - 6511; DOI: 10.1021/ic050794o |
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Efficient Electrochemical Conversion of Carbon Monoxide by Rhodium Octaethylporphyrin Adsorbed on Carbon Black Shin-ichi Yamazaki, Yusuke Yamada, and Kazuaki Yasuda pp 6512 - 6514; DOI: 10.1021/ic050911f |
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Participation of Sodium in the Bonding of Anionic Networks: Synthesis, Structure, and Bonding of Na3MIn2 (M = Au, Ag) Bin Li and John D. Corbett pp 6515 - 6517; DOI: 10.1021/ic050979v |
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Lewis Acid Adducts of [PCl2N]3 Amy J. Heston, Matthew J. Panzner, Wiley J. Youngs, and Claire A. Tessier pp 6518 - 6520; DOI: 10.1021/ic050974y |
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One-Dimensional Supramolecular Assemblies Based on a Re2(III,III) Synthon and Their Solid-State Phosphorescence Michael Q. Dequeant, Robert McGuire, Jr., David R. McMillin, and Tong Ren pp 6521 - 6523; DOI: 10.1021/ic051070f |
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Convenient Preparation and Full Characterization of a Synthetically Useful Salt of the Dithianitronium Cation, SNSSbF6, from Readily Available Starting Materials T. Stanley Cameron, Aaron Mailman, Jack Passmore, and Konstantin V. Shuvaev pp 6524 - 6528; DOI: 10.1021/ic0483139 |
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Tris(pyronato)- and Tris(pyridonato)-ruthenium(III) Complexes and Solution NMR Studies David C. Kennedy, Adam Wu, Brian O. Patrick, and Brian R. James pp 6529 - 6535; DOI: 10.1021/ic050034d |
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Discrete Iridium Pyridonate Chains with Variable Metal Valence: Nature and Energetics of the Ir-Ir Bonding from DFT Calculations B. Eva Villarroya, Cristina Tejel, Marie-Madeleine Rohmer, Luis A. Oro, Miguel A. Ciriano, and Marc Bénard pp 6536 - 6544; DOI: 10.1021/ic050419w |
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Novel Corrugated In9 Anionic Layer in Li2Y5In9: Square Pyramidal In5 Clusters Interconnected by Unusual Butterfly In4 Clusters Zhong-Ming Sun, Jiang-Gao Mao, and Da-Chun Pan pp 6545 - 6549; DOI: 10.1021/ic050462j |
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Structural and Magnetic Properties of Hexagonal Perovskites La1.2Sr2.7MO7.33 (M = Ru, Ir) Containing Peroxide Ions Thomas Götzfried, Armin Reller, and Stefan G. Ebbinghaus pp 6550 - 6557; DOI: 10.1021/ic050511s |
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Mono-, Di-, and Trinuclear Luminescent Silver(I) and Gold(I) N-Heterocyclic Carbene Complexes Derived from the Picolyl-Substituted Methylimidazolium Salt: 1-Methyl-3-(2-pyridinylmethyl)-1H-imidazolium Tetrafluoroborate Vincent J. Catalano and Adam L. Moore pp 6558 - 6566; DOI: 10.1021/ic050604+ |
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Neutral Pyridyl-Functionalized C,N-ortho-Chelated Aminoaryl Platinum(II) Corner Building Blocks for Application in Coordination Reactions Catelijne H. M. Amijs, Alexsandro Berger, Fouad Soulimani, Tom Visser, Gerard P. M. van Klink, Martin Lutz, Anthony L. Spek, and Gerard van Koten pp 6567 - 6578; DOI: 10.1021/ic050697v |
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Heterometallic MIIRuIII2 Compounds Constructed from trans-[Ru(Salen)(CN)2]- and trans-[Ru(Acac)2(CN)2]-. Synthesis, Structures, Magnetic Properties, and Density Functional Theoretical Study Wai-Fun Yeung, Pui-Ha Lau, Tai-Chu Lau, Hai-Yan Wei, Hao-Ling Sun, Song Gao, Zhi-Da Chen, and Wing-Tak Wong pp 6579 - 6590; DOI: 10.1021/ic0506456 |
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Organometallic Coordination Polymers Generated from Bent Bis(acetylenylphenyl)oxadiazole Ligands and Ag(I) Salts Yu-Bin Dong, Qiang Zhang, Le Wang, Jian-Ping Ma, Ru-Qi Huang, Da-Zhong Shen, and De-Zhan Chen pp 6591 - 6608; DOI: 10.1021/ic0508223 |
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Structural, Optical, and Photophysical Properties of Nickel(II) Alkylthioporphyrins: Insights from Experimental and DFT/TDDFT Studies Angela Rosa, Giampaolo Ricciardi, Evert Jan Baerends, Mikhail Zimin, Michael A. J. Rodgers, Shingo Matsumoto, and Noboru Ono pp 6609 - 6622; DOI: 10.1021/ic050838t |
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Synthesis of PtRu5(CO)14(PBut3)(-H)2(6-C) and Its Reactions with Pt(PBut3)2, HGePh3, and HSnPh3 Richard D. Adams, Burjor Captain, and Lei Zhu pp 6623 - 6631; DOI: 10.1021/ic051007q |
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Investigation of the Crystal Structure and the Structural and Magnetic Properties of SrCu2(PO4)2 Alexei A. Belik, Masaki Azuma, Akira Matsuo, Myung-Hwan Whangbo, Hyun-Joo Koo, Jun Kikuchi, Tomoyuki Kaji, Susumu Okubo, Hitoshi Ohta, Koichi Kindo, and Mikio Takano pp 6632 - 6640; DOI: 10.1021/ic051079h |
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Synthesis and Characterization of Mn2P2S6 Single-Crystal Nanorods and Nanotubes Chunhui Li, Xun Wang, Qing Peng, and Yadong Li pp 6641 - 6645; DOI: 10.1021/ic048570d |
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Macrocyclic Lanthanide Complexes as Artificial Nucleases and Ribonucleases: Effects of pH, Metal Ionic Radii, Number of Coordinated Water Molecules, Charge, and Concentrations of the Metal Complexes C. Allen Chang, Bo Hong Wu, and Bu Yuan Kuan pp 6646 - 6654; DOI: 10.1021/ic0485458 |
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Comparative EXAFS Investigation of Uranium(VI) and -(IV) Aquo Chloro Complexes in Solution Using a Newly Developed Spectroelectrochemical Cell C. Hennig, J. Tutschku, A. Rossberg, G. Bernhard, and A. C. Scheinost pp 6655 - 6661; DOI: 10.1021/ic048422n |
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Luminescent Transition Metal Complexes as Sensors: Structural Effects on pH Response Bernadette Higgins, B. A. DeGraff, and J. N. Demas pp 6662 - 6669; DOI: 10.1021/ic050044e |
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Nitrosylated Iron-Thiolate-Sulfinate Complexes with {Fe(NO)}6/7 Electronic Cores: Relevance to the Transformation between the Active and Inactive NO-Bound Forms of Iron-Containing Nitrile Hydratases Chien-Ming Lee, Chien-Hong Chen, Hao-Wen Chen, Jo-Lu Hsu, Gene-Hsiang Lee, and Wen-Feng Liaw pp 6670 - 6679; DOI: 10.1021/ic050108l |
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The Indium Subnitrides Ae6In4(InxLiy)N3-z (Ae = Sr and Ba) Mark S. Bailey, Daniel Y. Shen, Michael A. McGuire, Daniel C. Fredrickson, Brian H. Toby, Francis J. DiSalvo, Hisanori Yamane, Shinya Sasaki, and Masahiko Shimada pp 6680 - 6690; DOI: 10.1021/ic050613i |
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Evidence for a Carbonyl-Containing Intermediate in the 308-nm Photolysis of trans-RhCl(CO)(PMe3)2 R. Krishnan and Richard H. Schultz pp 6691 - 6694; DOI: 10.1021/ic050219k |
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New Evidence on the Structure of Potassium Salts of 12-Tungstophosphoric Acid, KxH3-xPW12O40 Jerzy Haber, Leszek Matachowski, Dariusz Mucha, Jerzy Stoch, and Priit Sarv pp 6695 - 6703; DOI: 10.1021/ic050350s |
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Tuning of Redox Properties for the Design of Ruthenium Anticancer Drugs: Part 2. Syntheses, Crystal Structures, and Electrochemistry of Potentially Antitumor [RuIII/IICl6-n(Azole)n]z (n = 3, 4, 6) Complexes Erwin Reisner, Vladimir B. Arion, Anna Eichinger, Norbert Kandler, Gerald Giester, Armando J. L. Pombeiro, and Bernhard K. Keppler pp 6704 - 6716; DOI: 10.1021/ic0503737 |
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195Pt NMR of Heteropolymetallic Complexes Containing Secondary Dithiooxamides as Binucleating Ligands Santo Lanza, Giovanna Callipari, Frédérique Loiseau, Scolastica Serroni, and Giuseppe Tresoldi pp 6717 - 6724; DOI: 10.1021/ic0507215 |
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Cyclic M2(RL)2 Coordination Complexes of 5-(3-[N-tert-Butyl-N-aminoxyl]phenyl)pyrimidine with Paramagnetic Transition Metal Dications Martha Baskett, Paul M. Lahti, Armando Paduan-Filho, and Nei F. Oliveira, Jr. pp 6725 - 6735; DOI: 10.1021/ic050435t |
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Calix[4]pyrrole Schiff Base Macrocycles: Novel Binucleating Ligands for Cu(I) and Cu(II) Jacqueline M. Veauthier, Elisa Tomat, Vincent M. Lynch, Jonathan L. Sessler, Utkir Mirsaidov, and John T. Markert pp 6736 - 6743; DOI: 10.1021/ic050690d |
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Electrochemistry, Spectroelectrochemistry, Chloride Binding, and O2 Catalytic Reactions of Free-Base Porphyrin-Cobalt Corrole Dyads Karl M. Kadish, Jianguo Shao, Zhongping Ou, Laurent Frémond, Riqiang Zhan, Fabien Burdet, Jean-Michel Barbe, Claude P. Gros, and Roger Guilard pp 6744 - 6754; DOI: 10.1021/ic050738n |
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NMR and Theoretical Study on the Coordination and Solution Structures of the Interaction between Diperoxovanadate Complexes and Histidine-like Ligands Xian-Yong Yu, Shu-Hui Cai, Xin Xu, and Zhong Chen pp 6755 - 6762; DOI: 10.1021/ic050739f |
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Thiol- and Thioether-Based Bifunctional Chelates for the {M(CO)3}+ Core (M = Tc, Re) Neva Lazarova, John Babich, John Valliant, Paul Schaffer, Shelly James, and Jon Zubieta pp 6763 - 6770; DOI: 10.1021/ic050735a |
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Direct Determination of the Anisotropy and Exchange Splittings in the Dimeric Single-Molecule Magnet [Mn4O3Cl4(O2CEt)3(py)3]2·8MeCN by Inelastic Neutron Scattering Andreas Sieber, Dolos Foguet-Albiol, Oliver Waldmann, Stefan T. Ochsenbein, Roland Bircher, George Christou, Felix Fernandez-Alonso, Hannu Mutka, and Hans U. Güdel pp 6771 - 6776; DOI: 10.1021/ic050764l |
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Cationic Rare-Earth Metal Trimethylsilylmethyl Complexes Supported by THF and 12-Crown-4 Ligands: Synthesis and Structural Characterization Benjamin R. Elvidge, Stefan Arndt, Peter M. Zeimentz, Thomas P. Spaniol, and Jun Okuda pp 6777 - 6788; DOI: 10.1021/ic0511165 |
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Reversible Skeletal Transmetalations of Inorganic Rings: Isolation of Aluminatophosphazenes, a Zwitterionic Phosphazene, and a Donor-Stabilized Alumazine-Phosphazene Hybrid Cation Eric Rivard, Paul J. Ragogna, Andrew R. McWilliams, Alan J. Lough, and Ian Manners pp 6789 - 6798; DOI: 10.1021/ic0509938 |
Issue 20
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Preface: Overview of the Forum on Solar and Renewable Energy Richard Eisenberg and Daniel G. Nocera pp 6799 - 6801; DOI: 10.1021/ic058006i |
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Chemical Approaches to Artificial Photosynthesis. 2 James H. Alstrum-Acevedo, M. Kyle Brennaman, and Thomas J. Meyer pp 6802 - 6827; DOI: 10.1021/ic050904r |
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Light-to-Chemical Energy Conversion in Lamellar Solids and Thin Films Paul G. Hoertz and Thomas E. Mallouk pp 6828 - 6840; DOI: 10.1021/ic050779j |
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Solar Energy Conversion by Dye-Sensitized Photovoltaic Cells Michael Grätzel pp 6841 - 6851; DOI: 10.1021/ic0508371 |
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Molecular Approaches to Solar Energy Conversion with Coordination Compounds Anchored to Semiconductor Surfaces Gerald J. Meyer pp 6852 - 6864; DOI: 10.1021/ic0505908 |
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Platinum Chromophore-Based Systems for Photoinduced Charge Separation: A Molecular Design Approach for Artificial Photosynthesis Soma Chakraborty, Thaddeus J. Wadas, Heidi Hester, Russell Schmehl, and Richard Eisenberg pp 6865 - 6878; DOI: 10.1021/ic0505605 |
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Molecular Chemistry of Consequence to Renewable Energy Jillian L. Dempsey, Arthur J. Esswein, David R. Manke, Joel Rosenthal, Jake D. Soper, and Daniel G. Nocera pp 6879 - 6892; DOI: 10.1021/ic0509276 |
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Exciton Multiplication and Relaxation Dynamics in Quantum Dots: Applications to Ultrahigh-Efficiency Solar Photon Conversion A. J. Nozik pp 6893 - 6899; DOI: 10.1021/ic0508425 |
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Chemical Control of Charge Transfer and Recombination at Semiconductor Photoelectrode Surfaces Nathan S. Lewis pp 6900 - 6911; DOI: 10.1021/ic051118p |
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Dimeric Dioxomolybdenum(VI) and Oxomolybdenum(V) Complexes with Citrate at Very Low pH and Neutral Conditions Zhao-Hui Zhou, Yuan-Fu Deng, Ze-Xing Cao, Rong-Hua Zhang, and Yuan L. Chow pp 6912 - 6914; DOI: 10.1021/ic048330y |
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Highly Stable Gold(III) Complex with a Hydantoin Ligand in Alkaline Media Kenichi Oyaizu, Yutaka Ohtani, Asako Shiozawa, Kenji Sugawara, Takashi Saito, and Makoto Yuasa pp 6915 - 6917; DOI: 10.1021/ic050515x |
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Unusual Role of Solvents in the Syntheses of {Fe-NO}6,7 Nitrosyls Derived from a Ligand with Carboxamido Nitrogen and Thiolato Sulfur Donors Todd C. Harrop, Marilyn M. Olmstead, and Pradip K. Mascharak pp 6918 - 6920; DOI: 10.1021/ic050659b |
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Mixed-Valent Diruthenium Diphosphonate with Kagomé Structure Bin Liu, Yi-Zhi Li, and Li-Min Zheng pp 6921 - 6923; DOI: 10.1021/ic050821a |
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Oxidative Degradation of Ethers Promoted by Strontium and Barium Tetraphenylimidodiphosphinates Jesús Morales-Juárez, Raymundo Cea-Olivares, Mónica M. Moya-Cabrera, Vojtech Jancik, Verónica García-Montalvo, and Rubén A. Toscano pp 6924 - 6926; DOI: 10.1021/ic050724h |
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Mononuclear Five-Coordinate Molybdenum(IV) and -(V) Monosulfide Complexes Coordinated with Dithiolene Ligands: Reversible Redox of Mo(V)/Mo(IV) and Irreversible Dimerization of [MoVS]- Cores to a Dinuclear [MoV2(-S)2]2- Core Hideki Sugimoto, Takashi Sakurai, Hiroyuki Miyake, Koji Tanaka, and Hiroshi Tsukube pp 6927 - 6929; DOI: 10.1021/ic0509128 |
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Structural Tuning of Ligand-Based Two-Electron Intervalence Charge Transfer Julien Bachmann and Daniel G. Nocera pp 6930 - 6932; DOI: 10.1021/ic0511017 |
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From Diamondoid Network to (4,4) Net: Effect of Ligand Topology on the Supramolecular Structural Diversity D. Krishna Kumar, D. Amilan Jose, Amitava Das, and Parthasarathi Dastidar pp 6933 - 6935; DOI: 10.1021/ic050972d |
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An Unusually Stable Trinuclear Manganese(II) Complex Bearing Bulk Carboxylic Radical Ligands Daniel Maspoch, Jordi Gómez-Segura, Neus Domingo, Daniel Ruiz-Molina, Klaus Wurst, Concepció Rovira, Javier Tejada, and Jaume Veciana pp 6936 - 6938; DOI: 10.1021/ic050977a |
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Magnetic Properties of Cyano-Bridged Ln3+-M3+ Complexes. Part I: Trinuclear Complexes (Ln3+ = La, Ce, Pr, Nd, Sm; M3+ = FeLS, Co) with bpy as Blocking Ligand Albert Figuerola, Joan Ribas, Miquel Llunell, David Casanova, Miguel Maestro, Santiago Alvarez, and Carmen Diaz pp 6939 - 6948; DOI: 10.1021/ic050648i |
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Magnetism of Cyano-Bridged Ln3+-M3+ Complexes. Part II: One-Dimensional Complexes (Ln3+ = Eu, Tb, Dy, Ho, Er, Tm; M3+ = Fe or Co) with bpy as Blocking Ligand Albert Figuerola, Joan Ribas, David Casanovas, Miguel Maestro, Santiago Alvarez, and Carmen Diaz pp 6949 - 6958; DOI: 10.1021/ic050650+ |
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Synthesis and X-ray Structure of the MnIICl2 and MnIIIF2 Complexes of N,N'-Dimethyl-2,11-diaza[3,3](2,6)pyridinophane. High-Field Electron Paramagnetic Resonance and Density Funtional Theory Studies of the Mn(III) Complex. Evidence for a Low-Lying Spin Triplet State Belén Albela, Riccardo Carina, Clotilde Policar, Sandrine Poussereau, Joan Cano, Jean Guilhem, Luba Tchertanov, Geneviève Blondin, Michel Delroisse, and Jean-Jacques Girerd pp 6959 - 6966; DOI: 10.1021/ic048302f |
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A 2D Layered Spin Crossover Complex Constructed by NH···Cl- Hydrogen Bonds: [FeIIH3LMe]Cl·I3 (H3LMe = Tris[2-(((2-methylimidazoyl-4-yl)methylidene)amino)ethyl]amine Masahiro Yamada, Eri Fukumoto, Makoto Ooidemizu, Nicolas Bréfuel, Naohide Matsumoto, Seiichiro Iijima, Masaaki Kojima, Nazzareno Re, Françoise Dahan, and Jean-Pierre Tuchagues pp 6967 - 6974; DOI: 10.1021/ic050008f |
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Study of Hg22+ and Complexes of NpO2+ and UO22+ in Solution. Examples of Cation-Cation Interactions Michael L. McKee and Marcel Swart pp 6975 - 6982; DOI: 10.1021/ic050224o |
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Cyano-Bridged Hexanuclear Fe4M2 (M = Ni, Co, Mn) Clusters: Spin-Canted Antiferromagnetic Ordering of Fe4Ni2 Cluster Jinkwon Kim, Sujin Han, Konstantin I. Pokhodnya, Jesse M. Migliori, and Joel S. Miller pp 6983 - 6988; DOI: 10.1021/ic0500356 |
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Characterization of a 1:1 Cu-O2 Adduct Supported by an Anilido Imine Ligand Anne M. Reynolds, Benjamin F. Gherman, Christopher J. Cramer, and William B. Tolman pp 6989 - 6997; DOI: 10.1021/ic050280p |
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Novel Zinc Phosphate Topologies Defined by Organic Ligands Jian Fan and Brian E. Hanson pp 6998 - 7008; DOI: 10.1021/ic050314t |
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Energetic Quaternary Salts Containing Bi(1,2,4-triazoles) Hong Xue, Brendan Twamley, and Jean'ne M. Shreeve pp 7009 - 7013; DOI: 10.1021/ic0504691 |
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Tridentate Copper Ligand Influences on Heme-Peroxo-Copper Formation and Properties: Reduced, Superoxo, and -Peroxo Iron/Copper Complexes Eunsuk Kim, Matthew E. Helton, Shen Lu, Pierre Moënne-Loccoz, Christopher D. Incarvito, Arnold L. Rheingold, Susan Kaderli, Andreas D. Zuberbühler, and Kenneth D. Karlin pp 7014 - 7029; DOI: 10.1021/ic050446m |
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NMR and Structural Investigations of A Nonplanar Iron Corrolate: Modified Patterns of Spin Delocalization and Coupling in A Slightly Saddled Chloroiron(III) Corrolate Radical Sara Nardis, Roberto Paolesse, Silvia Licoccia, Frank R. Fronczek, M. Graça H. Vicente, Tatjana K. Shokhireva, Sheng Cai, and F. Ann Walker pp 7030 - 7046; DOI: 10.1021/ic0504846 |
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Crystal Growth, Structural Transitions, and Magnetic Properties of the Fluorite-Related Osmates: Sm3OsO7, Eu3OsO7, and Gd3OsO7 William R. Gemmill, Mark D. Smith, Yurij A. Mozharivsky, Gordon J. Miller, and Hans-Conrad zur Loye pp 7047 - 7055; DOI: 10.1021/ic0506106 |
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Two Supramolecular Isomers of Molecular Squares and 1D Helical Chains with Alternating Right- and Left-Handed Chirality Long Jiang, Tong-Bu Lu, and Xiao-Long Feng pp 7056 - 7062; DOI: 10.1021/ic050626w |
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Cyano-Bridged CuII-MV (M = Mo, W) Bimetallic Layered Complexes Exhibiting Novel Honeycomblike Structures Young Sin You, Jung Hee Yoon, Jeong Hak Lim, Hyoung Chan Kim, and Chang Seop Hong pp 7063 - 7069; DOI: 10.1021/ic050634c |
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Fluoroformyl Trifluoroacetyl Disulfide, FC(O)SSC(O)CF3: Synthesis, Structure in Solid and Gaseous States, and Conformational Properties Mauricio F. Erben, Carlos O. Della Védova, Helge Willner, Frank Trautner, Heinz Oberhammer, and Ronald Boese pp 7070 - 7077; DOI: 10.1021/ic0506862 |
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Polymorphic One-Dimensional (N2H4)2ZnTe: Soluble Precursors for the Formation of Hexagonal or Cubic Zinc Telluride David B. Mitzi pp 7078 - 7086; DOI: 10.1021/ic050833w |
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Molecular and Electronic Structure of Five-Coordinate Complexes of Iron(II/III) Containing o-Diiminobenzosemiquinonate(1-) Radical Ligands Krzysztof Ch opek, Eckhard Bill, Thomas Weyhermüller, and Karl Wieghardtpp 7087 - 7098; DOI: 10.1021/ic050829k |
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Tuning of Spin Transition in Radical-Containing Iron(III) Complexes by Remote Ligand Substituents Soumen Mukherjee, Thomas Weyhermüller, Eckhard Bill, Karl Wieghardt, and Phalguni Chaudhuri pp 7099 - 7108; DOI: 10.1021/ic050885l |
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Modulation of the Ring Size and Nuclearity of Metallamacrocycles via the Steric Effect of Ligands: Preparation and Characterization of 18-Membered Hexanuclear, 24-Membered Octanuclear, and 30-Membered Decanuclear Manganese Metalladiazamacrocycles with - and -Branched N-Acylsalicylhydrazides Rohith P. John, Kyungjae Lee, Beom Jin Kim, Byoung Jin Suh, Hackjune Rhee, and Myoung Soo Lah pp 7109 - 7121; DOI: 10.1021/ic050891h |
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A Series of Three-Dimensional Lanthanide Coordination Polymers with Rutile and Unprecedented Rutile-Related Topologies Chao Qin, Xin-Long Wang, En-Bo Wang, and Zhong-Min Su pp 7122 - 7129; DOI: 10.1021/ic050906b |
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Self-Assembly of Neutral Platinum-Based Supramolecular Ensembles Incorporating Oxocarbon Dianions and Oxalate Neeladri Das, Ashutosh Ghosh, Atta M. Arif, and Peter J. Stang pp 7130 - 7137; DOI: 10.1021/ic050919p |
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Ln18Li8Rh5O39 (Ln = La, Pr): a Mixed-Metal Oxide with a Charge-Ordered Arrangement of Rh3+ and Rh4+ Philip P. C. Frampton, Peter D. Battle, and Clemens Ritter pp 7138 - 7142; DOI: 10.1021/ic050949s |
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Decomposition of Monochlorogallane, [H2GaCl]n, and Adducts with Amine and Phosphine Bases: Formation of Cationic Gallane Derivatives Christina Y. Tang, Anthony J. Downs, Tim M. Greene, Sarah Marchant, and Simon Parsons pp 7143 - 7150; DOI: 10.1021/ic050986j |
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Photophysical and Structural Impact of Phosphorylated Anions Associated to Lanthanide Complexes in Water Loïc J. Charbonnière, Rachel Schurhammer, Samir Mameri, Georges Wipff, and Raymond F. Ziessel pp 7151 - 7160; DOI: 10.1021/ic051033o |
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1D Helix, 2D Brick-Wall and Herringbone, and 3D Interpenetration d10 Metal-Organic Framework Structures Assembled from Pyridine-2,6-dicarboxylic Acid N-Oxide Li-Li Wen, Dong-Bin Dang, Chun-Ying Duan, Yi-Zhi Li, Zheng-Fang Tian, and Qing-Jin Meng pp 7161 - 7170; DOI: 10.1021/ic0509985 |
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Coordinatively Induced Length Control and Photoluminescence of W18O49 Nanorods Kyoungja Woo, Jangwon Hong, Jae-Pyoung Ahn, Jong-Ku Park, and Kang-Jin Kim pp 7171 - 7174; DOI: 10.1021/ic0504644 |
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Density Functional Theory-Based Prediction of the Formation Constants of Complexes of Ammonia in Aqueous Solution: Indications of the Role of Relativistic Effects in the Solution Chemistry of Gold(I) Robert D. Hancock and Libero J. Bartolotti pp 7175 - 7183; DOI: 10.1021/ic050471s |
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Condensed Two- and Three-Dimensional Aromatic Systems: A Theoretical Study on the Relative Stabilities of Isomers of CB19H16+, B20H15Cl, and B20H14Cl2 and Comparison to B12H10Cl22-, C6H4Cl2, C10H7Cl, and C10H6Cl2 Eluvathingal D. Jemmis, Biswarup Pathak, and Anakuthil Anoop pp 7184 - 7188; DOI: 10.1021/ic050730d |
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Infrared Spectrum and Structure of the Hf(OH)4 Molecule Xuefeng Wang and Lester Andrews pp 7189 - 7193; DOI: 10.1021/ic050614a |
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[1,2,5]Thiadiazolo[3,4-c][1,2,5]thiadiazolidyl: A Long-Lived Radical Anion and Its Stable Salts Alexander Yu. Makarov, Irina G. Irtegova, Nadezhda V. Vasilieva, Irina Yu. Bagryanskaya, Tobias Borrmann, Yuri V. Gatilov, Enno Lork, Ruediger Mews, Wolf-Dieter Stohrer, and Andrey V. Zibarev pp 7194 - 7199; DOI: 10.1021/ic050583j |
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(Fluoren-9-ylidene)methanedithiolato Complexes of Platinum: Synthesis, Reactivity, and Luminescence1 José Vicente, Pablo González-Herrero, María Pérez-Cadenas, Peter G. Jones, and Delia Bautista pp 7200 - 7213; DOI: 10.1021/ic050748o |
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Copper(II) Interaction with Unstructured Prion Domain Outside the Octarepeat Region: Speciation, Stability, and Binding Details of Copper(II) Complexes with PrP106-126 Peptides Giuseppe Di Natale, Giulia Grasso, Giuseppe Impellizzeri, Diego La Mendola, Giovanni Micera, Nikolett Mihala, Zoltán Nagy, Katalin Õsz, Giuseppe Pappalardo, Viktória Rigó, Enrico Rizzarelli, Daniele Sanna, and Imre Sóvágó pp 7214 - 7225; DOI: 10.1021/ic050754k |
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New CVD Precursors Capable of Depositing Copper Metal under Mixed O2/Ar Atmosphere Eddy Lay, Yi-Hwa Song, Yuan-Chieh Chiu, Yang-Miin Lin, Yun Chi, Arthur J. Carty, Shie-Ming Peng, and Gene-Hsiang Lee pp 7226 - 7233; DOI: 10.1021/ic050845h |
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Chemistry of a Ni(II) Acetohydroxamic Acid Complex: Formation, Reactivity with Water, and Attempted Preparation of Zinc and Cobalt Analogues Katarzyna Rudzka, Atta M. Arif, and Lisa M. Berreau pp 7234 - 7242; DOI: 10.1021/ic0508122 |
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Polyhedral Cobalt(II) and Iron(II) Siloxanes: Synthesis and X-ray Crystal Structure of [(RSi(OH)O2)Co(OPMe3)]4 and [(RSiO3)2(RSi(OH)O2)4(3-OH)2Fe8(THF)4] (R = (2,6-iPr2C6H3)N(SiMe3)) Umesh N. Nehete, Herbert W. Roesky, Hongping Zhu, Sharanappa Nembenna, Hans-Georg Schmidt, Mathias Noltemeyer, Dmitrij Bogdanov, and Konrad Samwer pp 7243 - 7248; DOI: 10.1021/ic050859n |
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Camouflaged Carborane Amphiphiles: Synthesis and Self-Assembly Ling Ma, Julie Hamdi, Jiaxing Huang, and M. Frederick Hawthorne pp 7249 - 7258; DOI: 10.1021/ic050895m |
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Comparative Studies of Substitution Reactions of Rhenium(I) Dicarbonyl-Nitrosyl and Tricarbonyl Complexes in Aqueous Media. Niklaus Marti, Bernhard Spingler, Frank Breher, and Roger Schibli: pp 7259 - 7260; DOI: 10.1021/ic058007a |
Issue 21
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Photocytotoxicity of a New Rh2(II,II) Complex: Increase in Cytotoxicity upon Irradiation Similar to That of PDT Agent Hematoporphyrin Alfredo M. Angeles-Boza, Patricia M. Bradley, Patty K.-L. Fu, Mikhail Shatruk, Matthew G. Hilfiger, Kim R. Dunbar, and Claudia Turro pp 7262 - 7264; DOI: 10.1021/ic0500715 |
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Unassisted 2-Coordination of Polycyclic Aromatic Hydrocarbons to Platinum(II) Jesús R. Berenguer, Juan Forniés, L. Francisco Martín, Antonio Martín, and Babil Menjón pp 7265 - 7267; DOI: 10.1021/ic050405q |
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N,N,N',N'-Tetrakis(2-quinolylmethyl)-2-hydroxy-1,3-propanediamine (Htqhpn) as a Supporting Ligand for a Low-Valent (-O)2 Tetranuclear Manganese Core Yuji Mikata, Motoko Wakamatsu, Haruka So, Yuriko Abe, Masahiro Mikuriya, Kôichi Fukui, and Shigenobu Yano pp 7268 - 7270; DOI: 10.1021/ic050582r |
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First Structural Characterization of a Delocalized, Mixed-Valent, Triangular Cu37+ Species: Chemical and Electrochemical Oxidation of a CuII3(3-O) Pyrazolate and Electronic Structure of the Oxidation Product Gellert Mezei, John E. McGrady, and Raphael G. Raptis pp 7271 - 7273; DOI: 10.1021/ic050729e |
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Formation of Zinc Phosphate Polymers and Networks through the Insertion of Metathiophosphates into Zinc Dialkyldithiophosphates Nicholas J. Mosey and Tom K. Woo pp 7274 - 7276; DOI: 10.1021/ic050839l |
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Reversible Penta- and Hexacoordination Motifs in [Co(TMPP)] Resulting in Interchange of 1D and 2D Supramolecular Designs Suman Maji, Anil Kumar, Kuntal Pal, and Sabyasachi Sarkar pp 7277 - 7279; DOI: 10.1021/ic050900m |
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Room-Temperature Irradiation Route To Synthesize a Large-Scale Single-Crystalline ZnO Hexangular Prism Yong Hu, Jiafu Chen, Xuan Xue, Tanwei Li, and Yi Xie pp 7280 - 7282; DOI: 10.1021/ic050909o |
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Pulsed EPR Studies of a Bacterial Sulfite-Oxidizing Enzyme with pH-Invariant Hyperfine Interactions from Exchangeable Protons Arnold M. Raitsimring, Ulrike Kappler, Changjian Feng, Andrei V. Astashkin, and John H. Enemark pp 7283 - 7285; DOI: 10.1021/ic0509534 |
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Synthesis of a Manganese Germavinylidene Complex from Bis(germavinylidene) Wing-Por Leung, Cheuk-Wai So, Kwok-Wai Kan, Hoi-Shan Chan, and Thomas C. W. Mak pp 7286 - 7288; DOI: 10.1021/ic050969u |
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Novel Structural and Magnetic Properties of a 1-D Iron(II)-Manganese(II) LIESST Compound Bridged by Cyanide Shinya Hayami, Gergely Juhász, Yonezo Maeda, Toshihiko Yokoyama, and Osamu Sato pp 7289 - 7291; DOI: 10.1021/ic0509837 |
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{Zn3(Et2O)2[(EtO)PO2(C6H5NH)]6·2THF}: A Trinuclear Zinc Amidophosphate with an Hourglass Structure Zhiyong Fu and Tristram Chivers pp 7292 - 7294; DOI: 10.1021/ic051012u |
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Spin-Crossover Cobalt(II) Compound with Banana-Shaped Structure Shinya Hayami, Reiko Moriyama, Yuji Shigeyoshi, Ryo Kawajiri, Tadaoki Mitani, Motoko Akita, Katsuya Inoue, and Yonezo Maeda pp 7295 - 7297; DOI: 10.1021/ic051059f |
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Novel 3-D Framework Nickel(II) Complex with Azide, Nicotinic Acid, and Nicotinate(1-) as Coligands: Hydrothermal Synthesis, Structure, and Magnetic Properties Fu-Chen Liu, Yong-Fei Zeng, Jian-Rong Li, Hong-Jie Zhang, and Xian-He Bu pp 7298 - 7300; DOI: 10.1021/ic051030b |
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Cuprophilicity-Induced Cocrystallization of [Cu2(4,4'-bpy)(CN)2]n Sheets and [Cu(SCN)]n Chains into a 3-D Pseudopolyrotaxane Xian-Ming Zhang, Zheng-Ming Hao, and Hai-Shun Wu pp 7301 - 7303; DOI: 10.1021/ic051104j |
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Imidomolybdenum(IV) Porphyrin Complexes: Synthesis, Characterization, and Intermetal Imido Transfer Reactivity Lisa M. Berreau, Jinyuan Chen, and L. Keith Woo pp 7304 - 7306; DOI: 10.1021/ic051100e |
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Trans-Fused Macrobicycle "Betweenanene" around a Planar Cu2(-CH3O)2 Core Showing Remarkable Antiferromagnetic Interaction Takayuki Ishida, Kenji Yanagi, and Takashi Nogami pp 7307 - 7309; DOI: 10.1021/ic051133u |
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Preference for Nitrogen versus Oxygen Donor Coordination in Uranyl- and Neptunyl(VI) Complexes Mark J. Sarsfield, Iain May, Stephanie M. Cornet, and Madeleine Helliwell pp 7310 - 7312; DOI: 10.1021/ic051161c |
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Inclusion of a Cu2+ Ion by a Large-Cavity Crown Ether Dibenzo-24-Crown-8 through Supramolecular Interactions Vaddypally Shivaiah and Samar K. Das pp 7313 - 7315; DOI: 10.1021/ic051176a |
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Niobium and Tantalum Tris(methimazolyl)borate Complexes [M(=NC6H3iPr2-2,6)Cl2{HB(mt)3}] (M = Nb, Ta; mt = Methimazolyl) Anthony F. Hill, A. David Rae, and Matthew K. Smith pp 7316 - 7318; DOI: 10.1021/ic051218v |
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Heterobimetallic Reductive Cross-Coupling of Benzonitrile with Carbon Dioxide, Pyridine, and Benzophenone Arjun Mendiratta and Christopher C. Cummins pp 7319 - 7321; DOI: 10.1021/ic051320s |
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Fluorinated Tris(pyrazolyl)borate Ligands without the Problematic Hydride Moiety: Isolation of Copper(I) Ethylene and Copper(I)-Tin(II) Complexes Using [MeB(3-(CF3)Pz)3]- H. V. Rasika Dias, Xiaoyu Wang, and Himashinie V. K. Diyabalanage pp 7322 - 7324; DOI: 10.1021/ic0513235 |
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Polymer Building Blocks: Self-Assembly of Silver(I) Cyclotriphosphazene Cationic Columns Eric W. Ainscough, Andrew M. Brodie, Craig V. Depree, Geoffrey B. Jameson, and Carl A. Otter pp 7325 - 7327; DOI: 10.1021/ic051334y |
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Chemistry of Transition-Metal Clusters with Mixed Sb/S Ligands: Evidence for a Terminal Sb=S Double Bond in Cp*3Rh3Sb2S5 (Cp* = C5Me5) Andreas Lange, Marek M. Kubicki, Joachim Wachter, and Manfred Zabel pp 7328 - 7332; DOI: 10.1021/ic050493e |
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Electronic Structures of Six-Coordinate Ferric Porphyrin Complexes with Weak Axial Ligands: Usefulness of 13C NMR Chemical Shifts Akito Hoshino, Yoshiki Ohgo, and Mikio Nakamura pp 7333 - 7344; DOI: 10.1021/ic0488942 |
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Bis(-oxo)dicopper(III) Complexes of a Homologous Series of Simple Peralkylated 1,2-Diamines: Steric Modulation of Structure, Stability, and Reactivity Adam P. Cole, Viswanath Mahadevan, Liviu M. Mirica, Xavier Ottenwaelder, and T. Daniel P. Stack pp 7345 - 7364; DOI: 10.1021/ic050331i |
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New Palladium(II) and Platinum(II) Complexes with the Model Nucleobase 1-Methylcytosine: Antitumor Activity and Interactions with DNA José Ruiz, Natalia Cutillas, Consuelo Vicente, María Dolores Villa, Gregorio López, Julia Lorenzo, Francesc X. Avilés, Virtudes Moreno, and Delia Bautista pp 7365 - 7376; DOI: 10.1021/ic0502372 |
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Photophysical Properties of Ru(II) Bipyridyl Complexes Containing Hemilabile Phosphine-Ether Ligands Sarah E. Angell, Yan Zhang, Cerrie W. Rogers, Michael O. Wolf, and Wayne E. Jones, Jr. pp 7377 - 7384; DOI: 10.1021/ic050436l |
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Solvothermal Synthesis of Nanocrystalline Copper Nitride from an Energetically Unstable Copper Azide Precursor Jonglak Choi and Edward G. Gillan pp 7385 - 7393; DOI: 10.1021/ic050497j |
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Tribasic Lead Maleate and Lead Maleate: Synthesis and Structural and Spectroscopic Characterizations François Bonhomme, Todd M. Alam, Aaron J. Celestian, David R. Tallant, Timothy J. Boyle, Brian R. Cherry, Ralph G. Tissot, Mark A. Rodriguez, John B. Parise, and May Nyman pp 7394 - 7402; DOI: 10.1021/ic050611y |
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Uranium(III)/(IV) Nitrile Adducts Including UI4(NCPh)4, a Synthetically Useful Uranium(IV) Complex Alejandro E. Enriquez, Brian L. Scott, and Mary P. Neu pp 7403 - 7413; DOI: 10.1021/ic050578f |
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Influence of Ligand Rigidity and Ring Substitution on the Structural and Electronic Behavior of Trivalent Iron and Gallium Complexes with Asymmetric Tridentate Ligands Camille Imbert, Hrant P. Hratchian, Mauricio Lanznaster, Mary Jane Heeg, Lew M. Hryhorczuk, Bruce R. McGarvey, H. Bernhard Schlegel, and Claudio N. Verani pp 7414 - 7422; DOI: 10.1021/ic050658j |
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KBi2-xPbx (0 < x 1): A Zintl Phase Evolving from a Distortion of the Cubic Laves-Phase Structure Siméon Ponou, Noémi Müller, Thomas F. Fässler, and Ulrich Häussermann pp 7423 - 7430; DOI: 10.1021/ic050603h |
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Structural and Spectroscopic Study of Reactions between Chelating Zinc-Binding Groups and Mimics of the Matrix Metalloproteinase and Disintegrin Metalloprotease Catalytic Sites: The Coordination Chemistry of Metalloprotease Inhibition Hongshan He, David T. Puerta, Seth M. Cohen, and Kenton R. Rodgers pp 7431 - 7442; DOI: 10.1021/ic050723p |
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Evidence of Incipient Bond-Stretching Isomerism in Sr2.04(1)Ca0.96(1)Sn5 from Variable-Temperature Structural Studies Shalabh Gupta and Ashok K. Ganguli pp 7443 - 7448; DOI: 10.1021/ic050677t |
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Spectroscopy and Coordination Chemistry of a New Bisnaphthalene-Bisphenanthroline Ligand Displaying a Sensing Ability for Metal Cations João Pina, J. Seixas de Melo, Fernando Pina, Carlos Lodeiro, J. C. Lima, A. Jorge Parola, Conxa Soriano, M. Paz Clares, M. Teresa Albelda, Ricardo Aucejo, and Enrique García-España pp 7449 - 7458; DOI: 10.1021/ic050733q |
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Contrasting Chemistry of cis- and trans-Platinum(II) Diamine Anticancer Compounds: Hydrolysis Studies of Picoline Complexes Geraldine McGowan, Simon Parsons, and Peter J. Sadler pp 7459 - 7467; DOI: 10.1021/ic050763t |
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NMR and EPR Studies of Low-Spin Fe(III) Complexes of meso-Tetra-(2,6-Disubstituted Phenyl)Porphyrinates Complexed to Imidazoles and Pyridines of Widely Differing Basicities C. Todd Watson, Sheng Cai, Nikolai V. Shokhirev, and F. Ann Walker pp 7468 - 7484; DOI: 10.1021/ic0507316 |
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Trilacunary Heteropolytungstates Functionalized by Organometallic Ruthenium(II), [(RuC6H6)2XW9O34]6- (X = Si, Ge) Li-Hua Bi, Ulrich Kortz, Michael H. Dickman, B. Keita, and L. Nadjo pp 7485 - 7493; DOI: 10.1021/ic0508627 |
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Oxygen Atom Transfer Reactivity from a Dioxo-Mo(VI) Complex to Tertiary Phosphines: Synthesis, Characterization, and Structure of Phosphoryl Intermediate Complexes Victor N. Nemykin and Partha Basu pp 7494 - 7502; DOI: 10.1021/ic0508324 |
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Role of Anions on the Crystal Structures of Copper(II) and Zinc(II) Complexes of a Tunable Butterfly Cyclophane Macrocycle Martin Chadim, Pilar Díaz, Enrique García-España, Jana Hoda ová, Julio Latorre, Malva Liu-González, Santiago V. Luis, José M. Llinares, and Ji í Závadapp 7503 - 7510; DOI: 10.1021/ic051099j |
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NMR Investigation of the Interaction of Vanadate with Carbasilatranes in Aqueous Solutions Evgenios M. Evgeniou, Spyros A. Pergantis, Epameinondas Leontidis, and Anastasios D. Keramidas pp 7511 - 7522; DOI: 10.1021/ic050929q |
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Magnetic Properties of Isostructural BaCoP2O7, BaNiP2O7, and BaCuP2O7 Studied with dc and ac Magnetization and Specific Heat Alexei A. Belik, Masaki Azuma, and Mikio Takano pp 7523 - 7529; DOI: 10.1021/ic050938z |
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Structure and Magnetic Properties of (meso-Tetraphenylporphinato)manganese(III) Bis(dithiolato)nickelates Louise N. Dawe, Jesse Miglioi, Laura Turnbow, Michelle L. Taliaferro, William W. Shum, Joshua D. Bagnato, Lev N. Zakharov, Arnold L. Rheingold, Atta M. Arif, Marc Fourmigué, and Joel S. Miller pp 7530 - 7539; DOI: 10.1021/ic050980u |
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Counteranion-Controlled Water Cluster Recognition in a Protonated Octaamino Cryptand P. S. Lakshminarayanan, D. Krishna Kumar, and Pradyut Ghosh pp 7540 - 7546; DOI: 10.1021/ic051191f |
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Photon-, Electron-, and Proton-Induced Isomerization Behavior of Ferrocenylazobenzenes Aiko Sakamoto, Akira Hirooka, Kosuke Namiki, Masato Kurihara, Masaki Murata, Manabu Sugimoto, and Hiroshi Nishihara pp 7547 - 7558; DOI: 10.1021/ic051184r |
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Phosphate Triester Hydrolysis Promoted by an N2S(thiolate)Zn Complex: Mechanistic Implications for the Metal-Dependent Reactivity of Peptide Deformylase David P. Goldberg, Robert C. diTargiani, Frances Namuswe, Ellen C. Minnihan, SeChin Chang, Lev N. Zakharov, and Arnold L. Rheingold pp 7559 - 7569; DOI: 10.1021/ic0511571 |
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Sulfate Complexation of Trivalent Lanthanides Probed by Nanoelectrospray Mass Spectrometry and Time-Resolved Laser-Induced Luminescence Thomas Vercouter, Badia Amekraz, Christophe Moulin, Eric Giffaut, and Pierre Vitorge pp 7570 - 7581; DOI: 10.1021/ic048503j |
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Chelate Ring Size Variations and Their Effects on Coordination Chemistry and Catechol Dioxygenase Reactivity of Iron(III) Complexes Michael Merkel, Matthias Pascaly, Bernt Krebs, Jörg Astner, Simon P. Foxon, and Siegfried Schindler pp 7582 - 7589; DOI: 10.1021/ic050708k |
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Vibrational Spectra and Gas-Phase Structure of N-Methyl-S,S-bis(trifluoromethyl)sulfimide, CH3N=S(CF3)2 Frank Trautner, Rosa M. S. Alvarez, Edgardo H. Cutin, Norma L. Robles, Rüdiger Mews, and Heinz Oberhammer pp 7590 - 7594; DOI: 10.1021/ic0504947 |
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A Deprotonated Intermediate in the Amide Methanolysis Reaction of an N4O-Ligated Mononuclear Zinc Complex Ewa Szajna, Magdalena M. Makowska-Grzyska, Chad C. Wasden, Atta M. Arif, and Lisa M. Berreau pp 7595 - 7605; DOI: 10.1021/ic050750f |
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The Synthesis, Structural, and Spectroscopic Characterization of Uranium(IV) Perrhenate Complexes Gordon H. John, Iain May, Clint A. Sharrad, Andrew D. Sutton, David Collison, Madeleine Helliwell, and Mark J. Sarsfield pp 7606 - 7615; DOI: 10.1021/ic0507971 |
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NMR, PGSE Diffusion, and X-ray Diffraction Studies of Lithium and Potassium Salts Derived from Diphenylphosphino(o-cyanophenyl)aniline and Their Crown Ether Complexes Ignacio Fernández, Frank Breher, Paul S. Pregosin, Zhaofu Fei, and Paul J. Dyson pp 7616 - 7623; DOI: 10.1021/ic050753s |
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Effect of Pressure on Proton-Coupled Electron Transfer Reactions of Seven-Coordinate Iron Complexes in Aqueous Solutions David Sarauli, Roland Meier, Gao-Feng Liu, Ivana Ivanovi -Burmazovi, and Rudi van Eldikpp 7624 - 7633; DOI: 10.1021/ic0507767 |
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Infrared Spectra of CH3-CrH, CH3-WH, CH2=WH2, and CHWH3 Formed by Activation of CH4 with Cr and W Atoms Han-Gook Cho, Lester Andrews, and Colin Marsden pp 7634 - 7643; DOI: 10.1021/ic051090h |
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Exploring the Universality of Unusual Conformations of the 17-Membered Pt(d(G*pG*)) Macrochelate Ring. Dependence of Conformer Formation on a Change in Bidentate Carrier Ligand from an sp3 to an sp2 Nitrogen Donor Debadeep Bhattacharyya, Patricia A. Marzilli, and Luigi G. Marzilli pp 7644 - 7651; DOI: 10.1021/ic050925l |
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An Electrochiroptical Molecular Switch: Mechanistic and Kinetic Studies Homar S. Barcena, Biao Liu, Michael V. Mirkin, and James W. Canary pp 7652 - 7660; DOI: 10.1021/ic051048m |
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General Synthesis of Di--oxo Dimanganese Complexes as Functional Models for the Oxygen Evolving Complex of Photosystem II Hongyu Chen, Ranitendranath Tagore, Siddhartha Das, Christopher Incarvito, J. W. Faller, Robert H. Crabtree, and Gary W. Brudvig pp 7661 - 7670; DOI: 10.1021/ic0509940 |
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Iron(III) Coordination Chemistry of Alterobactin A: A Siderophore from the Marine Bacterium Alteromonas luteoviolacea Pamela D. Holt, Richard R. Reid, Brent L. Lewis, George W. Luther III, and Alison Butler pp 7671 - 7677; DOI: 10.1021/ic0512072 |
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[Ru(phen)2(PHEHAT)]2+ and [Ru(phen)2(HATPHE)]2+: Two Ruthenium(II) Complexes with the Same Ligands but Different Photophysics and Spectroelectrochemistry Arnaud Boisdenghien, Cécile Moucheron, and Andrée Kirsch-De Mesmaeker pp 7678 - 7685; DOI: 10.1021/ic051306f |
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On the Existence and Stability of Branched Selenium Chains: Isomers of Me2Se3 and Et2Se3. R. Steudel and and Y. Steudel: pp 7686 - 7686; DOI: 10.1021/ic050639+ |
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Theoretical Reduction Potentials for Nitrogen Oxides from CBS-QB3 Energetics and (C)PCM Solvation Calculations Andrew S. Dutton, Jon M. Fukuto, and Kendall N. Houk: pp 7687 - 7688; DOI: 10.1021/ic051423a |
Issue 22
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First-Transition-Metal Complexes Containing the Ligands 6-Amino-6-methylperhydro-1,4-diazepine (AAZ) and a New Functionalized Derivative: Can AAZ Act as a Mimetic Ligand for 1,4,7-Triazacyclononane? Rosely A. Peralta, Ademir Neves, Adailton J. Bortoluzzi, Annelise Casellato, Ademir dos Anjos, Alessandra Greatti, Fernando R. Xavier, and Bruno Szpoganicz pp 7690 - 7692; DOI: 10.1021/ic050755c |
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Isolated Mn12 Single-Molecule Magnets Grafted on Gold Surfaces via Electrostatic Interactions Eugenio Coronado, Alicia Forment-Aliaga, Francisco M. Romero, Valdis Corradini, Roberto Biagi, Valentina De Renzi, Alessandro Gambardella, and Umberto del Pennino pp 7693 - 7695; DOI: 10.1021/ic0508021 |
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Template-Assisted Ligand Encapsulation; the Impact of an Unusual Coordination Geometry on a Supramolecular Pyridylphosphine-Zn(II)porphyrin Assembly Arjan W. Kleij, Mark Kuil, Duncan M. Tooke, Anthony L. Spek, and Joost N. H. Reek pp 7696 - 7698; DOI: 10.1021/ic050858v |
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Direct Incorporation of a Ferric Ion in the Porphyrinogen Core: Tetrakis(cyclohexyl)iron Porphyrinogen Anion with Different Conformers and Its Reaction with Iodine Dibyendu Bhattacharya, Soumen Dey, Suman Maji, Kuntal Pal, and Sabyasachi Sarkar pp 7699 - 7701; DOI: 10.1021/ic050890p |
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A T-Shaped Three-Coordinate Nickel(I) Carbonyl Complex and the Geometric Preferences of Three-Coordinate d9 Complexes Nathan A. Eckert, Adriana Dinescu, Thomas R. Cundari, and Patrick L. Holland pp 7702 - 7704; DOI: 10.1021/ic0510213 |
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Structure of [UO2Cl4]2- in Acetonitrile Kelly Servaes, Christoph Hennig, Rik Van Deun, and Christiane Görller-Walrand pp 7705 - 7707; DOI: 10.1021/ic051098r |
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Palladium and Rhodium Ureaphosphine Complexes: Exploring Structural and Catalytic Consequences of Anion Binding Paul A. Duckmanton, Alexander J. Blake, and Jason B. Love pp 7708 - 7710; DOI: 10.1021/ic051110f |
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Enantiopure 1,1'-Binaphthyl-Based Polyoxometalate-Containing Molecular Hybrids Meng Lu, Jeonghee Kang, Degang Wang, and Zhonghua Peng pp 7711 - 7713; DOI: 10.1021/ic051129i |
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Cyanide-Bridged W(V)-Mn(II) Bimetallic Double-Zigzag Chains with a Metamagnetic Nature Jung Hee Yoon, Hyoung Chan Kim, and Chang Seop Hong pp 7714 - 7716; DOI: 10.1021/ic051415u |
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Kinetic and Mechanistic Studies on the Reaction of Nitric Oxide with a Water-Soluble Octa-anionic Iron(III) Porphyrin Complex Joo-Eun Jee, Siegfried Eigler, Frank Hampel, Norbert Jux, Maria Wolak, Achim Zahl, Grazyna Stochel, and Rudi van Eldik pp 7717 - 7731; DOI: 10.1021/ic050924t |
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Mechanistic Information on the Reductive Elimination from Cationic Trimethylplatinum(IV) Complexes to Form Carbon-Carbon Bonds Joanna Procelewska, Achim Zahl, Günter Liehr, Rudi van Eldik, Nicole A. Smythe, B. Scott Williams, and Karen I. Goldberg pp 7732 - 7742; DOI: 10.1021/ic050478+ |
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Polynuclear Lanthanide Hydroxo Complexes: New Chemical Precursors for Coordination Polymers N. Mahé, O. Guillou, C. Daiguebonne, Y. Gérault, A. Caneschi, C. Sangregorio, J. Y. Chane-Ching, P. E. Car, and T. Roisnel pp 7743 - 7750; DOI: 10.1021/ic0401086 |
Synthesis, Crystal Structure, and Solution Stability of Keggin-Type Heteropolytungstates (NH4)6NiII0.5[-FeIIIO4W11O30NiIIO5(OH2)]·nH2O, (NH4)7Zn0.5[-ZnO4W11O30ZnO5(OH2)]·nH2O, and (NH4)7NiII0.5[-ZnO4W11O30NiIIO5(OH2)]·nH2O (n  18)Heiko Weiner, Hans-Joachim Lunk, Rita Friese, and Hans Hartl pp 7751 - 7761; DOI: 10.1021/ic048155l |
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New Class of Verdoheme Analogues with Weakly Coordinating Anions: The Structure of (-Oxo)bis[(octaethyloxoporphinato)iron(III)] Hexafluorophosphate Mozhgan Khorasani-Motlagh, Nasser Safari, Meissam Noroozifar, Jilla Saffari, Mahtab Biabani, Júlio S. Rebouças, and Brian O. Patrick pp 7762 - 7769; DOI: 10.1021/ic050211a |
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Heteroleptic Cyclometalated Iridium(III) Complexes Displaying Blue Phosphorescence in Solution and Solid State at Room Temperature Cheng-Han Yang, Shih-Wen Li, Yun Chi, Yi-Ming Cheng, Yu-Shan Yeh, Pi-Tai Chou, Gene-Hsiang Lee, Chih-Hsiang Wang, and Ching-Fong Shu pp 7770 - 7780; DOI: 10.1021/ic050311g |
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Electronic Structure of M(BH4)4, M = Zr, Hf, and U, by Variable Photon-Energy Photoelectron Spectroscopy and Density Functional Calculations Jennifer C. Green, Monica de Simone, Marcello Coreno, Aled Jones, Helen M. I. Pritchard, and G. Sean McGrady pp 7781 - 7793; DOI: 10.1021/ic050370u |
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Polymeric Networks of Copper(II) Phenylmalonate with Heteroaromatic N-donor Ligands: Synthesis, Crystal Structure, and Magnetic Properties Jorge Pasán, Joaquín Sanchiz, Catalina Ruiz-Pérez, Francesc Lloret, and Miguel Julve pp 7794 - 7801; DOI: 10.1021/ic0503986 |
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Toward Modeling H-NOX Domains: A DFT Study of Heme-NO Complexes as Hydrogen Bond Acceptors Espen Tangen, Anders Svadberg, and Abhik Ghosh pp 7802 - 7805; DOI: 10.1021/ic050486q |
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Possible Side Reactions Due to Water in Emulsion Polymerization by Late Transition Metal Complexes. 1. Water Complexation and Hydrolysis of the Growing Chain Iordan H. Hristov, Roger L. DeKock, Grant D. W. Anderson, Inigo Göttker-Schnetmann, Stefan Mecking, and Tom Ziegler pp 7806 - 7818; DOI: 10.1021/ic050501r |
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Density Functional Study of 8- and 11-Vertex Polyhedral Borane Structures: Comparison with Bare Germanium Clusters R. B. King, I. Silaghi-Dumitrescu, and A. Lupan pp 7819 - 7824; DOI: 10.1021/ic050656z |
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Ligand-Controlled Mixed-Valence Copper Rectangular Grid-Type Coordination Polymers Based on Pyridylterpyridine Lei Hou, Dan Li, Wen-Juan Shi, Ye-Gao Yin, and Seik Weng Ng pp 7825 - 7832; DOI: 10.1021/ic050558d |
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Coordination Networks with Flexible Ligands Based on Silver(I) Salts: Complexes of 1,3-Bis(phenylthio)propane with Silver(I) Salts of PF6-, CF3COO-, CF3CF2COO-, CF3CF2CF2COO-, p-TsO-, and CF3SO3- Mohamed Osman Awaleh, Antonella Badia, and François Brisse pp 7833 - 7845; DOI: 10.1021/ic050617n |
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Intramolecular Energy Transfer Involving Heisenberg Spin-Coupled Dinuclear Iron-Oxo Complexes Laura B. Picraux, Amanda L. Smeigh, Dong Guo, and James K. McCusker pp 7846 - 7859; DOI: 10.1021/ic0506761 |
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Ligand Conformation Enforces Trigonal Bipyramidal Coordination Geometry in a New Dinuclear Bis(pyrazolato)-Bridged Copper(II) Complex: Synthesis, Crystal Structure, and Properties of [Cu(Npy2pz)]2(ClO4)2·2CH3CN Stefania Tanase, Iryna A. Koval, Elisabeth Bouwman, René de Gelder, and Jan Reedijk pp 7860 - 7865; DOI: 10.1021/ic050793w |
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Indium(III)-Induced Fluorescent Excimer Formation and Extinction in Calix[4]arene-Fluoroionophores Sung Kuk Kim, Su Ho Kim, Hyun Jung Kim, Seoung Ho Lee, Soon W. Lee, Jaejung Ko, Richard A. Bartsch, and Jong Seung Kim pp 7866 - 7875; DOI: 10.1021/ic050702v |
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Pyridine-Substituted Oligopeptides as Scaffolds for the Assembly of Multimetallic Complexes: Variation of Chain Length Kristi Ohr, Brian P. Gilmartin, and Mary Elizabeth Williams pp 7876 - 7885; DOI: 10.1021/ic050769i |
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Self-Assembly of Rectangles and Prisms via a Molecular "Clip" Duckhyun Kim, Jong Hyub Paek, Moo-Jin Jun, Jin Yong Lee, Sang Ook Kang, and Jaejung Ko pp 7886 - 7894; DOI: 10.1021/ic0508369 |
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Synthesis, Characterization, and X-ray Crystal Structures of Cyclam Derivatives. 8. Thermodynamic and Kinetic Appraisal of Lead(II) Chelation by Octadentate Carbamoyl-Armed Macrocycles1 François Cuenot, Michel Meyer, Enrique Espinosa, and Roger Guilard pp 7895 - 7910; DOI: 10.1021/ic0508019 |
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Synthesis and Characterization of Monomeric, Oligomeric, and Polymeric Aluminum 8-Hydroxyquinolines Cheolbeom Bae, Seunghwa Lee, Sung-Yool Choi, and Gwanghoon Kwag pp 7911 - 7917; DOI: 10.1021/ic050920o |
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Moisture-Triggered 1,3,5-Triazine-Based CuII Molecular Switch: a Combined X-ray Single-Crystal and Powder Diffraction Study Hélène Casellas, Patrick Gamez, Jan Reedijk, Ilpo Mutikainen, Urho Turpeinen, Norberto Masciocchi, Simona Galli, and Angelo Sironi pp 7918 - 7924; DOI: 10.1021/ic0509231 |
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Cyclodiphosphazanes with Hemilabile Ponytails: Synthesis, Transition Metal Chemistry (Ru(II), Rh(I), Pd(II), Pt(II)), and Crystal and Molecular Structures of Mononuclear (Pd(II), Rh(I)) and Bi- and Tetranuclear Rhodium(I) Complexes P. Chandrasekaran, Joel T. Mague, and Maravanji S. Balakrishna pp 7925 - 7932; DOI: 10.1021/ic0509478 |
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Syntheses, Structures, and Reactivity of New Pentamethylcyclopentadienyl-Rhodium(III) and -iridium(III) 4-Acyl-5-Pyrazolonate Complexes Claudio Pettinari, Riccardo Pettinari, Mauro Fianchini, Fabio Marchetti, Brian W. Skelton, and Allan H. White pp 7933 - 7942; DOI: 10.1021/ic050985r |
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Eilatin Complexes of Ruthenium and Osmium. Synthesis, Electrochemical Behavior, and Near-IR Luminescence Sheba D. Bergman, Dalia Gut, Moshe Kol, Cristiana Sabatini, Andrea Barbieri, and Francesco Barigelletti pp 7943 - 7950; DOI: 10.1021/ic051022v |
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Structural Insights into the Coordination and Extraction of Pb(II) by Disulfonamide Ligands Derived from o-Phenylenediamine Robert J. Alvarado, Jay M. Rosenberg, Aileen Andreu, Jeffrey C. Bryan, Wei-Zhong Chen, Tong Ren, and Konstantinos Kavallieratos pp 7951 - 7959; DOI: 10.1021/ic051103r |
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Methyl Displacements from Cyclopentadienyl Ring Planes in Sterically Crowded (C5Me5)3M Complexes William J. Evans, Stosh A. Kozimor, and Joseph W. Ziller pp 7960 - 7969; DOI: 10.1021/ic051130h |
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Reductive and Oxidative DNA Damage by Photoactive Platinum(II) Intercalators Wei Lu, David A. Vicic, and Jacqueline K. Barton pp 7970 - 7980; DOI: 10.1021/ic051124l |
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Cubic and Spirocyclic Radicals Containing a Tetraimidophosphate Dianion [P(NR)3(NR')]2- Andrea F. Armstrong, Tristram Chivers, Heikki M. Tuononen, Masood Parvez, and René T. Boeré pp 7981 - 7991; DOI: 10.1021/ic051128q |
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Blue and Near-UV Phosphorescence from Iridium Complexes with Cyclometalated Pyrazolyl or N-Heterocyclic Carbene Ligands Tissa Sajoto, Peter I. Djurovich, Arnold Tamayo, Muhammed Yousufuddin, Robert Bau, Mark E. Thompson, Russell J. Holmes, and Stephen R. Forrest pp 7992 - 8003; DOI: 10.1021/ic051296i |
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Comparative Study of the Coordination Chemistry and Lactide Polymerization of Alkoxide and Amide Complexes of Zinc and Magnesium with a -Diiminato Ligand Bearing Ether Substituents Malcolm H. Chisholm, Judith C. Gallucci, and Khamphee Phomphrai pp 8004 - 8010; DOI: 10.1021/ic048363d |
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Syntheses, Structures, and Magnetic Properties of Unusual Nonlinear Polynuclear Copper(II) Complexes Containing Derivatives of 1,2,4-Triazole and Pivalate Ligands Jian-Hao Zhou, Ru-Mei Cheng, You Song, Yi-Zhi Li, Zhi Yu, Xue-Tai Chen, Zi-Ling Xue, and Xiao-Zeng You pp 8011 - 8022; DOI: 10.1021/ic050475x |
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Interactions of Silicate Ions with Zinc(II) and Aluminum(III) in Alkaline Aqueous Solution Michel R. Anseau, Jennifer P. Leung, Nita Sahai, and Thomas W. Swaddle pp 8023 - 8032; DOI: 10.1021/ic050594c |
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Binuclear Wirelike Dimers Based on Ruthenium(II)-Bipyridine Units Linked by Ethynylene-Oligothiophene-Ethynylene Bridges Andrea Barbieri, Barbara Ventura, Lucia Flamigni, Francesco Barigelletti, Gerda Fuhrmann, Peter Bäuerle, Sébastien Goeb, and Raymond Ziessel pp 8033 - 8043; DOI: 10.1021/ic050596x |
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BTA Copper Complexes Manfred Friedrich, Juan Carlos Gálvez-Ruiz, Thomas M. Klapötke, Peter Mayer, Birgit Weber, and Jan J. Weigand pp 8044 - 8052; DOI: 10.1021/ic050657r |
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Simple, High-Yield Methods for the Synthesis of Aldehydes Directly from o-, m-, and p-Carborane and Their Further Conversions Paola Dozzo, Ramesh A. Kasar, and Stephen B. Kahl pp 8053 - 8057; DOI: 10.1021/ic0506660 |
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Dissociation of 2,4-Bis(2,4,6-tri-tert-butylphenyl)-cyclo-1,3-dipnicta-2,4-diazanes (pnict = P, As, Sb) Imposed by Substituent Steric Strain: A Cyclobutane/Olefin Analogy Neil Burford, T. Stanley Cameron, Charles L. B. Macdonald, Katherine N. Robertson, Robert Schurko, Denise Walsh, Robert McDonald, and Roderick E. Wasylishen pp 8058 - 8064; DOI: 10.1021/ic050770h |
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Designing Molecular Bistability in Ruthenium Dimethyl Sulfoxide Complexes Aaron A. Rachford, Jeffrey L. Petersen, and Jeffrey J. Rack pp 8065 - 8075; DOI: 10.1021/ic050778r |
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Ground-State Electronic and Magnetic Properties of a 3-Oxo-Bridged Trinuclear Cu(II) Complex: Correlation to the Native Intermediate of the Multicopper Oxidases Jungjoo Yoon and Edward I. Solomon pp 8076 - 8086; DOI: 10.1021/ic0507870 |
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Cysteamine and Its Homoleptic Complexes with Group 12 Metal Ions. Differences in the Coordination Chemistry of ZnII, CdII, and HgII with a Small N,S-Donor Ligand Holger Fleischer, Yvonne Dienes, Bernd Mathiasch, Volker Schmitt, and Dieter Schollmeyer pp 8087 - 8096; DOI: 10.1021/ic050814m |
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Precise Investigation of the Axial Ligand Substitution Mechanism on a Hydrogenphosphato-Bridged Lantern-Type Platinum(III) Binuclear Complex in Acidic Aqueous Solution Satoshi Iwatsuki, Chiho Mizushima, Naoyuki Morimoto, Shinji Muranaka, Koji Ishihara, and Kazuko Matsumoto pp 8097 - 8104; DOI: 10.1021/ic050930p |
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New Fluorescence PET Systems Based on N2S2 Pyridine-Anthracene-Containing Macrocyclic Ligands. Spectrophotometric, Spectrofluorimetric, and Metal Ion Binding Studies Abel Tamayo, Carlos Lodeiro, Lluis Escriche, Jaume Casabó, Berta Covelo, and Pablo González pp 8105 - 8115; DOI: 10.1021/ic050926d |
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Synthesis and Reactivity of W3Te74+ Clusters and Chalcogen Exchange in the M3Q7 (M = Mo, W; Q = S, Se, Te) Cluster Family Maxim N. Sokolov, Pavel A. Abramov, Artem L. Gushchin, Irina V. Kalinina, Dmitry Y. Naumov, Alexander V. Virovets, Eugenia V. Peresypkina, Cristian Vicent, Rosa Llusar, and Vladimir P. Fedin pp 8116 - 8124; DOI: 10.1021/ic050962c |
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Non-heme Iron(II) Complexes Containing Tripodal Tetradentate Nitrogen Ligands and Their Application in Alkane Oxidation Catalysis George J. P. Britovsek, Jason England, and Andrew J. P. White pp 8125 - 8134; DOI: 10.1021/ic0509229 |
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Synthesis of Nickel-Monocarbollide Complexes by Oxidative Insertion Thomas D. McGrath, Andreas Franken, Jason A. Kautz, and F. Gordon A. Stone pp 8135 - 8144; DOI: 10.1021/ic051115c |
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Coordination Chemistry of a New Rigid, Hexadentate Bispidine-Based Bis(amine)tetrakis(pyridine) Ligand Christian Bleiholder, Heidi Börzel, Peter Comba, Rosana Ferrari, Matthias Heydt, Marion Kerscher, Shigemasa Kuwata, Gabor Laurenczy, Geoffrey A. Lawrance, Achim Lienke, Bodo Martin, Michael Merz, Bernd Nuber, and Hans Pritzkow pp 8145 - 8155; DOI: 10.1021/ic0513383 |
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Oxidizing Intermediates from the Sterically Hindered Iron Salen Complexes Related to the Oxygen Activation by Nonheme Iron Enzymes Takuya Kurahashi, Yoshio Kobayashi, Shigenori Nagatomo, Takehiko Tosha, Teizo Kitagawa, and Hiroshi Fujii pp 8156 - 8166; DOI: 10.1021/ic051377e |
Issue 23
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Rare-Earth Iodides in Ionic Liquids: The Crystal Structure of [SEt3]3[LnI6] (Ln = Nd, Sm) Arash Babai and Anja-Verena Mudring pp 8168 - 8169; DOI: 10.1021/ic051533h |
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Crystal Structure of Stoichiometric YBa2Fe3O8 Pavel Karen, Emmanuelle Suard, and François Fauth pp 8170 - 8172; DOI: 10.1021/ic048746b |
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Structure and Reactivity of a Pyridine-1-imido-2-thiolato Complex of Iridium(III), Cp*Ir(1-N-2-Spy), Generated by Photolysis of the (Azido)(pyridine-2-thiolato) Complex, Cp*Ir(2-Spy)(N3) Yusuke Sekioka, Sumio Kaizaki, James M. Mayer, and Takayoshi Suzuki pp 8173 - 8175; DOI: 10.1021/ic051097z |
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Self-Assembly of a Nonanuclear Nickel(II) Complex and Its Magnetic Properties Sumit Khanra, Thomas Weyhermüller, Eva Rentschler, and Phalguni Chaudhuri pp 8176 - 8178; DOI: 10.1021/ic0510821 |
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A Novel Open-Framework Copper Borophosphate: Cu(H2O)2[B2P2O8(OH)2] Hengzhen Shi, Min Li, Hejin Tangbo, Aiguo Kong, Bo Chen, and Yongkui Shan pp 8179 - 8181; DOI: 10.1021/ic0511773 |
Cationic Five-Coordinate PtII Complexes as Donors in the Formation of Pt Ag Dative BondsDaron E. Janzen, Larry F. Mehne, Donald G. VanDerveer, and Gregory J. Grant pp 8182 - 8184; DOI: 10.1021/ic0511874 |
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Oxygenation of a Ruthenium(II) Thiolate to a Ruthenium(II) Sulfinate Proceeds via Ruthenium(III) Craig A. Grapperhaus, Selma Poturovic, and Mark S. Mashuta pp 8185 - 8187; DOI: 10.1021/ic051211d |
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Group IV Complexes of a Tetradentate Amine Mono(phenolate) Ligand: a Second Side-Arm Donor Stabilizes Cationic Species Stanislav Groysman, Ekaterina Sergeeva, Israel Goldberg, and Moshe Kol pp 8188 - 8190; DOI: 10.1021/ic051400w |
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Deuterium-Induced Copper Pairing in Zr2CuD~5 Yaroslav E. Filinchuk and Klaus Yvon pp 8191 - 8193; DOI: 10.1021/ic0514039 |
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A Tetranuclear CrIIINiII3 Cyano-Bridged Complex Based on M(tacn) Derivative Building Blocks Jean-Noël Rebilly, Laure Catala, Eric Rivière, Régis Guillot, Wolfgang Wernsdorfer, and Talal Mallah pp 8194 - 8196; DOI: 10.1021/ic0514391 |
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Hexaazaphenalenyl Anion Revisited: A Highly Symmetric Planar System with Multiple-Networking Ability for Self-Assembled Metal Complexation Shuichi Suzuki, Yasushi Morita, Kozo Fukui, Kazunobu Sato, Daisuke Shiomi, Takeji Takui, and Kazuhiro Nakasuji pp 8197 - 8199; DOI: 10.1021/ic051583m |
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Metal Effect on the Supramolecular Structure, Photophysics, and Acid-Base Character of Trinuclear Pyrazolato Coinage Metal Complexes Mohammad A. Omary, Manal A. Rawashdeh-Omary, M. W. Alexander Gonser, Oussama Elbjeirami, Tom Grimes, Thomas R. Cundari, Himashinie V. K. Diyabalanage, Chammi S. Palehepitiya Gamage, and H. V. Rasika Dias pp 8200 - 8210; DOI: 10.1021/ic0508730 |
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Chiral Supramolecules: Organometallic Molecular Loops Made from Enantiopure R-[cis-Rh2(C6H4PPh2)2(CH3CN)6](BF4)2 F. Albert Cotton, Carlos A. Murillo, and Rongmin Yu pp 8211 - 8215; DOI: 10.1021/ic051149k |
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Oxomolybdenum Tetrathiolates with Sterically Encumbering Ligands: Modeling the Effect of a Protein Matrix on Electronic Structure and Reduction Potentials Rebecca L. McNaughton, Sujit Mondal, Victor N. Nemykin, Partha Basu, and Martin L. Kirk pp 8216 - 8222; DOI: 10.1021/ic0482281 |
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Chiral Organometallic Triangles with Rh-Rh Bonds. 2. Compounds Prepared from Enantiopure cis-Rh2(C6H4PPh2)2(OAc)2(HOAc)2 and Their Catalytic Potentials F. Albert Cotton, Carlos A. Murillo, Salah-E. Stiriba, Xiaoping Wang, and Rongmin Yu pp 8223 - 8233; DOI: 10.1021/ic051282c |
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Structural and Spectroscopic Features of Mono- and Binuclear Nickel(II) Complexes with Tetradentate N(amine)2S(thiolate)2 Ligation Robert T. Stibrany, Stephen Fox, Parimal K. Bharadwaj, Harvey J. Schugar, and Joseph A. Potenza pp 8234 - 8242; DOI: 10.1021/ic050114h |
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Bismuth Borates: Two New Polymorphs of BiB3O6 Linyan Li, Guobao Li, Yingxia Wang, Fuhui Liao, and Jianhua Lin pp 8243 - 8248; DOI: 10.1021/ic050190k |
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Cyclic Trimer versus Head-Tail Dimer in Metal-Nucleobase Complexes: Importance of Relative Orientation (Syn, Anti) of the Metal Entities and Relevance as a Metallaazacrown Compound Wei-Zheng Shen, Deepali Gupta, and Bernhard Lippert pp 8249 - 8258; DOI: 10.1021/ic050255j |
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Structural, Electronic, and Vibrational Characterization of Fe-HNO Porphyrinates by Density Functional Theory Douglas P. Linder and Kenton R. Rodgers pp 8259 - 8264; DOI: 10.1021/ic0504745 |
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Influence of the Reaction Temperature and pH on the Coordination Modes of the 1,4-Benzenedicarboxylate (BDC) Ligand: A Case Study of the NiII(BDC)/2,2'-Bipyridine System Yong Bok Go, Xiqu Wang, Ekaterina V. Anokhina, and Allan J. Jacobson pp 8265 - 8271; DOI: 10.1021/ic050644d |
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Novel Metal-Linked Face-to-Face Porphyrazine Dimer Chang Zhong, Min Zhao, Charlotte Stern, Anthony G. M. Barrett, and Brian M. Hoffman pp 8272 - 8276; DOI: 10.1021/ic050788s |
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Theoretical Investigation of Paramagnetic Diazabutadiene Gallium(III)-Pnictogen Complexes: Insights into the Interpretation and Simulation of Electron Paramagnetic Resonance Spectra Heikki M. Tuononen and Andrea F. Armstrong pp 8277 - 8284; DOI: 10.1021/ic050864r |
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Synthesis, Structures, and Magnetic Properties of Heteronuclear Cu(II)-Ln(III) (Ln = La, Gd, or Tb) Complexes Feng He, Ming-Liang Tong, and Xiao-Ming Chen pp 8285 - 8292; DOI: 10.1021/ic0507159 |
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Bimodal System (Luminophore and Paramagnetic Contrastophore) Derived from Ln(III) Complexes Based on a Bipyridine-Containing Macrocyclic Ligand Isabelle Nasso, Chantal Galaup, Fabien Havas, Pierre Tisnès, Claude Picard, Sophie Laurent, Luce Vander Elst, and Robert N. Muller pp 8293 - 8305; DOI: 10.1021/ic0507722 |
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High-Spin Diimine Complexes of Iron(II) Reject Binding of Carbon Monoxide: Theoretical Analysis of Thermodynamic Factors Inhibiting or Favoring Spin-Crossover Ned J. Hardman, Xinggao Fang, Brian L. Scott, Robert J. Wright, Richard L. Martin, and Gregory J. Kubas pp 8306 - 8316; DOI: 10.1021/ic050966h |
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Comparative Study of Ruthenium(II) Tris(bipyridine) Derivatives for Electrochemiluminescence Application Ming Zhou, Gilles P. Robertson, and Jacques Roovers pp 8317 - 8325; DOI: 10.1021/ic0510112 |
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Double-Stranded Metal-Organic Networks for One-Dimensional Mixed Valence Coordination Polymers Daniel Robertson, John F. Cannon, and Nikolay Gerasimchuk pp 8326 - 8342; DOI: 10.1021/ic050465w |
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Scanning Probe Microscopy Characterization of Single Chains Based on a One-Dimensional Oxalato-Bridged Manganese(II) Complex with 4-Aminotriazole Urko García-Couceiro, David Olea, Oscar Castillo, Antonio Luque, Pascual Román, Pedro J. de Pablo, Julio Gómez-Herrero, and Félix Zamora pp 8343 - 8348; DOI: 10.1021/ic0505302 |
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Sulfur K-Edge XAS and DFT Calculations on [Fe4S4]2+ Clusters: Effects of H-bonding and Structural Distortion on Covalency and Spin Topology Abhishek Dey, Cara L. Roche, Marc A. Walters, Keith O. Hodgson, Britt Hedman, and Edward I. Solomon pp 8349 - 8354; DOI: 10.1021/ic050981m |
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Europium(III) and Its Halides in Anhydrous Room-Temperature Imidazolium-Based Ionic Liquids: A Combined TRES, EXAFS, and Molecular Dynamics Study Clotilde Gaillard, Isabelle Billard, Alain Chaumont, Soufiane Mekki, Ali Ouadi, Melissa A. Denecke, Gilles Moutiers, and Georges Wipff pp 8355 - 8367; DOI: 10.1021/ic051055a |
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Primary Photoinduced Processes in Bimetallic Dyads with Extended Aromatic Bridges. Tetraazatetrapyridopentacene Complexes of Ruthenium(II) and Osmium(II) Claudio Chiorboli, Sandro Fracasso, Marcella Ravaglia, Franco Scandola, Sebastiano Campagna, Kelly L. Wouters, Rama Konduri, and Frederick M. MacDonnell pp 8368 - 8378; DOI: 10.1021/ic051062z |
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Synthesis of the Five-Coordinate Ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'4] {PCP = 2,6-(CH2PtBu2)2C6H3, BAr'4 = 3,5-(CF3)2C6H3, L = 1-ClCH2Cl, 1-N2, or -Cl-Ru(PCP)(CO)}: Reactions with Phenyldiazomethane and Phenylacetylene Jubo Zhang, Khaldoon A. Barakat, Thomas R. Cundari, T. Brent Gunnoe, Paul D. Boyle, Jeffrey L. Petersen, and Cynthia S. Day pp 8379 - 8390; DOI: 10.1021/ic051074k |
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Structural and Chiroptical Properties of the Two Coordination Isomers of YbDOTA-Type Complexes Lorenzo Di Bari, Gennaro Pescitelli, A. Dean Sherry, and Mark Woods pp 8391 - 8398; DOI: 10.1021/ic0511118 |
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Hexacyanocobaltate(III) Anions as Precursors of Co(II)-Ni(II) Cyano-Bridged Multidimensional Assemblies: Hydrothermal Syntheses, Crystal and Powder X-ray Structures, and Magnetic Properties A. Rodriguez, H. Sakiyama, N. Masciocchi, S. Galli, N. Gálvez, F. Lloret, and E. Colacio pp 8399 - 8406; DOI: 10.1021/ic0511672 |
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Revisiting the Electronic Structure of Phosphazenes Adrian B. Chaplin, John A. Harrison, and Paul J. Dyson pp 8407 - 8417; DOI: 10.1021/ic0511266 |
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Characterization and Comparison of Cm(III) and Eu(III) Complexed with 2,6-Di(5,6-dipropyl-1,2,4-triazin-3-yl)pyridine Using EXAFS, TRFLS, and Quantum-Chemical Methods Melissa A. Denecke, André Rossberg, Petra J. Panak, Michael Weigl, Bernd Schimmelpfennig, and Andreas Geist pp 8418 - 8425; DOI: 10.1021/ic0511726 |
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Computational Study of Sulfur Atom-Transfer Reactions from Thiiranes to ER3 (E = As, P; R = CH3, Ph) Abdellatif Ibdah, James H. Espenson, and William S. Jenks pp 8426 - 8432; DOI: 10.1021/ic051228w |
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Synthesis, Structure, and Magnetic Ordering of Layered (2-D) V-Based Tris(oxalato)metalates Kil Sik Min, Arnold L. Rhinegold, and Joel S. Miller pp 8433 - 8441; DOI: 10.1021/ic051373+ |
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Synthesis, Structures, and DFT Bonding Analysis of New Titanium Hydrazido(2-) Complexes Thomas B. Parsons, Nilay Hazari, Andrew R. Cowley, Jennifer C. Green, and Philip Mountford pp 8442 - 8458; DOI: 10.1021/ic051271j |
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Homoleptic Trimethylsilylacetylide Complexes of Chromium(III), Iron(II), and Cobalt(III): Syntheses, Structures, and Ligand Field Parameters Louise A. Berben and Jeffrey R. Long pp 8459 - 8468; DOI: 10.1021/ic051551z |
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Reductive Nitrosylation and Proton-Assisted Bridge Splitting of a (-Oxo)dimanganese(III) Complex Derived from a Polypyridine Ligand with One Carboxamide Group Kaushik Ghosh, Aura A. Eroy-Reveles, Marilyn M. Olmstead, and Pradip K. Mascharak pp 8469 - 8475; DOI: 10.1021/ic0503535 |
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Multiconfigurational Theoretical Study of the Octamethyldimetalates of Cr(II), Mo(II), W(II), and Re(III): Revisiting the Correlation between the M-M Bond Length and the * Transition Energy Francesco Ferrante, Laura Gagliardi, Bruce E. Bursten, and Alfred P. Sattelberger pp 8476 - 8480; DOI: 10.1021/ic050406i |
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Structurally Characterized Ternary U-O-N Compound, UN4O12: UO2(NO3)2·N2O4 or NO+UO2(NO3)3-? Margaret-Jane Crawford and Peter Mayer pp 8481 - 8485; DOI: 10.1021/ic050409v |
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Local Order in Depolymerized Silicate Lattices Graciela Pacheco-Malagón, Patricia Pérez-Romo, Norma A. Sanchez-Flores, María L. Guzmán-Castillo, Carlos López, José M. Saniger, Francisco Hernández-Beltrán, and José J. Fripiat pp 8486 - 8494; DOI: 10.1021/ic050562p |
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Factors Controlling Metal-Ion Selectivity in the Binding Sites of Calcium-Binding Proteins. The Metal-Binding Properties of Amide Donors. A Crystallographic and Thermodynamic Study Laura A. Clapp, Chynthia J. Siddons, Jason R. Whitehead, Donald G. VanDerveer, Robin D. Rogers, Scott T. Griffin, S. Bart Jones, and Robert D. Hancock pp 8495 - 8502; DOI: 10.1021/ic050632s |
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One-Dimensional BiPO4 Nanorods and Two-Dimensional BiOCl Lamellae: Fast Low-Temperature Sonochemical Synthesis,Characterization, and Growth Mechanism Jun Geng, Wen-Hua Hou, Yi-Nong Lv, Jun-Jie Zhu, and Hong-Yuan Chen pp 8503 - 8509; DOI: 10.1021/ic050674g |
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Disilver(I) Rectangular-Shaped Metallacycles: X-ray Crystal Structure and Dynamic Behavior in Solution Chun-Long Chen, Hai-Yan Tan, Jun-Hua Yao, Yi-Qian Wan, and Cheng-Yong Su pp 8510 - 8520; DOI: 10.1021/ic050673o |
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Autoxidation-Product-Initiated Dioxygenases: Vanadium-Based, Record Catalytic Lifetime Catechol Dioxygenase Catalysis Cindy-Xing Yin, Yoh Sasaki, and Richard G. Finke pp 8521 - 8530; DOI: 10.1021/ic050717t |
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Tris(thioimidazolyl)borate-Zinc-Thiolate Complexes for the Modeling of Biological Thiolate Alkylations Mohamed M. Ibrahim, Jan Seebacher, Gunther Steinfeld, and Heinrich Vahrenkamp pp 8531 - 8538; DOI: 10.1021/ic0508270 |
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Tetrakis(thiadiazole)porphyrazines. 4. Direct Template Synthesis, Structure, General Physicochemical Behavior, and Redox Properties of AlIII, GaIII, and InIII Complexes Maria Pia Donzello, Rita Agostinetto, Svetlana S. Ivanova, Masato Fujimori, Yosuke Suzuki, Hirofumi Yoshikawa, Jing Shen, Kunio Awaga, Claudio Ercolani, Karl M. Kadish, and Pavel A. Stuzhin pp 8539 - 8551; DOI: 10.1021/ic050866b |
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Synthesis of the Pivalamidate-Bridged Pentanuclear Platinum(II,III) Linear Complexes with Pt···Pt Interactions Kazuko Matsumoto, Saiko Arai, Masahiko Ochiai, Wanzhi Chen, Ayako Nakata, Hiromi Nakai, and Shuhei Kinoshita pp 8552 - 8560; DOI: 10.1021/ic050942a |
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Synthesis and Structure of a Distorted Octahedral Palladium(II) Complex Coordinated with a Tetrathioether Ligand Tethered with Bulky Substituents Nobuhiro Takeda, Daisuke Shimizu, and Norihiro Tokitoh pp 8561 - 8568; DOI: 10.1021/ic050944v |
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1,2-Dicarba-closo-dodecaboran-1-yl Naphthalene Derivatives Kiminori Ohta, Tokuhito Goto, and Yasuyuki Endo pp 8569 - 8573; DOI: 10.1021/ic0509736 |
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Spectroscopic and Thermodynamic Characterization of the E151D and E151A Altered Leucine Aminopeptidases from Aeromonas proteolytica Krzysztof P. Bzymek, Sabina I. Swierczek, Brian Bennett, and Richard C. Holz pp 8574 - 8580; DOI: 10.1021/ic051034g |
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Efficient Photoreduction Process of [Ru3(3-O)(-CH3CO2)6L3]+ by Electron-Mediation via the Viologen Dication by Excitation of a Zinc Porphyrin Midoriko Otake, Mitsunari Itou, Yasuyuki Araki, Osamu Ito, and Hiroaki Kido pp 8581 - 8586; DOI: 10.1021/ic050960s |
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Heme Axial Methionine Fluxion in Pseudomonas aeruginosa Asn64Gln Cytochrome c551 Xin Wen and Kara L. Bren pp 8587 - 8593; DOI: 10.1021/ic050976i |
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Oxidative Addition of Methyl Iodide to a New Type of Binuclear Platinum(II) Complex: a Kinetic Study Sirous Jamali, S. Masoud Nabavizadeh, and Mehdi Rashidi pp 8594 - 8601; DOI: 10.1021/ic0511064 |
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Wurster's Thiacrown Ethers: Synthesis, Properties, and Pt(II)-Coordination Chemistry John W. Sibert, Philip B. Forshee, and Vincent Lynch pp 8602 - 8609; DOI: 10.1021/ic051125d |
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Formation and Characterization of Thorium Methylidene CH2=ThHX Complexes Jonathan T. Lyon and Lester Andrews pp 8610 - 8616; DOI: 10.1021/ic051153w |
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Synthesis, Structural Characterization, and Computational Studies of Novel Diiodine Adducts with the Heterocyclic Thioamides N-Methylbenzothiazole-2-thione and Benzimidazole-2-thione: Implications with the Mechanism of Action of Antithyroid Drugs Ghada J. Corban, Sotiris K. Hadjikakou, Nick Hadjiliadis, Maciej Kubicki, Edward R. T. Tiekink, Ian S. Butler, Evangelos Drougas, and Agnie M. Kosmas pp 8617 - 8627; DOI: 10.1021/ic0484396 |
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Biferrocene-M(mnt)2 Charge-Transfer Complexes (M = Ni, Co; mnt = Maleonitriledithiolate). Structure, Valence States, and Magnetic Properties Tomoyuki Mochida, Kousuke Takazawa, Hideaki Matsui, Masashi Takahashi, Masuo Takeda, Michiko Sato, Yutaka Nishio, Koji Kajita, and Hatsumi Mori pp 8628 - 8641; DOI: 10.1021/ic048285u |
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Forum on Solar and Renewable Energy pp 8642 - 8642; DOI: 10.1021/ic058009v |
Issue 24
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Stabilization of Unsolvated Europium and Ytterbium Pentafluorophenyls by -Bonding Encapsulation through a Sterically Crowded Triazenido Ligand Sven-Oliver Hauber and Mark Niemeyer pp 8644 - 8646; DOI: 10.1021/ic0514602 |
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Cleavage of X-H Bonds (X = N, O, or C) by Copper(I) Alkyl Complexes To Form Monomeric Two-Coordinate Copper(I) Systems Laurel A. Goj, Elizabeth D. Blue, Colleen Munro-Leighton, T. Brent Gunnoe, and Jeffrey L. Petersen pp 8647 - 8649; DOI: 10.1021/ic0517624 |
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[(Triphos)Ni(2-BH4)]: An Unusual Nickel(I) Borohydride Complex Mathivathani Kandiah, G. Sean McGrady, Andreas Decken, and Peter Sirsch pp 8650 - 8652; DOI: 10.1021/ic051541y |
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Synthesis and Properties of Ph2S(=N-(Ph2)SN)2 Takayoshi Fujii, Mihoko Kanno, Mitsuo Hirata, Teruyoshi Fujimori, and Toshiaki Yoshimura pp 8653 - 8655; DOI: 10.1021/ic051523g |
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Diiron(II) -Aqua--hydroxo Model for Non-Heme Iron Sites in Proteins Ivan V. Korendovych, Sergey V. Kryatov, William M. Reiff, and Elena V. Rybak-Akimova pp 8656 - 8658; DOI: 10.1021/ic051739i |
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Single-Molecule Magnets: A Reductive Aggregation Route to New Types of Mn12 Complexes Philippa King, Wolfgang Wernsdorfer, Khalil A. Abboud, and George Christou pp 8659 - 8669; DOI: 10.1021/ic051150j |
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Intermetallic Compounds with Near Zintl Phase Behavior: RE2Zn3Ge6 (RE = La, Ce, Pr, Nd) Grown from Liquid Indium James R. Salvador, Daniel Bilc, Jeffrey R. Gour, Subhendra D. Mahanti, and Mercouri G. Kanatzidis pp 8670 - 8679; DOI: 10.1021/ic050941i |
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Structure, Bonding, and Reactivity of Ti and Zr Amidate Complexes: DFT and X-Ray Crystallographic Studies Robert K. Thomson, Federico E. Zahariev, Zhe Zhang, Brian O. Patrick, Yan Alexander Wang, and Laurel L. Schafer pp 8680 - 8689; DOI: 10.1021/ic0502980 |
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Metal-Enhanced H-Bond Donor Tendencies of Urea and Thiourea toward Anions: Ditopic Receptors for Silver(I) Salts Valeria Amendola, David Esteban-Gómez, Luigi Fabbrizzi, Maurizio Licchelli, Enrico Monzani, and Félix Sancenón pp 8690 - 8698; DOI: 10.1021/ic050871f |
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The Challenge of Being Straight: Explaining the Linearity of a Low-Spin {FeNO}7 Unit in a Tropocoronand Complex Espen Tangen, Jeanet Conradie, and Abhik Ghosh pp 8699 - 8706; DOI: 10.1021/ic050781a |
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C- and Z-Shaped Coordination Compounds. Synthesis, Structure, and Spectroelectrochemistry of cis- and trans-[Re(CO)3(L)]2-2,2'-bisbenzimidizolate with L = 4-Phenylpyridine, 2,4'-Bipyridine, or Pyridine Peter H. Dinolfo, Kurt D. Benkstein, Charlotte L. Stern, and Joseph T. Hupp pp 8707 - 8714; DOI: 10.1021/ic050894u |
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A New Coordination Mode of the Photometric Reagent Glyoxalbis(2-hydroxyanil) (H2gbha): Bis-Bidentate Bridging by gbha2- in the Redox Series {(-gbha)[Ru(acac)2]2}n (n = -2, -1, 0, +1, +2), Including a Radical-Bridged Diruthenium(III) and a RuIII/RuIV Intermediate Sanjib Kar, Biprajit Sarkar, Sandeep Ghumaan, Dipankar Roy, Francisco A. Urbanos, Jan Fiedler, Raghavan B. Sunoj, Reyes Jimenez-Aparicio, Wolfgang Kaim, and Goutam Kumar Lahiri pp 8715 - 8722; DOI: 10.1021/ic050950r |
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Cationic Bis-cyclometalated Iridium(III) Diimine Complexes and Their Use in Efficient Blue, Green, and Red Electroluminescent Devices Arnold B. Tamayo, Simona Garon, Tissa Sajoto, Peter I. Djurovich, Irina M. Tsyba, Robert Bau, and Mark E. Thompson pp 8723 - 8732; DOI: 10.1021/ic050970t |
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[1,10]-Phenanthrolin-2-yl Ketones and Their Coordination Chemistry Thomas Bark and Randolph P. Thummel pp 8733 - 8739; DOI: 10.1021/ic050996k |
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Electroactive Ligands: The First Metal Complexes of Tetrathiafulvenyl-Acetylacetonate Julien Massue, Nathalie Bellec, Stéphanie Chopin, Eric Levillain, Thierry Roisnel, Rodolphe Clérac, and Dominique Lorcy pp 8740 - 8748; DOI: 10.1021/ic051017r |
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Architectural Isomerism in the Three-Dimensional Polymeric Spin Crossover System {Fe(pmd)2[Ag(CN)2]2}: Synthesis, Structure, Magnetic Properties, and Calorimetric Studies Ana Galet, M. Carmen Muñoz, Ana B. Gaspar, and José A. Real pp 8749 - 8755; DOI: 10.1021/ic0509074 |
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Synthesis and Structure of Ta4S9Br8. An Emergent Family of Early Transition Metal Chalcogenide Clusters Maxim N. Sokolov, Artem L. Gushchin, Pavel A. Abramov, Alexandr V. Virovets, Eugenia V. Peresypkina, Svetlana G. Kozlova, Boris A. Kolesov, Cristian Vicent, and Vladimir P. Fedin pp 8756 - 8761; DOI: 10.1021/ic051014e |
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Non-Interpenetrated Square-Grid Coordination Polymers Synthesized Using an Extremely Long N,N'-Type Ligand Chun-Long Chen, Andrea M. Goforth, Mark D. Smith, Cheng-Yong Su, and Hans-Conrad zur Loye pp 8762 - 8769; DOI: 10.1021/ic051068o |
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Syntheses; 77Se, 203Tl, and 205Tl NMR; and Theoretical Studies of the Tl2Se66-, Tl3Se65-, and Tl3Se75- Anions and the X-ray Crystal Structures of [2,2,2-crypt-Na]4[Tl4Se8]·en and [2,2,2-crypt-Na]2[Tl2Se4]1·en Ayaaz M. Pirani, Hélène P. A. Mercier, Reijo J. Suontamo, Gary J. Schrobilgen, David P. Santry, and Horst Borrmann pp 8770 - 8785; DOI: 10.1021/ic0510922 |
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Sn19.3Cu4.7As22I8: a New Clathrate-I Compound with Transition-Metal Atoms in the Cationic Framework Kirill A. Kovnir, Alexei V. Sobolev, Igor A. Presniakov, Oleg I. Lebedev, Gustaaf Van Tendeloo, Walter Schnelle, Yuri Grin, and Andrei V. Shevelkov pp 8786 - 8793; DOI: 10.1021/ic051160k |
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Cadmium(II), Nickel(II), and Zinc(II) Complexes of Vacataporphyrin: A Variable Annulene Conformation inside a Standard Porphyrin Frame Ewa Pacholska-Dudziak, Janusz Skonieczny, Mi osz Pawlicki, Ludmia Szterenberg, and Lechosaw Latos-Grayskipp 8794 - 8803; DOI: 10.1021/ic0511470 |
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Synthesis and Electronic Characterization of Bipyridine Dithiolate Rhodium(III) Complexes Daniel Amarante, Cheryl Cherian, Anthony Catapano, Rebekah Adams, Man Hoi Wang, and Elise G. Megehee pp 8804 - 8809; DOI: 10.1021/ic051171d |
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Correlation of Spin States and Spin Delocalization with the Dioxygen Reactivity of Catecholatoiron(III) Complexes Masakazu Higuchi, Yutaka Hitomi, Hisataka Minami, Tsunehiro Tanaka, and Takuzo Funabiki pp 8810 - 8821; DOI: 10.1021/ic051173y |
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From Low-Dimensional Manganese(II) Azido Motifs to Higher-Dimensional Materials: Structure and Magnetic Properties En-Qing Gao, Ai-Ling Cheng, Yan-Xia Xu, Ming-Yuan He, and Chun-Hua Yan pp 8822 - 8835; DOI: 10.1021/ic0512328 |
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Pillared-Layer Microporous Metal-Organic Frameworks Constructed by Robust Hydrogen Bonds. Synthesis, Characterization, and Magnetic and Adsorption Properties of 2,2'-Biimidazole and Carboxylate Complexes Bing-Bing Ding, Yan-Qin Weng, Zong-Wan Mao, Chi-Keung Lam, Xiao-Ming Chen, and Bao-Hui Ye pp 8836 - 8845; DOI: 10.1021/ic051195k |
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Polyoxometalate-Supported Transition Metal Complexes and Their Charge Complementarity: Synthesis and Characterization of [M(OH)6Mo6O18{Cu(Phen)(H2O)2}2][M(OH)6Mo6O18{Cu(Phen)(H2O) Cl}2]·5H2O (M = Al3+, Cr3+) Vaddypally Shivaiah and Samar K. Das pp 8846 - 8854; DOI: 10.1021/ic050830j |
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Semiconductive Coordination Networks from Bismuth(III) Bromide and 1,2-Bis(methylthio)phenylacetylene-Based Ligands Kunhao Li, Hanhui Xu, Zhengtao Xu, Matthias Zeller, and Allen D. Hunter pp 8855 - 8860; DOI: 10.1021/ic0512734 |
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Solvothermal Syntheses of [Ln(en)3(H2O)x(3-x-SbS4)] (Ln = La, x = 0; Ln = Nd, x = 1) and [Ln(en)4]SbS4·0.5en (Ln = Eu, Dy, Yb): A Systematic Study on the Formation and Crystal Structures of New Lanthanide Thioantimonates(V) Dingxian Jia, Qianxin Zhao, Yong Zhang, Jie Dai, and Jinglin Zuo pp 8861 - 8867; DOI: 10.1021/ic051402g |
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Structural Constraints in the Design of Silver Sulfonate Coordination Networks: Three New Polysulfonate Open Frameworks Dennis J. Hoffart, Sean A. Dalrymple, and George K. H. Shimizu pp 8868 - 8875; DOI: 10.1021/ic0513888 |
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Steric Protection of a Photosensitizer in a N,N-Bis[2-(2-pyridyl)ethyl]-2-phenylethylamine-copper(II) Bowl that Enhances Red Light-Induced DNA Cleavage Activity Shanta Dhar, Munirathinam Nethaji, and Akhil R. Chakravarty pp 8876 - 8883; DOI: 10.1021/ic0505246 |
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Barriers to Racemization in C3-Symmetric Complexes Containing the Hydrotris(2-mercapto-1-ethylimidazolyl)borate (TmEt) Ligand Philip J. Bailey, Alice Dawson, Chiara McCormack, Stephen A. Moggach, Iain D. H. Oswald, Simon Parsons, David W. H. Rankin, and Andrew Turner pp 8884 - 8898; DOI: 10.1021/ic0505293 |
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Thioether Complexes of Palladium(II) and Platinum(II) as Artificial Peptidases. Residue-Selective Peptide Cleavage by a Palladium(II) Complex Stacey A. Stoffregen, Amanda K. K. Griffin, and Nenad M. Kosti pp 8899 - 8907; DOI: 10.1021/ic0506613 |
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Isomers of cyclo-Heptasulfur and Their Coordination to Li+: an Ab Initio Molecular Orbital Study Ming Wah Wong, Yana Steudel, and Ralf Steudel pp 8908 - 8915; DOI: 10.1021/ic050332a |
Complexation to FeII, NiII, and ZnII of Multidentate Ligands Resulting from Condensation of 2-Pyridinecarboxaldehyde with , -Triamines: Selective Imidazolidine/Hexahydropyrimidine Ring Opening RevisitedNicolas Bréfuel, Christine Lepetit, Sergiu Shova, Françoise Dahan, and Jean-Pierre Tuchagues pp 8916 - 8928; DOI: 10.1021/ic050791b |
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Tuning the Triplet Energy Levels of Pyrazolone Ligands to Match the 5D0 Level of Europium(III) Mei Shi, Fuyou Li, Tao Yi, Dengqing Zhang, Huaiming Hu, and Chunhui Huang pp 8929 - 8936; DOI: 10.1021/ic050844p |
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A Family of Oxo-Chalcogenide Molybdenum and Tungsten Complexes, (n-Bu4N)2[M2O2(-Q)2(1,3-dithiole-2-thione-4,5-dithiolate)2] (M = Mo, W; Q = S, Se): New Synthetic Entries, Structure, and Gas-Phase Behavior Rosa Llusar, Sonia Triguero, Cristian Vicent, Maxim N. Sokolov, Benoît Domercq, and Marc Fourmigué pp 8937 - 8946; DOI: 10.1021/ic0508728 |
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Tautomerization of Methyldiazene to Formaldehyde-Hydrazone in Ruthenium and Osmium Complexes Gabriele Albertin, Stefano Antoniutti, Alessia Bacchi, Fabiola De Marchi, and Giancarlo Pelizzi pp 8947 - 8954; DOI: 10.1021/ic050817z |
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Electron Exchange between -Keggin Tungstoaluminates and a Well-Defined Cluster-Anion Probe for Studies in Electron Transfer Yurii V. Geletii, Craig L. Hill, Alan J. Bailey, Kenneth I. Hardcastle, Rajai H. Atalla, and Ira A. Weinstock pp 8955 - 8966; DOI: 10.1021/ic050860m |
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Terpyridine Zn(II), Ru(III), and Ir(III) Complexes: The Relevant Role of the Nature of the Metal Ion and of the Ancillary Ligands on the Second-Order Nonlinear Response of Terpyridines Carrying Electron Donor or Electron Acceptor Groups Francesca Tessore, Dominique Roberto, Renato Ugo, Maddalena Pizzotti, Silvio Quici, Marco Cavazzini, Silvia Bruni, and Filippo De Angelis pp 8967 - 8978; DOI: 10.1021/ic050975q |
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Gadolinium and Neodymium Citrates: Evidence for Weak Ferromagnetic Exchange between Gadolinium(III) Cations Ricardo Baggio, Rafael Calvo, María Teresa Garland, Octavio Peña, Mireille Perec, and Alberto Rizzi pp 8979 - 8987; DOI: 10.1021/ic0510056 |
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Examination of the Bonding in Binary Transition-Metal Monophosphides MP (M = Cr, Mn, Fe, Co) by X-Ray Photoelectron Spectroscopy Andrew P. Grosvenor, Stephen D. Wik, Ronald G. Cavell, and Arthur Mar pp 8988 - 8998; DOI: 10.1021/ic051004d |
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Redox Properties of Wild-Type and Heme-Binding Loop Mutants of Bacterial Cytochromes c Measured by Direct Electrochemistry Tao Ye, Ravinder Kaur, Xin Wen, Kara L. Bren, and Sean J. Elliott pp 8999 - 9006; DOI: 10.1021/ic051003l |
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Synthesis and Molecular Structures of Mononitrosyl (N2S2)M(NO) Complexes (M = Fe, Co) Chao-Yi Chiang, Jonghyuk Lee, Christopher Dalrymple, Michael C. Sarahan, Joseph H. Reibenspies, and Marcetta Y. Darensbourg pp 9007 - 9016; DOI: 10.1021/ic051027s |
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Ion Pairing in Ti(IV) Trisamidotriazacyclononane Compounds Ana M. Martins, José R. Ascenso, Sílvia M. B. Costa, Alberto R. Dias, Humberto Ferreira, and José A. B. Ferreira pp 9017 - 9022; DOI: 10.1021/ic0510258 |
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Electrochemistry and Spectroelectrochemistry of Heterobimetallic Porphyrin-Corrole Dyads. Influence of the Spacer, Metal Ion, and Oxidation State on the Pyridine Binding Ability Karl M. Kadish, Jianguo Shao, Zhongping Ou, Riqiang Zhan, Fabien Burdet, Jean-Michel Barbe, Claude P. Gros, and Roger Guilard pp 9023 - 9038; DOI: 10.1021/ic051073s |
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One-Dimensional Azido-Bridged Chiral Metal Complexes with Ferromagnetic or Antiferromagnetic Interactions: Syntheses, Structures, and Magnetic Studies He-Rui Wen, Cai-Feng Wang, You Song, Jing-Lin Zuo, and Xiao-Zeng You pp 9039 - 9045; DOI: 10.1021/ic051108o |
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Lanthanide Borohydride Complexes Supported by Diaminobis(phenoxide) Ligands for the Polymerization of -Caprolactone and L- and rac-Lactide Fanny Bonnet, Andrew R. Cowley, and Philip Mountford pp 9046 - 9055; DOI: 10.1021/ic051316g |
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UV-Vis, NMR, and Time-Resolved Spectroscopy Analysis of Photoisomerization Behavior of Three- and Six-Azobenzene-Bound Tris(bipyridine)cobalt Complexes Kyoko Yamaguchi, Shoko Kume, Kosuke Namiki, Masaki Murata, Naoto Tamai, and Hiroshi Nishihara pp 9056 - 9067; DOI: 10.1021/ic0513538 |
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Reactivity of Bis(-hydroxo) Divanadium Site in -H2SiV2W10O404- with Hydroxo Compounds Yoshinao Nakagawa, Kazuhiro Uehara, and Noritaka Mizuno pp 9068 - 9075; DOI: 10.1021/ic051163x |
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Infrared Spectra and Structures of the Coinage Metal Dihydroxide Molecules Xuefeng Wang and Lester Andrews pp 9076 - 9083; DOI: 10.1021/ic051201c |
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Novel Hydridoirida--diketones Containing Small Molecules, CO, or Ethylene: Their Behavior in Coordinating Solvents Such as Dimethylsulfoxide or Acetonitrile Francisco Acha, María A. Garralda, Lourdes Ibarlucea, Elena Pinilla, and M. Rosario Torres pp 9084 - 9091; DOI: 10.1021/ic051219n |
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Vertex-Linked ZnO2S2 Tetrahedra in the Oxysulfide BaZnOS: a New Coordination Environment for Zinc in a Condensed Solid Sarah Broadley, Zoltán A. Gál, Furio Corà, Catherine F. Smura, and Simon J. Clarke pp 9092 - 9096; DOI: 10.1021/ic051240o |
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Multinuclear and Dynamic NMR Study of trans-[Pt(Cl)(PHCy2)2(PCy2)], [Pt(Cl)(PHCy2)3][BF4], [Pt(Cl)(PHCy2)3][Cl], trans-[Pt(Cl)(PHCy2)2{P(S)Cy2}], and trans-[Pt(Cl)(PHCy2)2{P(O)Cy2}]. Influence of Intramolecular P=O···H-P and Cl···H-P Interactions on Restricted Rotation about Pt-P Bond. X-ray Structure of trans-[Pt(Cl)(PHCy2)2{P(O)Cy2}] Piero Mastrorilli, Cosimo F. Nobile, Mario Latronico, Vito Gallo, Ulli Englert, Francesco P. Fanizzi, and Oronzo Sciacovelli pp 9097 - 9104; DOI: 10.1021/ic051198x |
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Physical Parameters and Electron-Transfer Kinetics of the Copper(II/I) Complex with the Macrocyclic Sexadentate Ligand [18]aneS6 Gezahegn Chaka, L. A. Ochrymowycz, and D. B. Rorabacher pp 9105 - 9111; DOI: 10.1021/ic0515608 |
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Tetranuclear Manganese(II) Complexes of Thiacalixarene Macrocycles with Trigonal Prismatic Six-Coordinate Geometries: Synthesis, Structure, and Magnetic Properties Cédric Desroches, Guillaume Pilet, Serguei A. Borshch, Stéphane Parola, and Dominique Luneau pp 9112 - 9120; DOI: 10.1021/ic050507g |
Issue 25
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Unprecedented Hybrid Scorpionate/Phosphine Ligand Able To Be Anchored to Carbosilane Dendrimers Miguel A. Casado, Verena Hack, José A. Camerano, Miguel A. Ciriano, Cristina Tejel, and Luis A. Oro pp 9122 - 9124; DOI: 10.1021/ic051279t |
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Novel Excited Quintet State in Porphyrin: Bis(quinoline)-TEMPO-yttrium-tetraphenylporphine Complex Luca Maretti, Saiful S. M. Islam, Yasunori Ohba, Takashi Kajiwara, and Seigo Yamauchi pp 9125 - 9127; DOI: 10.1021/ic0511827 |
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New Skeletal 3D Polymeric Inorganic Cluster [W4S16Cu16Cl16]n with Cu in Mixed-Valence States: Solid-State Synthesis, Crystal Structure, and Third-Order Nonlinear Optical Properties Ya Cai, Yan Wang, Yizhi Li, Xiaoshu Wang, Xinquan Xin, Caiming Liu, and Hegen Zheng pp 9128 - 9130; DOI: 10.1021/ic051230n |
Structural Characterization of a Methylaluminoxane (MAO)-Magnesium Dichloride Cluster: Model of MAO Grafted onto a MgCl2 Support ukasz John, Józef Utko, Lucjan B. Jerzykiewicz, and Piotr Sobotapp 9131 - 9133; DOI: 10.1021/ic051441s |
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Redox-Switchable Molecular Containers Consisting of Dicobalt Complexes H. Shimakoshi, T. Takemoto, I. Aritome, and Y. Hisaeda pp 9134 - 9136; DOI: 10.1021/ic051482o |
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Synthesis and Structural Characterization of a Uranyl(VI) Complex Possessing Unsupported Unidentate Thiolate Ligands Shanmugaperumal Kannan, Charles L. Barnes, and Paul B. Duval pp 9137 - 9139; DOI: 10.1021/ic0517117 |
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Nitrogen-Atom Exchange Mediated by Nitrido Complexes of Molybdenum Robyn L. Gdula, Marc J. A. Johnson, and Nathan W. Ockwig pp 9140 - 9142; DOI: 10.1021/ic051859q |
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Crystal Structures and Magnetic Properties of Mixed Iridium-Ruthenium Triple Perovskites. 1. Ba3MRuIrO9 (M = Lanthanide, Y) Michael W. Lufaso and Hans-Conrad zur Loye pp 9143 - 9153; DOI: 10.1021/ic051344z |
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Crystal Structures and Magnetic Properties of Mixed Iridium-Ruthenium Triple Perovskites. 2. Ba3MRuIrO9 (M = Li, Na, Mg, Ni, Zn, Bi, In) Michael W. Lufaso and Hans-Conrad zur Loye pp 9154 - 9161; DOI: 10.1021/ic051345r |
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Synthesis and Properties of Cobalt(III) Complexes of 4-Substituted Pyridine-Capped Dioxocyclams Angela L. Reiff, Eva M. Garcia-Frutos, Jun Mo Gil, Oren P. Anderson, and Louis S. Hegedus pp 9162 - 9174; DOI: 10.1021/ic050200h |
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Dynamic Formation of Coordination Polymers versus Tetragonal Prisms and Unexpected Magnetic Superexchange Coupling Mediated by Encapsulated Anions in the Cobalt(II) 1,3-Bis(pyrid-4-ylthio)propan-2-one Series Benlai Wu, Daqiang Yuan, Benyong Lou, Lei Han, Caiping Liu, Chunxi Zhang, and Maochun Hong pp 9175 - 9184; DOI: 10.1021/ic050455v |
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Crystal Structures, Raman Spectroscopy, and Magnetic Properties of Ba7.5Al13Si29 and Eu0.27Ba7.22Al13Si29 Cathie L. Condron, Rhiannon Porter, Ting Guo, and Susan M. Kauzlarich pp 9185 - 9191; DOI: 10.1021/ic050483d |
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New Synthetic Approach to Yttrium Hydroxoacetates, Structural Characterization, and Use as a Precursor for Coated Conductors Peter Lobinger, Harald Jarzina, Herbert W. Roesky, Sanjay Singh, S. Shravan Kumar, Hans-Georg Schmidt, Matthias Noltemeyer, and Herbert C. Freyhardt pp 9192 - 9196; DOI: 10.1021/ic0505192 |
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Copper(I) and -(II) Complexes of Neutral and Deprotonated N-(2,6-Diisopropylphenyl)-3-[bis(2-pyridylmethyl)amino]propanamide Timothy E. Patten, Christina Troeltzsch, and Marilyn M. Olmstead pp 9197 - 9206; DOI: 10.1021/ic0505697 |
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Synthesis and Structural Characterization of a New Heterobimetallic Coordination Complex of Barium and Cobalt for Use as a Precursor for Chemical Vapor Deposition Asif A. Tahir, Kieran C. Molloy, Muhammad Mazhar, Gabriele Kociok-Köhn, Mazhar Hamid, and Sarim Dastgir pp 9207 - 9212; DOI: 10.1021/ic050564+ |
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Syntheses, X-ray Structures, Photochemistry, Redox Properties, and DFT Calculations of Interconvertible fac- and mer-[Mn(SPS)(CO)3] Isomers Containing a Flexible SPS-Based Pincer Ligand Marjolaine Doux, Nicolas Mézailles, Louis Ricard, Pascal Le Floch, Pedro D. Vaz, Maria José Calhorda, Taasje Mahabiersing, and Franti ek Hartlpp 9213 - 9224; DOI: 10.1021/ic050774m |
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Transformation from a 2D Stacked Layer to 3D Interpenetrated Framework by Changing the Spacer Functionality: Synthesis, Structure, Adsorption, and Magnetic Properties Tapas Kumar Maji, Masaaki Ohba, and Susumu Kitagawa pp 9225 - 9231; DOI: 10.1021/ic050835g |
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Synthesis and Photophysical Properties of Meso-Substituted Bisporphyrins: Comparative Study of Phosphorescence Quenching for Dioxygen Sensing Sébastien Faure, Christine Stern, Roger Guilard, and Pierre D. Harvey pp 9232 - 9241; DOI: 10.1021/ic0508573 |
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Ca6Cu2Sn7: Novel 3D Open Framework with Unusual Sn4 Tetramers Zhong-Ming Sun, Sheng-Qing Xia, Yi-Zhi Huang, Li-Ming Wu, and Jiang-Gao Mao pp 9242 - 9246; DOI: 10.1021/ic051164p |
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Synthesis and Characterization of Two Isomeric, Self-Assembled Arsenic-Thiolate Macrocycles W. Jake Vickaryous, Elisabeth Rather Healey, Orion B. Berryman, and Darren W. Johnson pp 9247 - 9252; DOI: 10.1021/ic050954w |
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Stereochemical Influence of the Ligand on the Structure of Manganese Complexes: Implications for Catalytic Epoxidations Meenal D. Godbole, Anna C. G. Hotze, Ronald Hage, Allison M. Mills, Huub Kooijman, Anthony L. Spek, and Elisabeth Bouwman pp 9253 - 9266; DOI: 10.1021/ic051223z |
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Neutron Powder Diffraction Study of Pb(HfxTi1-x)O3 Ceramics (0.10 x 0.50) J. Frantti, Y. Fujioka, S. Eriksson, S. Hull, and M. Kakihana pp 9267 - 9278; DOI: 10.1021/ic051169m |
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Synthesis, Structure, and Luminescent Property of a Heterometallic Metal-Organic Framework Constructed from Rod-Shaped Secondary Building Blocks Jianghua He, Jihong Yu, Yuetao Zhang, Qinhe Pan, and Ruren Xu pp 9279 - 9282; DOI: 10.1021/ic051143v |
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Nitrosyl Isocyanate (ONNCO): Gas-Phase Generation and a HeI Photoelectron Spectroscopy Study Xiaoqing Zeng, Maofa Ge, Zheng Sun, and Dianxun Wang pp 9283 - 9287; DOI: 10.1021/ic051349w |
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NH/ Interaction in a Spin-Crossover Complex [FeII(HLMe)2](BPh4)2·2CH3CN (BPh4- = Tetraphenylborate; HLMe = 2-Methylimidazol-4-yl-methylideneamino-2-ethylpyridine) Shinobu Arata, Haruna Torigoe, Tomotaka Iihoshi, Naohide Matsumoto, Françoise Dahan, and Jean-Pierre Tuchagues pp 9288 - 9292; DOI: 10.1021/ic051215i |
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Kinetics and Mechanism of Acid-Catalyzed Oxidation of Bromide Ions by the Aqueous Chromyl(IV) Ion Meiling Hung and Andreja Bakac pp 9293 - 9298; DOI: 10.1021/ic051310r |
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First Experimental Evidence of Potassium Ordering in Layered K4Co7O14 Maxime Blangero, Rodolphe Decourt, Dany Carlier, Gerbrand Ceder, Michael Pollet, Jean-Pierre Doumerc, Jacques Darriet, and Claude Delmas pp 9299 - 9304; DOI: 10.1021/ic0514804 |
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Remote and Adjacent Excited-State Electron Transfer at TiO2 Interfaces Sensitized to Visible Light with Ru(II) Compounds Feng Liu and Gerald J. Meyer pp 9305 - 9313; DOI: 10.1021/ic0513336 |
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Luminescent Lanthanide Selenites and Tellurites Decorated by MoO4 Tetrahedra or MoO6 Octahedra: Nd2MoSe2O10, Gd2MoSe3O12, La2MoTe3O12, and Nd2MoTe3O12 Yue-Ling Shen, Hai-Long Jiang, Jian Xu, Jiang-Gao Mao, and Kok Wai Cheah pp 9314 - 9321; DOI: 10.1021/ic051376m |
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Computational Studies of the H-Cluster of Fe-Only Hydrogenases: Geometric, Electronic, and Magnetic Properties and Their Dependence on the [Fe4S4] Cubane Adam T. Fiedler and Thomas C. Brunold pp 9322 - 9334; DOI: 10.1021/ic050946f |
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Synthesis, Crystal Structure, and Solid-State NMR Spectroscopy of a Salt-Inclusion Stannosilicate: [Na3F][SnSi3O9] Chen-Hui Liao, Pai-Ching Chang, Hsien-Ming Kao, and Kwang-Hwa Lii pp 9335 - 9339; DOI: 10.1021/ic0514086 |
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Inorganic Supramolecular Host Architectures: [(M@18c6)2][TlI4]·2H2O, M = 0.5 Tl, (NH4,NH3), (H3O,H2O) Franziska Rieger and Anja-V. Mudring pp 9340 - 9346; DOI: 10.1021/ic051430z |
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New Metal-Organic Polygons Involving MM Quadruple Bonds: M8(O2CtBu)4(-SC4H2-3,4-{CO2}2)6 (M = Mo, W) Matthew J. Byrnes, Malcolm H. Chisholm, and Nathan J. Patmore pp 9347 - 9352; DOI: 10.1021/ic051516s |
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New Metal Iodates: Syntheses, Structures, and Characterizations of Noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric -Cs2I4O11 and Rb2I6O15(OH)2·H2O Kang Min Ok and P. Shiv Halasyamani pp 9353 - 9359; DOI: 10.1021/ic051340u |
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Cobalt-Containing Silicotungstate Sandwich Dimer [{Co3(B--SiW9O33(OH))(B--SiW8O29(OH)2)}2]22- Bassem S. Bassil, Ulrich Kortz, Anca S. Tigan, Juan M. Clemente-Juan, Bineta Keita, Pedro de Oliveira, and Louis Nadjo pp 9360 - 9368; DOI: 10.1021/ic0515554 |
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Syntheses and Structural Characterization of New Mixed-Valent Tellurium Oxides, A4[Te56+Te34+]O23 (A = Rb and K) M. P. Minimol and K. Vidyasagar pp 9369 - 9373; DOI: 10.1021/ic0515599 |
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Influence of Neutral Ligands on the Structures of Silver(I) Sulfonates Fang-Fang Li, Jian-Fang Ma, Shu-Yan Song, Jin Yang, Ying-Ying Liu, and Zhong-Min Su pp 9374 - 9383; DOI: 10.1021/ic050984z |
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Trans Influence of Boryl Ligands and Comparison with C, Si, and Sn Ligands Jun Zhu, Zhenyang Lin, and Todd B. Marder pp 9384 - 9390; DOI: 10.1021/ic0513641 |
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Preparation and O2 Binding Study of Myoglobin Having a Cobalt Porphycene Takashi Matsuo, Takashi Tsuruta, Keiko Maehara, Hideaki Sato, Yoshio Hisaeda, and Takashi Hayashi pp 9391 - 9396; DOI: 10.1021/ic0513639 |
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Uridine Binding by Zn(II) Macrocyclic Complexes: Diversion of RNA Cleavage Catalysts Clifford S. Rossiter, Ryan A. Mathews, and Janet R. Morrow pp 9397 - 9404; DOI: 10.1021/ic050892+ |
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Chromate Nanorods/Nanobelts: General Synthesis, Characterization, and Properties Jiahe Liang, Qing Peng, Xun Wang, Xi Zheng, Ruji Wang, Xinping Qiu, Cewen Nan, and Yadong Li pp 9405 - 9415; DOI: 10.1021/ic048237+ |
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Inorganic-Organic Hybrids of the p,p'-Diphenylmethylenediphosphinate, pcp2-. Synthesis, Characterization, and XRPD Structures of [Sn(pcp)] and [Cu(pcp)] Jens Beckmann, Ferdinando Costantino, Dainis Dakternieks, Andrew Duthie, Andrea Ienco, Stefano Midollini, Cassandra Mitchell, Annabella Orlandini, and Lorenzo Sorace pp 9416 - 9423; DOI: 10.1021/ic050683p |
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Comparison of Protective Effects against Reactive Oxygen Species of Mononuclear and Dinuclear Cu(II) Complexes with N-Substituted Benzothiazolesulfonamides Marta González-Álvarez, Gloria Alzuet, Joaquín Borrás, Lucas del Castillo Agudo, Santiago García-Granda, and José Manuel Montejo-Bernardo pp 9424 - 9433; DOI: 10.1021/ic050110c |
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Synthesis and Relaxivity Studies of a Tetranuclear Gadolinium(III) Complex of DO3A as a Contrast-Enhancing Agent for MRI B. Jebasingh and V. Alexander pp 9434 - 9443; DOI: 10.1021/ic050743r |
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Synthesis and in Solution and Solid State Structural Study of Intramolecular Pt···H Interactions in Pentafluorophenyl Platinum(II) Complexes Containing the Ligands Triazene, Formamidine, and 2-Aminopyridine José M. Casas, Beatriz E. Diosdado, Larry R. Falvello, Juan Forniés, and Antonio Martín pp 9444 - 9452; DOI: 10.1021/ic050800g |
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Arsinophosphonium Cations from Arsenium-phosphine and -bisphosphine Coordination Chemistry Neil Burford, Paul J. Ragogna, Kendall Sharp, Robert McDonald, and Michael J. Ferguson pp 9453 - 9460; DOI: 10.1021/ic050989w |
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Bonding and Metal-Atom Dynamics in Two Unique Sn(I)-Sn(III) Complexes Philip P. Power, Cornel Stanciu, Israel Nowik, and Rolfe H. Herber pp 9461 - 9463; DOI: 10.1021/ic050916c |
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Synthesis and Characterization of the Open-Framework Barium Bisphosphonate [Ba3(O3PCH2NH2CH2PO3)2(H2O)4]·3H2O Sebastian Bauer, Helen Müller, Thomas Bein, and Norbert Stock pp 9464 - 9470; DOI: 10.1021/ic050935m |
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Solution Self-Assembly, Spontaneous Deprotonation, and Crystal Structures of Bipyrazolate-Bridged Metallomacrocycles with Dimetal Centers Shu-Yan Yu, Hai-Ping Huang, Sheng-Hui Li, Qing Jiao, Yi-Zhi Li,, Biao Wu, Yoshihisa Sei, Kentaro Yamaguchi, Yuan-Jiang Pan, and Hong-Wei Ma pp 9471 - 9488; DOI: 10.1021/ic0509332 |
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A Chloro-Bridged Dimanganese Complex and an Oxo-Bridged Dititanium Complex of a Ditopic Bis(pyrazol-1-yl)borate Ligand Susanne Bieller, Michael Bolte, Hans-Wolfram Lerner, and Matthias Wagner pp 9489 - 9496; DOI: 10.1021/ic051689h |
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Spectroscopic and Electrochemical Studies of U(IV)-Hexachloro Complexes in Hydrophobic Room-Temperature Ionic Liquids [BuMeIm][Tf2N] and [MeBu3N][Tf2N] S. I. Nikitenko, C. Cannes, C. Le Naour, P. Moisy, and D. Trubert pp 9497 - 9505; DOI: 10.1021/ic051065b |
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Coupling of an Aldehyde or Ketone to Pyridine Mediated by a Tungsten Imido Complex Trevor W. Hayton, James M. Boncella, Brian L. Scott, Khalil A. Abboud, and Ryan C. Mills pp 9506 - 9517; DOI: 10.1021/ic0511367 |
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Effects of Steric Constraint on Chromium(III) Complexes of Tetraazamacrocycles, 2. Comparison of the Chemistry and Photobehavior of the trans-Dichloro- and trans-Dicyano- Complexes of Cyclam, 1,4-C2-Cyclam, and 1,11-C3-Cyclam Paul S. Wagenknecht, Chuanjiang Hu, Denise Ferguson, Lawrence C. Nathan, Robert D. Hancock, Jason R. Whitehead, Kimberley Wright-Garcia, and Michael T. Vagnini pp 9518 - 9526; DOI: 10.1021/ic051366l |
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Modeling the Active Site of Nitrile Hydratase: Synthetic Strategies to Ensure Simultaneous Coordination of Carboxamido-N and Thiolato-S to Fe(III) Centers Todd C. Harrop, Marilyn M. Olmstead, and Pradip K. Mascharak pp 9527 - 9533; DOI: 10.1021/ic051183z |
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Tetranuclear Platinum Phosphido Complexes with Different Structures Juan Forniés, Consuelo Fortuño, Reyes Gil, and Antonio Martín pp 9534 - 9541; DOI: 10.1021/ic051248y |
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First Structural Characterization of a Protactinium(V) Single Oxo Bond in Aqueous Media Claire Le Naour, Didier Trubert, Maria V. Di Giandomenico, Clara Fillaux, Christophe Den Auwer, Philippe Moisy, and Christoph Hennig pp 9542 - 9546; DOI: 10.1021/ic0512330 |
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Neutral and Ionic Complexes of C60 with Metal Dibenzyldithiocarbamates. Reversible Dimerization of C60- in Ionic Multicomponent Complex [CrI(C6H6)2+]·(C60-)·0.5[Pd(dbdtc)2] Dmitri V. Konarev, Andrey Yu. Kovalevsky, Akihiro Otsuka, Gunzi Saito, and Rimma N. Lyubovskaya pp 9547 - 9553; DOI: 10.1021/ic051261i |
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Characterization and ab Initio XRPD Structure Determination of a Novel Silicate with Vierer Single Chains: The Crystal Structure of NaYSi2O6 Daniel M. Többens, Volker Kahlenberg, and Reinhard Kaindl pp 9554 - 9560; DOI: 10.1021/ic051401o |
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A Practical Synthesis of Isomerically Pure 1,10-Difunctionalized Derivatives of the [closo-1-CB9H10] Anion Bryan Ringstrand, Andrzej Balinski, Andreas Franken, and Piotr Kaszynski pp 9561 - 9566; DOI: 10.1021/ic051311j |
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New Linear High-Valent Tetranuclear Manganese-Oxo Cluster Relevant to the Oxygen-Evolving Complex of Photosystem II with Oxo, Hydroxo, and Aqua Coordinated to a Single Mn(IV) Hongyu Chen, Marie-Noëlle Collomb, Carole Duboc, Geneviève Blondin, Eric Rivière, J. W. Faller, Robert H. Crabtree, and Gary W. Brudvig pp 9567 - 9573; DOI: 10.1021/ic051462m |
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Synthesis of Ortho- and Meta-Re(I)-Metallocarboranes in Water Oyebola O. Sogbein, Andrew E. C. Green, Paul Schaffer, Raymond Chankalal, Edwin Lee, Brian D. Healy, Pierre Morel, and John F. Valliant pp 9574 - 9584; DOI: 10.1021/ic0511221 |
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Aqueous Fluoride and the Preparation of [99mTc(CO)3(OH2)3]+ and 99mTc-Carborane Complexes Oyebola O. Sogbein, Andrew E. C. Green, and John F. Valliant pp 9585 - 9591; DOI: 10.1021/ic051123t |
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New Example of a Non-Heme Mononuclear Iron(IV) Oxo Complex. Spectroscopic Data and Oxidation Activity Marlène Martinho, Frédéric Banse, Jean-François Bartoli, Tony A. Mattioli, Pierrette Battioni, Olivier Horner, Sophie Bourcier, and Jean-Jacques Girerd pp 9592 - 9596; DOI: 10.1021/ic051213y |
Issue 26
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Synthesis, Characterization, and Cytotoxicity of a Novel Highly Charged Trinuclear Platinum Compound. Enhancement of Cellular Uptake with Charge Amanda L. Harris, Xiaohong Yang, Alex Hegmans, Lawrence Povirk, John J. Ryan, Lloyd Kelland, and Nicholas P. Farrell pp 9598 - 9600; DOI: 10.1021/ic051390z |
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Unusual, Bifurcated Photoreactivity of a Rhenium(I) Carbonyl Complex of Triethynylphosphine Sean E. Hightower, Robert C. Corcoran, and B. Patrick Sullivan pp 9601 - 9603; DOI: 10.1021/ic050901e |
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Synthesis and Structural Analysis of the First Nanosized Platinum-Gold Carbonyl/Phosphine Cluster, Pt13[Au2(PPh3)2]2(CO)10(PPh3)4, Containing a Pt-Centered [Ph3PAu-AuPPh3]-Capped Icosahedral Pt12 Cage Namal de Silva and Lawrence F. Dahl pp 9604 - 9606; DOI: 10.1021/ic050990v |
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A Favorable Case Where an Experimental Electron Density Analysis Offers a Lead for Understanding a Specific Fluxional Process Observed in Solution Yannick Ortin, Noël Lugan, Sébastien Pillet, Mohammed Souhassou, Claude Lecomte, Karine Costuas, and Jean-Yves Saillard pp 9607 - 9609; DOI: 10.1021/ic051239p |
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[M(R-dmet)2] Bis(1,2-dithiolenes): a Promising New Class Intermediate between [M(dmit)2] and [M(R,R'-timdt)2] (M = Ni, Pd, Pt) M. Carla Aragoni, Massimiliano Arca, Francesco A. Devillanova, Francesco Isaia, Vito Lippolis, Annalisa Mancini, Luca Pala, Alexandra M. Z. Slawin, and J. Derek Woollins pp 9610 - 9612; DOI: 10.1021/ic051260q |
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Why Are Carborane Acids so Acidic? An Electrostatic Interpretation of Brnsted Acid Strengths P. Balanarayan and Shridhar R. Gadre pp 9613 - 9615; DOI: 10.1021/ic051347b |
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Methoxide of an Anderson-Type Polyoxometalate and Its Conversion to a New Type of Species, [IMo9O32(OH)(OH2)3]4- Daisuke Honda, Tomoji Ozeki, and Atsushi Yagasaki pp 9616 - 9618; DOI: 10.1021/ic051351n |
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Solid-State Photochromic Device Based on Nanocrystalline TiO2 Functionalized with Electron Donor-Acceptor Species Matteo Biancardo, Roberto Argazzi, and Carlo A. Bignozzi pp 9619 - 9621; DOI: 10.1021/ic0514593 |
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Reduction of the Host Cationic Framework Charge by Isoelectronic Substitution: Synthesis and Structure of Hg7Ag2P8X6 (X = Br, I) and Hg6Ag4P8Br6 Olga S. Oleneva, Andrei V. Olenev, Tatiana A. Shestimerova, Alexey I. Baranov, Evgeny V. Dikarev, and Andrei V. Shevelkov pp 9622 - 9624; DOI: 10.1021/ic0513944 |
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Highly Sensitive Ammonium Tetraazidoaurates(III) Thomas M. Klapötke, Burkhard Krumm, Juan-Carlos Galvez-Ruiz, and Heinrich Nöth pp 9625 - 9627; DOI: 10.1021/ic051543i |
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Oxygen Binding of Water-Soluble Cobalt Porphyrins in Aqueous Solution James P. Collman, Yi-Long Yan, Todd Eberspacher, Xiangjin Xie, and Edward I. Solomon pp 9628 - 9630; DOI: 10.1021/ic0516717 |
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mer-[Fe(pcq)(CN)3]-: A Novel Cyanide-Containing Building Block and Its Application to Assembling Cyanide-Bridged Trinuclear FeIII2MnII Complexes [pcq- = 8-(Pyridine-2-carboxamido)quinoline Anion] Zhong-Hai Ni, Hui-Zhong Kou, Li-Fang Zhang, Wei-Wei Ni, Yun-Bo Jiang, Ai-Li Cui, Joan Ribas, and Osamu Sato pp 9631 - 9633; DOI: 10.1021/ic051385v |
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Secondary Bonding Interactions Observed in Two Arsenic Thiolate Complexes Timothy G. Carter, Elisabeth Rather Healey, Melanie A. Pitt, and Darren W. Johnson pp 9634 - 9636; DOI: 10.1021/ic051522o |
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Synthesis and Structural Characterization of M(PMe3)3(O2CR)2(OH2)H2 (M = Mo, W): Aqua-Hydride Complexes of Molybdenum and Tungsten Guang Zhu and Gerard Parkin pp 9637 - 9639; DOI: 10.1021/ic051617q |
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Theoretical Study of Catalytic Dinitrogen Reduction under Mild Conditions Markus Reiher, Boris Le Guennic, and Barbara Kirchner pp 9640 - 9642; DOI: 10.1021/ic0517568 |
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Metal-Metal Bond or Isolated Metal Centers? Interaction of Hg(CN)2 with Square Planar Transition Metal Cyanides Róbert Jószai, Imre Beszeda, Attila C. Bényei, Andreas Fischer, Margit Kovács, Mikhail Maliarik, Péter Nagy, Andrey Shchukarev, and Imre Tóth pp 9643 - 9651; DOI: 10.1021/ic050352c |
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MXAN Analysis of the XANES Energy Region of a Mononuclear Copper Complex: Applications to Bioinorganic Systems Ritimukta Sarangi, Maurizio Benfatto, Kuniko Hayakawa, Luigi Bubacco, Edward I. Solomon, Keith O. Hodgson, and Britt Hedman pp 9652 - 9659; DOI: 10.1021/ic050703n |
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((Fluoroformyl)imido)sulfuryl Difluoride, FC(O)N=S(O)F2: Structural, Conformational, and Configurational Properties in the Gaseous and Condensed Phases Roland Boese, Edgardo H. Cutin, Rüdiger Mews, Norma L. Robles, and Carlos O. Della Védova pp 9660 - 9666; DOI: 10.1021/ic050808q |
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Luminescence Ranging from Red to Blue: A Series of Copper(I)-Halide Complexes Having Rhombic {Cu2(-X)2} (X = Br and I) Units with N-Heteroaromatic Ligands Hiromi Araki, Kiyoshi Tsuge, Yoichi Sasaki, Shoji Ishizaka, and Noboru Kitamura pp 9667 - 9675; DOI: 10.1021/ic0510359 |
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Synthesis, Structure, and Magnetic Properties of Sr2NiOsO6 and Ca2NiOsO6: Two New Osmium-Containing Double Perovskites René Macquart, Seung-Joo Kim, William R. Gemmill, Judith K. Stalick, Yongjae Lee, Tom Vogt, and Hans-Conrad zur Loye pp 9676 - 9683; DOI: 10.1021/ic051045+ |
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A Novel Diamine Adduct of Zinc Bis(2-thenoyl-trifluoroacetonate) as a Promising Precursor for MOCVD of Zinc Oxide Films Graziella Malandrino, Manuela Blandino, Laura M. S. Perdicaro, Ignazio L. Fragalà, Patrizia Rossi, and Paolo Dapporto pp 9684 - 9689; DOI: 10.1021/ic051175i |
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Controlling Emission Energy, Self-Quenching, and Excimer Formation in Highly Luminescent NCN-Coordinated Platinum(II) Complexes Sarah J. Farley, David L. Rochester, Amber L. Thompson, Judith A. K. Howard, and J. A. Gareth Williams pp 9690 - 9703; DOI: 10.1021/ic051049e |
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Electronic Structure Study of Seven-Coordinate First-Row Transition Metal Complexes Derived from 1,10-Diaza-15-crown-5: A Successful Marriage of Theory with Experiment Carlos Platas-Iglesias, Lea Vaiana, David Esteban-Gómez, Fernando Avecilla, José Antonio Real, Andrés de Blas, and Teresa Rodríguez-Blas pp 9704 - 9713; DOI: 10.1021/ic051119h |
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Syntheses, Crystal Structures, and Spectroscopic and Magnetic Properties of [Mn2III(H2L1)(Cl4Cat)4·2H2O] and [Mn2III(H2L2)(Cl4Cat)4·2CH3CN·2H2O]: Temperature-Dependent Valence Tautomerism in Solution Nizamuddin Shaikh, Sanchita Goswami, Anangamohan Panja, Hao-Ling Sun, Feng Pan, Song Gao, and Pradyot Banerjee pp 9714 - 9722; DOI: 10.1021/ic051064j |
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Crystal Structure, Magnetic Properties, and 57Fe Mössbauer Spectroscopy of the Two-Dimensional Coordination Polymers [M(1,2-bis(1,2,4-triazol-4-yl)ethane)2(NCS)2] (MII = Fe, Co) Yann Garcia, Georges Bravic, Christine Gieck, Daniel Chasseau, Wolfgang Tremel, and Philipp Gütlich pp 9723 - 9730; DOI: 10.1021/ic050971l |
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Inorganic-Metalorganic Hybrids Based on Copper(II)-Monosubstituted Keggin Polyanions and Dinuclear Copper(II)-Oxalate Complexes. Synthesis, X-ray Structural Characterization, and Magnetic Properties Santiago Reinoso, Pablo Vitoria, Juan M. Gutiérrez-Zorrilla, Luis Lezama, Leire San Felices, and Javier I. Beitia pp 9731 - 9742; DOI: 10.1021/ic051134m |
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X-ray Diffraction and EXAFS Studies of Hydroxo-Cu(II) Complexes Based on a Calix[6]arene-N3 Ligand: Evidence for a Mononuclear-Dinuclear Equilibrium Controlled by Supramolecular Features Guillaume Izzet, Yves M. Frapart, Thierry Prangé, Karine Provost, Alain Michalowicz, and Olivia Reinaud pp 9743 - 9751; DOI: 10.1021/ic0511322 |
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Pyridylporphyrin Metallacycles with a Slipped Cofacial Geometry: Spectroscopic, X-ray, and Photophysical Characterization Elisabetta Iengo, Ennio Zangrando, Marco Bellini, Enzo Alessio, Anna Prodi, Claudio Chiorboli, and Franco Scandola pp 9752 - 9762; DOI: 10.1021/ic051210l |
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Between Ni(mnt)2 and Ni(tfd)2 Dithiolene Complexes: the Unsymmetrical 2-(Trifluoromethyl)acrylonitrile-1,2-dithiolate and Its Nickel Complexes Olivier Jeannin, Jacques Delaunay, Frédéric Barrière, and Marc Fourmigué pp 9763 - 9770; DOI: 10.1021/ic051226b |
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Fluorocarbon Soluble Copper(II) Carboxylate Complexes with Nonfluoroponytailed Nitrogen Ligands as Precatalysts for the Oxidation of Alkenols and Alcohols under Fluorous Biphasic or Thermomorphic Modes: Structural and Mechanistic Aspects Maria Contel, Pedro R. Villuendas, Jacob Fernández-Gallardo, Pablo J. Alonso, Jean-Marc Vincent, and Richard H. Fish pp 9771 - 9778; DOI: 10.1021/ic051220m |
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Cadmium(II) and Zinc(II) Complexes of Pyrrole-Appended Oxacarbaporphyrin: A Side-on Coordination Mode of O-Confused Carbaporphyrin Mi osz Pawlicki, Lechosaw Latos-Grayski, and Ludmia Szterenbergpp 9779 - 9786; DOI: 10.1021/ic051238x |
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A Mets Motif Peptide Found in Copper Transport Proteins Selectively Binds Cu(I) with Methionine-Only Coordination Jianfeng Jiang, Istvan A. Nadas, M. Alison Kim, and Katherine J. Franz pp 9787 - 9794; DOI: 10.1021/ic051180m |
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Magnetism, Electron Paramagnetic Resonance, Electrochemistry, and Mass Spectrometry of the Pentacopper(II)-Substituted Tungstosilicate [Cu5(OH)4(H2O)2(A--SiW9O33)2]10-, A Model Five-Spin Frustrated Cluster Saritha Nellutla, Johan van Tol, Naresh S. Dalal, Li-Hua Bi, Ulrich Kortz, Bineta Keita, Louis Nadjo, Gregory A. Khitrov, and Alan G. Marshall pp 9795 - 9806; DOI: 10.1021/ic0512633 |
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Acetylene Cyclotrimerization by Early Second-Row Transition Metals in the Gas Phase. A Theoretical Study Mayra Martinez, Maria del Carmen Michelini, Ivan Rivalta, Nino Russo, and Emilia Sicilia pp 9807 - 9816; DOI: 10.1021/ic051281k |
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Structure-Controlled Solventless Thermolytic Synthesis of Uniform Silver Nanodisks Yu-Biao Chen, Ling Chen, and Li-Ming Wu pp 9817 - 9822; DOI: 10.1021/ic051246d |
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A Kinetically Controlled Trans Bifunctionalized Organoimido Derivative of the Lindqvist-Type Hexamolybdate: Synthesis, Spectroscopic Characterization, and Crystal Structure of (n-Bu4N)2{trans-[Mo6O17(NAr)2]} (Ar = 2,6-dimethylphenyl) Yun Xia, Yongge Wei, Yuan Wang, and Hongyou Guo pp 9823 - 9828; DOI: 10.1021/ic051319t |
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Synthesis, Characterization, and Luminescence Properties of a New Series of Eu3+-Containing Macrocycles Christopher G. Gulgas and Theresa M. Reineke pp 9829 - 9836; DOI: 10.1021/ic051324x |
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Synthesis, Structures, and Magnetic Properties of the Copper(II), Cobalt(II), and Manganese(II) Complexes with 9-Acridinecarboxylate and 4-Quinolinecarboxylate Ligands Xian-He Bu, Ming-Liang Tong, Ya-Bo Xie, Jian-Rong Li, Ho-Chol Chang, Susumu Kitagawa, and Joan Ribas pp 9837 - 9846; DOI: 10.1021/ic050886d |
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Electrochemical and Spectroscopic Studies of the Chloro and Oxochloro Complex Formation of Nb(V) and Ta(V) in NaCl-AlCl3 Melts J. H. von Barner and N. J. Bjerrum pp 9847 - 9851; DOI: 10.1021/ic050367a |
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Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 3. A New Highly Electron-Deficient Octacationic Macrocycle: Tetrakis-2,3-[5,6-di{2-(N-methyl)pyridiniumyl}pyrazino]porphyrazine, [(2-Mepy)8TPyzPzH2]8+ Costanza Bergami, Maria Pia Donzello, Claudio Ercolani, Fabrizio Monacelli, Karl M. Kadish, and Corrado Rizzoli pp 9852 - 9861; DOI: 10.1021/ic051084l |
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Tetra-2,3-pyrazinoporphyrazines with Externally Appended Pyridine Rings. 4. UV-Visible Spectral and Electrochemical Evidence of the Remarkable Electron-Deficient Properties of the New Tetrakis-2,3-[5,6-di{2-(N-methyl)pyridiniumyl}pyrazino]porphyrazinatometal Octacations, [(2-Mepy)8TPyzPzM]8+ (M = MgII(H2O), CoII, CuII, ZnII) Costanza Bergami, Maria Pia Donzello, Fabrizio Monacelli, Claudio Ercolani, and Karl M. Kadish pp 9862 - 9873; DOI: 10.1021/ic051085d |
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Stereochemical Investigations of a Novel Class of Chiral Phosphapalladacycle Complexes Derived from 1-[(2,5-Dimethyl)phenyl]ethyldiphenylphosphine Joseph Kok-Peng Ng, Yongxin Li, Geok-Kheng Tan, Lip-Lin Koh, Jagadese J. Vittal, and Pak-Hing Leung pp 9874 - 9886; DOI: 10.1021/ic0509579 |
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Dithiolate Complexes of Manganese and Rhenium: X-ray Structure and Properties of an Unusual Mixed Valence Cluster Mn3(CO)6(-2-SCH2CH2CH2S)3 Noorjahan Begum, Md. Iqbal Hyder, Shariff E. Kabir, G. M. Golzar Hossain, Ebbe Nordlander, Dalia Rokhsana, and Edward Rosenberg pp 9887 - 9894; DOI: 10.1021/ic050987b |
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Synthesis and Growth Mechanisms of One-Dimensional Strontium Hydroxyapatite Nanostructures Tae-Gon Kim and Byungwoo Park pp 9895 - 9901; DOI: 10.1021/ic051013m |
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X-ray Structures and Homolysis of Some Alkylcobalt(III) Phthalocyanine Complexes Wlodzimierz Galezowski and Maciej Kubicki pp 9902 - 9913; DOI: 10.1021/ic051078p |
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Substituent Effects on Indium-Phosphorus Bonding in (4-RC6H4S)3In·PR'3 Adducts (R = H, Me, F; R' = Et, Cy, Ph): A Spectroscopic, Structural, and Thermal Decomposition Study Glen G. Briand, Reagan J. Davidson, and Andreas Decken pp 9914 - 9920; DOI: 10.1021/ic051138r |
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Versatility of Dithiophosphates in the Syntheses of Copper(I) Complexes with Bis(diphenylphosphino)alkanes: Abstraction of Chloride from Dichloromethane Ben-Jie Liaw, Tarlok S. Lobana, Ya-Wen Lin, Ju-Chun Wang, and C. W. Liu pp 9921 - 9929; DOI: 10.1021/ic051166+ |
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Novel Rhenium Chelate System Derived from Dimercaptosuccinic Acid for the Selective Labeling of Biomolecules Tobias K. Heinrich, Werner Kraus, Hans-Jürgen Pietzsch, Christoph Smuda, and Hartmut Spies pp 9930 - 9937; DOI: 10.1021/ic051148s |
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Synthesis of WO3 Nanorods by Reacting WO(OMe)4 under Autogenic Pressure at Elevated Temperature Followed by Annealing S. V. Pol, V. G. Pol, V. G. Kessler, G. A. Seisenbaeva, L. A. Solovyov, and A. Gedanken pp 9938 - 9945; DOI: 10.1021/ic051179n |
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Nitric Oxide Production by Visible Light Irradiation of Aqueous Solution of Nitrosyl Ruthenium Complexes Marília Gama Sauaia, Renata Galvão de Lima, Antonio Claudio Tedesco, and Roberto Santana da Silva pp 9946 - 9951; DOI: 10.1021/ic051346j |
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Oxidation of Thioglycolate by [Os(phen)3]3+: an Unusual Example of Redox-Mediated Aromatic Substitution Meiling Hung and David M. Stanbury pp 9952 - 9960; DOI: 10.1021/ic051241g |
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Coordination Versatility of Pyridine-Functionalized N-Heterocyclic Carbenes: A Detailed Study of the Different Activation Procedures. Characterization of New Rh and Ir Compounds and Study of Their Catalytic Activity Elena Mas-Marzá, Mercedes Sanaú, and Eduardo Peris pp 9961 - 9967; DOI: 10.1021/ic051272b |
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Synthesis and Characterization of New Calcium Phenylphosphonates and 4-Carboxyphenylphosphonates Jan Svoboda, Vít  zslav Zima, Ludvík Bene, Klára Melánová, and Milan Vlekpp 9968 - 9976; DOI: 10.1021/ic051606x |
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Proton NMR Spectroscopy and Magnetic Properties of a Solution-Stable Dicopper(II) Complex Bearing a Single -Hydroxo Bridge Iryna A. Koval, Karlijn van der Schilden, Anna MariaSchuitema, Patrick Gamez, Catherine Belle, Jean-Louis Pierre, Matthias Lüken, Bernt Krebs, Olivier Roubeau, and JanReedijk: pp 9977 - 9977; DOI: 10.1021/ic058010u |
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Enantiopure 1,1'-Binaphthyl-Based Polyoxometalate-Containing Molecular Hybrids Meng Lu, Jeonghee Kang, Degang Wang, and ZhonghuaPeng: pp 9977 - 9977; DOI: 10.1021/ic058012e |